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Cho Ba(OH)2 vào muối Al sẽ có 2TH sau:
TH1: kết tủa Al(OH)3 chưa bị hòa tan
Al3+ + 3OH– → Al(OH)3↓
→ nAl(OH)3 = nAl3+ → nAl(OH)3 = xn + 0,04n
TH2: kết tủa Al(OH)3 bị hòa tan một phần
Al3+ + 3OH– → Al(OH)3↓
(xn + 0,04n)→ 3(xn + 0,04n) (xn + 0,04n)
Al(OH)3 + OH– → AlO2– + 2H2O
0,952 – 3(xn + 0,04n) ←0,952
→ nAl(OH)3 = 4xn + 0,16n – 0,952
a) $Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
Theo PTHH : $n_{Zn} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$
$m_{Zn} = 0,2.65 = 13(gam)$
$m_{ZnO} = 21,1 - 13 = 8,1(gam)$
c) $n_{ZnO} = 0,1(mol)$
Theo PTHH : $n_{HCl} = 2n_{Zn} + 2n_{ZnO} = 0,6(mol)$
$m_{dd\ HCl} = \dfrac{0,6.36,5}{16,6\%} = 132(gam)$
d) $m_{dd\ sau\ pư} = 21,1 + 132 - 0,2.2 = 152,7(gam)$
$n_{ZnCl_2} = n_{Zn} + n_{ZnO} = 0,3(mol)$
$C\%_{ZnCl_2} = \dfrac{0,3.136}{152,7}.100\% = 26,72\%$
\(m_{ct}=\dfrac{19,6.200}{100}=39,2\left(g\right)\)
\(n_{H2SO4}=\dfrac{39,2}{98}=0,4\left(mol\right)\)
\(m_{ct}=\dfrac{5,2.200}{100}=10,4\left(g\right)\)
\(n_{BaCl2}=\dfrac{10,4}{208}=0,05\left(mol\right)\)
Pt : \(H_2SO_4+BaCl_2\rightarrow2HCl+BaSO_4|\)
1 1 2 1
0,4 0,05 0,1 0,05
a) Lập tỉ số so sánh: \(\dfrac{0,4}{1}>\dfrac{0,05}{1}\)
⇒ H2SO4 dư , BaCl2 phản ứng hết
⇒ Tính toán dựa vào số mol của BaCl2
\(n_{BaSO4}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
⇒ \(m_{BaSO4}=0,05.233=11,65\left(g\right)\)
b) \(n_{HCl}=\dfrac{0,05.2}{1}=0,1\left(mol\right)\)
⇒ \(m_{HCl}=0,1.36,5=3,65\left(g\right)\)
\(n_{H2SO4\left(dư\right)}=0,4-0,05=0,35\left(mol\right)\)
⇒ \(m_{H2SO4\left(dư\right)}=0,35.98=34,3\left(g\right)\)
\(m_{ddspu}=200+200-11,65=388,35\left(g\right)\)
\(C_{ddHCl}=\dfrac{3,65.100}{388,35}=0,94\)0/0
\(C_{ddH2SO4\left(dư\right)}=\dfrac{34,3.100}{388,35}=8,83\)0/0
Chúc bạn học tốt
\(a.n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\\ n_{BaCl_2}=\dfrac{200.5,2\%}{208}=0,05\left(mol\right)\\ BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ Vì:\dfrac{0,05}{1}< \dfrac{0,4}{1}\\ \Rightarrow H_2SO_4dư\\ n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\\ \Rightarrow m_{\downarrow}=m_{BaSO_4}=0,05.233=11,65\left(g\right)\\ b.m_{ddsau}=200+200-11,65=388,35\left(g\right)\\ C\%_{ddHCl}=\dfrac{0,05.2.36,5}{388,35}.100\approx0,94\%\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{\left(0,4-0,05\right).98}{388,35}.100\approx8,832\%\)
PT: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
a, Giả sử: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)
⇒ 24x + 27y = 12,6 (1)
Ta có: \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Mg}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y\left(mol\right)\)
\(\Rightarrow x+\dfrac{3}{2}y=0,6\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MG}=\dfrac{0,3.24}{12,6}.100\%\approx57,1\%\\\%m_{Al}\approx42,9\%\end{matrix}\right.\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{H_2SO_4}=n_{H_2}=0,6\left(mol\right)\\n_{MgSO_4}=n_{Mg}=0,3\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{H_2SO_4}=0,6.98=58,8\left(g\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{58,8}{14,7\%}=400\left(g\right)\)
Ta có: m dd sau pư = 12,6 + 400 - 0,6.2 = 411,4 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgSO_4}=\dfrac{0,3.120}{411,4}.100\%\approx8,75\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{411,4}.100\%\approx8,31\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,1 0,15 0 ,05 0,15
a)\(V=0,15\cdot22,4=3,36\left(l\right)\)
b)\(m_{H_2SO_4}=0,15\cdot98=14,7\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,7}{9,8}\cdot100=150\left(g\right)\)
c) \(m_{H_2}=0,15\cdot2=0,3\left(g\right)\)
\(m_{ddsau}=2,7+150-0,3=152,4\left(g\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0,05\cdot342=17,1\left(g\right)\)
\(\Rightarrow C\%=\dfrac{17,1}{152,4}\cdot100=11,22\%\)
Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)
\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Dung dịch A gồm: CuSO4 và H2SO4 dư
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?
\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,3mol 0,6mol 0,3mol
\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)
