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a) Ta có: \(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)
Gọi a và b lần lượt là số mol của Al và Zn
Bảo toàn mol e: \(3a+2b=1,4\)
Mà \(27a+65b=31,4\)
\(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{31,4}\cdot100\%\approx17,2\%\\\%m_{Zn}=82,8\%\end{matrix}\right.\)
b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=1,4mol\)
\(\Rightarrow V_{HCl}=\dfrac{1,4}{2}=0,7\left(l\right)=700\left(ml\right)\)
Đặt :
nAl = a mol
nZn = b mol
mB = 27a + 65b = 31.4 (g) (1)
2Al + 6HCl => 2AlCl3 + 3H2
a___________________1.5a
Zn + 2HCl => ZnCl2 + H2
b__________________b
nH2 = 1.5a + b = 15.68/22.4 = 0.7 (mol) (2)
(1) , (2) :
a = 0.2
b = 0.4
%Al = 5.4/31.4 * 100% = 17.19%
%Zn = 100 - 17.19 = 82.81%
nHCl = 2nH2 = 0.7*2 = 1.4 (mol)
Vdd HCl = 1.4 / 2 = 0.7 (l)
Ta có: \(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)
Gọi a và b lần lượt là số mol của Al và Fe
Bảo toàn mol e: \(3a+2b=1,4\)
Mà \(27a+56b=27,8\)
\(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,4\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2\cdot27}{27,8}\cdot100\approx19,42\%\\\%m_{Fe}=80,58\%\end{matrix}\right.\)
Đặt :
nAl = a mol
nFe = b mol
mB = 27a + 56b = 27.8 (g) (1)
2Al + 6HCl => 2AlCl3 + 3H2
a___________________1.5a
Fe + 2HCl => FeCl2 + H2
b__________________b
nH2 = 1.5a + b = 15.68/22.4 = 0.7 (mol) (2)
(1) , (2) :
a = 0.2
b = 0.4
%Al = 5.4/27.8 * 100% = 19.42%
%Fe = 100 - 19.42 = 80.58%
1)
a)
$CaO + 2HCl \to CaCl_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CO_2} = 0,2(mol)$
$n_{CaCl_2} = 0,3(mol)$
Suy ra:
$n_{CaO} = 0,3 - 0,2 = 0,1(mol)$
$\%m_{CaO} = \dfrac{0,1.56}{0,1.56 + 0,2.100}.100\% = 21,875\%$
$\%m_{CaCO_3} = 78,125\%$
b)
$m_{dd} = 0,1.56 + 0,2.100 + 50 - 0,2.44 = 66,8(gam)$
$C\%_{CaCl_2} = \dfrac{33,3}{66,8}.100\% = 49,85\%$
Câu 4 :
a)
Gọi $n_{Fe} = a(mol) ; n_{MgO} = b(mol)$
Suy ra: $56a + 40b = 19,2(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$MgO + 2HCl \to MgCl_2 + H_2O$
Theo PTHH : $n_{HCl} = 2a + 2b = 0,4.2 = 0,8(2)$
Từ (1)(2) suy ra a = b = 0,2
$\%m_{Fe} = \dfrac{0,2.56}{19,2}.100\% = 58,33\%$
$\%m_{MgO} = 100\% -58,33\% = 41,67\%$
b)
$n_{FeCl_2} = a = 0,2(mol)$
$n_{MgCl_2} = b = 0,2(mol)$
$m_{muối} = 0,2.127 + 0,2.95 = 44,4(gam)$
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\end{matrix}\right.\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)
0,2_____0,4_____0,2____0,2_____0,2 (mol)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
0,1_____0,2_____0,1____0,1 (mol)
Ta có: \(\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CaO}=\dfrac{5,6}{5,6+20}\cdot100\%=21,875\%\\\%m_{CaCO_3}=78,125\%\end{matrix}\right.\)
Mặt khác: \(m_{CO_2}=0,2\cdot44=8,8\left(g\right)\)
\(\Rightarrow m_{dd\left(sau.p/ứ\right)}=m_{CaO}+m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=66,8\left(g\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{33,3}{66,8}\cdot100\%\approx49,85\%\)
nCO2=\(\dfrac{4,48}{22,4}=0,2\) mol
nCaCl2=\(\dfrac{33,3}{111}=0,3\)
CaCO2 + 2HCl → CaCl2 + CO2 + H2O
0,2 ← 0,2 ← 0,2
CaO + 2HCl → CaCl2 + H2O
0,1 ← 0,1
a) % CaO=\(\dfrac{0,1.56}{0,1.56+0,2.100}.100\%=21,875\%\)
% CaCO3 =100% - 21,875%= 78,125%
b) a = mCaO+mCaCO3 =0,1.56+0,2.100=25,6g
mdd sau pư= a + mddHCl - mCO2
= 25,6 + 50 - 0,2.44=66,8g
C%CaCl2=\(\dfrac{33,3}{66,8}.100\%\simeq49,85\%\)
Gọi : \(\left\{{}\begin{matrix}n_{MgO}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\)⇒ 40a + 65b = 34(1)
\(MgO + 2HCl \to MgCl_2 + H_2O\\ Zn + 2HCl \to ZnCl_2 + H_2O\)
Muối gồm :\(\left\{{}\begin{matrix}n_{MgCl_2}=a\left(mol\right)\\n_{ZnCl_2}=b\left(mol\right)\end{matrix}\right.\)
Suy ra : 95a + 136b = 73,4(2)
Từ (1)(2) suy ra a = 0,2 ; b = 0,4
Vậy :
\(\%m_{MgO} = \dfrac{0,2.40}{34} .100\% = 23,53\%\\ \%m_{Zn} = 100\% - 23,53\% = 76,47\%\)
\(PTHH:CaO+2HCl\rightarrow CaCl2+H2O\)
________0,1____________0,1____________
\(CaCO3+2HCl\rightarrow CaCl2+CO2+H2O\)
0,2_____________0,2_________0,2_________
Ta có :
\(n_{CO2}=\frac{4,48}{22,4}=0,2\left(mol\right)\)
\(n_{CaCl2}=\frac{33,3}{111}=0,3\left(mol\right)\)
\(\rightarrow n_{CaCO3}=0,2\left(mol\right),n_{CaO}=0,1\left(mol\right)\)
\(a=m_{CaCO3}+m_{CaO}=0,2.100+0,1.56=25,6\left(g\right)\)
\(2A+2aHCl\rightarrow2ACl_a+aH_2\)
\(TheoPTHH:n_{H_2}=\dfrac{an_A}{2}=0,5an_A=0,5.a.\dfrac{1,17}{A}=\dfrac{V}{22,4}=0,015\)
\(\Rightarrow\dfrac{a}{A}=\dfrac{1}{39}\)
\(\Rightarrow\) A là Kali ( K ).
\(\Rightarrow n_{HCl}=2n_{H_2}=0,03\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{n}{C_M}=\dfrac{0,03}{1,2}=0,025\left(l\right)=25\left(ml\right)\)
PTHH: \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\) (2)
a) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{CaO}=0,1mol\\n_{CaCO_3}=0,2mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{hh}=20+5,6=25,6\left(g\right)\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=0,2mol\\n_{HCl\left(2\right)}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=0,6mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,3}=2\left(M\right)\)
PT: \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\) (2)
a, Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(\Sigma n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\)
Theo PT (2): \(n_{CaCl_2}=n_{CO_2}=0,2\left(mol\right)\)
\(\Rightarrow n_{CaCl_2\left(1\right)}=0,3-0,2=0,1\left(mol\right)\)
Theo PT (1): \(n_{CaO}=n_{CaCl_2}=0,1\left(mol\right)\)
Theo PT (2): \(n_{CaCO_3}=n_{CO_2}=0,2\left(mol\right)\)
\(\Rightarrow m_A=m_{CaO}+m_{CaCO_3}=0,1.56+0,2.100=25,6\left(g\right)\)
b, Theo PT (1) + (2): \(\Sigma n_{HCl}=2n_{CaO}+2n_{CaCO_3}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{ddHCl}}=\dfrac{0,6}{0,3}=2M\)
Bạn tham khảo nhé!