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a. PTHH:
\(Cu+H_2SO_4--\times-->\)
\(CuO+H_2SO_4--->CuSO_4+H_2O\left(1\right)\)
\(Cu+2H_2SO_{4_{đặc}}\overset{t^o}{--->}CuSO_4+SO_2+2H_2O\left(2\right)\)
Ta có: \(n_{SO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Theo PT(2): \(n_{Cu}=n_{SO_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)
\(\Rightarrow\%_{m_{Cu}}=\dfrac{3,2}{10}.100\%=32\%\)
\(\%_{m_{CuO}}=100\%-32\%=68\%\)
PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(Cu+2H_2SO_{4\left(đ\right)}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O\)
Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT: \(n_{Cu}=n_{SO_2}=0,25\left(mol\right)\)
\(\Rightarrow\%m_{Cu}=\dfrac{0,25.64}{24}.100\%\approx66,67\%\)
a)
H2SO4(loãng, dư)+CuO→ H2O+ CuSO4(1)
(mol)
H2SO4(loãng, dư)+Cu→không phản ứng
Cu+ 2H2SO4(đặc, nóng)→ CuSO4+ SO2+ 2H2O(2)
(mol) 0,15 0,3 0,15 0,15
b)
\(n_{SO_2}=\dfrac{V}{22,4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(m_{Cu}=n.M=0,15.64=9,6\left(gam\right)\)
→\(m_{CuO}=m_{hh}-m_{Cu}=17,6-9,6=8\left(gam\right)\)
=>\(C\%_{Cu}=\dfrac{9,6}{17,6}.100\%=54,54\%\)
\(C\%_{CuO}=\dfrac{8}{17,6}.100\%=0,45\%\)
nHCl=\(\dfrac{100,85.1,19.36,5\%}{36,5}\)=1,19(mol)
Bảo toàn nguyên tố Cl => nCuCl2=\(\dfrac{1}{2}n_{HCl}\) =0,595(mol)
Ta có : nCu(OH)2=0,4(mol)=nCuCl2n <0,595
=> HCl dư khi tác dụng với hỗn hợp A
CuO+2HCl−−−>CuCl2+H2O
0,4<----0,8<-------0,4
=> Chất rắn C không tan chỉ có Cu
nSO2=\(\dfrac{11,2}{22,4}\)=0,5(mol)
Cu+2H2SO4(đ,n)−−−>CuSO4+SO2↑+2H2O
0,5<-------------------------------------0,5
=>
\(\%m_{CuO}=\dfrac{0,4.80}{0,4.80+0,5.64}.100=50\%\)
=>%mCu =100-50=50%
b, 2NaOH+CuCl2−−−>2NaCl+Cu(OH)2↓
0,8<----------0,4<-----------------------0,4
=> \(m_{ddNaOH}=\dfrac{0,8.40}{25\%}=128\left(g\right)\)
=> VddNaOH=\(\dfrac{128}{1,28}\)=100(ml)
\(CuO+H_2SO_{4\left(24,5\%\right)}\rightarrow CuSO_4+H_2O\)
\(Cu+2H_2SO_{4đ}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O\)
\(n_{SO_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(\Rightarrow n_{Cu}=0,05\left(mol\right)\)
\(\Rightarrow m_{CuO}=10-64.0,05=6,8\left(g\right)\)
\(\Rightarrow n_{CuO}=0,085\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(24,5\%\right)}=0,085\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(24,5\%\right)}=8,33\left(g\right)\)
\(\Rightarrow m_{ddH_2SO_4\left(24,5\%\right)}=34\left(g\right)\)
a)
$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + 2H_2O$
$n_{Cu} = n_{SO_2} = \dfrac{1,12}{22,4} = 0,05(mol)$
$\%m_{Cu} = \dfrac{0,05.64}{10}.100\% = 32\%$
$\%m_{CuO} = 100\% -32\% = 68\%$
b)
$NaOH + SO_2 \to NaHSO_3$
$n_{NaOH} = n_{SO_2} = 0,05(mol)$
$V_{dd\ NaOH} = \dfrac{0,05}{2} = 0,025(lít) = 25(ml)$
cảm ơn bạn