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\(n_{HCl}=0,2.3=0,6\left(mol\right)\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2\\ n_{Fe_2O_3}=\dfrac{0,6}{6}=0,1\left(mol\right)\\ \Rightarrow m_{Fe_2O_3}=0,1.160=16\left(g\right)\)
Mg + 2HCl -> MgCl2 + H2
0.2 0.4 0.2 0.2
\(nHCl=0.2\times2=0.4mol\)
a.\(m=0.2\times24=4.8g\); \(V=0.2\times22.4=4.48l\)
b.MgCl2 + 2NaOH -> Mg(OH)2 + NaCl
0.2 0.2
\(mNaOH=20\%\times100=20g\Rightarrow nNaOH=0.5mol\)
=> MgCl2 hết, NaOH dư
\(mMg\left(OH\right)2=0.2\times58=11.6g\)
\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)
\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)
PTHH
Mg + 2HCl ----> MgCl2 + H2 (1)
MgO + 2HCl -----> MgCl2 + H2O (2)
a) Theo pt(1) n Mg = n H2 = \(\frac{1,12}{22,4}\) = 0,05 (mol)
==> m Mg = 0,005 . 24=1,2 (g)
%m Mg = \(\frac{1,2}{3,2}\). 100%= 37,5%
%m MgO= 100% - 37,5%= 62,5%
b)m dd sau pư = 3,2 + 246,9 - 0,05 . 2=250 (g)
Theo pt(1)(2) n MgCl2(1) = n Mg = 0,05 mol
n MgCl2 (2) = n MgO=\(\frac{3,2-1,2}{40}\)=0,05(mol)
==> tổng n MgCl2 = 0,1 (mol) ---->m MgCl2 = 9,5 (g)
C%(MgCl2)= \(\frac{9,5}{250}\) .100% = 3,8%
1/ nNaCl=5,85/58,5=0,1 mol.
nAgNO3=34/170=0,2 mol.
PTPU: NaCl+AgNO3=>AgCl+NaNO3
vì NaCl và AgNO3 phan ung theo ti le 1:1 (nAgNO3 p.u=nNaCl=0,1 mol)
=>AgNO3 du
nAgNO3 du= 0,2-0,1=0,1 mol.
Ta tinh luong san pham theo chat p.u het la NaCl
sau p.u co: AgNO3 du:0,1 mol; AgCl ket tua va NaCl: nAgCl=nNaNO3=nNaCl=0,1 mol.V(dd)=300+200=500ml=0,5 ()l
=>khoi lg ket tua: mAgCl=0,1.143,5=14,35 g
C(M)AgNO3=C(M)NaNO3=n/V=0,1/0,5=0,2 M
a) \(NaOH+HCl\rightarrow NaCl+H_2O\)
0,1................0,3
LẬp tỉ lệ : \(\dfrac{0,1}{1}< \dfrac{0,3}{1}\)=> Sau pứ HCl dư
\(m_{NaCl}=0,1.58,5=5,85\left(g\right)\)
b) \(CM_{NaCl}=\dfrac{0,1}{0,2+0,3}=0,2M\)
\(CM_{HCl\left(dư\right)}=\dfrac{\left(0,3-0,1\right)}{0,2+0,3}=0,4M\)
PTHH: Zn + 2HCl \(\rightarrow\) ZnCl2 + H2\(\uparrow\)
nZn = \(\dfrac{6,5}{65}=0,1\left(mol\right)\)
Theo PT: nHCl = 2nZn =2.0,1=0,2(mol)
nH2=nZn=0,1 ( mol )
=>VH2=0,1 . 22,4= 2,24( l )
Đổi : 500ml=0,5l
=> CM = \(\dfrac{n}{V}\) = \(\dfrac{0,2}{0,5}\) = 0,4( M )
PTHH: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
Ta có: \(n_{HCl}=0,2\cdot3=0,6\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{FeCl_3}=0,2\left(mol\right)\\n_{Fe_2O_3}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=0,1\cdot160=16\left(g\right)\\m_{FeCl_3}=0,2\cdot162,5=32,5\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_3}=\dfrac{32,5}{16+200\cdot1,1}\cdot100\%\approx13,77\%\\C_{M_{FeCl_3}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)