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nKOH = 0,5.0,3 = 0,15 mol
CH3COOH + KOH → CH3COOK + H2O
0,15 0,15 0,15 mol
a) CM CH3COOH = 0,15/0,2 =0,75M
b) Thể tích của dung dịch thu được sau phản ứng: 500 ml
CM CH3COOK = 0,15/0,5 = 0,3M
c) Phản ứng lên men giấm
C2H5OH + O2 → CH3COOH + H2O
0,15 0,15
→ mC2H5OH = 0,15.46 = 6,9 gam
\(n_{KOH}=0,5\cdot0,3=0,15mol\)
\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,15 0,15 0,15 0,15
a)\(C_{M_{CH_3COOH}}=\dfrac{0,15}{0,2}=0,75M\)
b)\(C_{M_{CH_3COOK}}=\dfrac{0,15}{0,2+0,3}=0,3M\)
a, \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
b, Phần này đề hỏi tính khối lượng gì bạn nhỉ?
c, \(n_{Zn}=\dfrac{32,5}{65}=0,5\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{Zn}=1\left(mol\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{1.60}{36\%}=\dfrac{500}{3}\left(g\right)\)
Cho kim loại Magie tác dụng vừa đủ với 200 gam dung dịch axit axetic 15%.
a. Tính khối lượng Magie phản ứng ?
b. Tính nồng độ phần trăm dung dịch muối thu được sau phản ứng ?
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mCH3COOH= 200.15%= 30(g) => nCH3COOH= 30/60=0,5(mol)
a) Mg + 2 CH3COOH -> (CH3COO)2Mg + H2
0,25___0,5_______0,25_____________0,25(mol)
mMg= 0,25.24= 6(g)
b) m(CH3COO)2Mg=142.0,25=35,5(g)
mdd(CH3COO)2Mg= 6+200-0,25.2=205,5(g)
=> \(C\%dd\left(CH3COO\right)2Mg=\frac{35,5}{205,5}.100\approx17,275\%\)
a) Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)
PTHH: Na2CO3 + 2CH3COOH --> 2CH3COONa + CO2 + H2O
0,0125<-----0,025------------>0,025------>0,0125
=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)
c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)
\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)
a, \(m_{CH_3COOH}=100.6\%=6\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{6}{60}=0,1\left(mol\right)\)
PT: \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{NaHCO_3}=n_{CH_3COONa}=n_{CO_2}=n_{CH_3COOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{NaHCO_3}=0,1.84=8,4\left(g\right)\)
\(V_{CO_2}=0,1.22,4=2,24\left(l\right)\)
b, Ta có: m dd sau pư = 100 + 8,4 - 0,1.44 = 104 (g)
\(\Rightarrow C\%_{CH_3COONa}=\dfrac{0,1.82}{104}.100\%\approx7,88\%\)
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,1 0,2
a. \(V_{CH_3COOH}=\dfrac{0,2}{1}=0,2\left(l\right)\)
b. \(CH_3COOH+C_2H_5OH⇌\left(H_2SO_{4đ},t^o\right)CH_3COOC_2H_5+H_2O\)
0,2 0,2
Với H% = 80
\(m_{CH_3COOC_2H_5}=\dfrac{0,2.88.80}{100}=14,08\left(g\right)\)
\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
Rượu etylic \(C_2H_5OH\)
Axit axetic \(CH_3COOH\)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)
\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)
0,2 0,1 0,2 0,1 0,1
\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)
\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)
a)
\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Na2CO3 --> 2CH3COONa + CO2 + H2O
0,2<----------0,1<-------------0,2<-------0,1
=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)
\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)
b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)
\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)
\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{\left(CH_3COO\right)_2Fe}=0,2.174=34,8\left(g\right)\)
Ta có: \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\)
m dd sau pư = 11,2 + 200 - 0,2.2 = 210,8 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{34,8}{210,8}.100\%\approx16,51\%\)
