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Ta có: \(n_{Al}=\dfrac{4,86}{27}=0,18\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
a, \(n_{HCl}=3n_{Al}=0,54\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,54}{0,15}=3,6\left(M\right)\)
b, \(n_{AlCl_3}=n_{Al}=0,18\left(mol\right)\Rightarrow m_{AlCl_3}=0,18.133,5=24,03\left(g\right)\)
c, \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,27\left(mol\right)\Rightarrow V_{H_2}=0,27.24,79=6,6933\left(l\right)\)
a) PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b) Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) \(\Rightarrow n_{HCl}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{HCl}=\dfrac{0,3\cdot36,5}{100}\cdot100\%=10,95\%\)
c+d) Theo PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,3\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddHCl}-m_{H_2}=104,8\left(g\right)\)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{26,7}{104,8}\cdot100\%\approx25,48\%\)
\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\\ a,m_{AlCl_3}=133,5.0,1=13,35\left(g\right)\\ n_{H_2}=\dfrac{3}{2}.0,1=0,15\left(mol\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,n_{HCl}=\dfrac{6}{2}.0,1=0,3\left(mol\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
Ta có: \(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
a, Theo PT: \(n_{H_2\left(LT\right)}=\dfrac{3}{2}n_{Al}=0,15\left(mol\right)\)
\(\Rightarrow V_{H_2\left(LT\right)}=0,15.24,79=3,7185\left(l\right)\)
\(\Rightarrow H=\dfrac{V_{H_2\left(TT\right)}}{V_{H_2\left(LT\right)}}.100\%=\dfrac{2,479}{3,7185}.100\%\approx66,67\%\)
b, \(n_{HCl}=\dfrac{6}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{n_{HCl}}{C_{M_{HCl}}}=\dfrac{0,3}{1,5}=0,2\left(l\right)\)
c, \(n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=n_{AlCl_3}.M_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
a) Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,6mol\) \(\Rightarrow m_{HCl}=0,6\cdot36,5=21,9\left(g\right)\)
b) Theo PTHH: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3mol\)
\(\Rightarrow V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\)
c)
+) Cách 1:
Theo PTHH: \(n_{AlCl_3}=n_{Al}=0,2mol\) \(\Rightarrow m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\)
+) Cách 2:
Ta có: \(m_{H_2}=0,3\cdot2=0,6\left(g\right)\)
Bảo toàn khối lượng: \(m_{AlCl_3}=m_{Al}+m_{HCl}-m_{H_2}=26,7\left(g\right)\)
a, \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
\(m_{HCl}=109,5.10\%=10,95\left(g\right)\Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)
PTHH: 2Al + 6HCl → 2AlCl3 + 3H2
Mol: 0,1 0,3 0,1 0,15
Ta có: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) ⇒ Al hết, HCl hết
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\)
b, \(m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\)
c, mdd sau pứ = 2,7 + 109,5 - 0,15.2 = 111,9 (g)
\(C\%_{ddAlCl_3}=\dfrac{13,35.100\%}{111,9}=11,93\%\)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\n_{HCl}=\dfrac{109,5\cdot10\%}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{2}=\dfrac{0,3}{6}\) \(\Rightarrow\) Al và HCl đều p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{AlCl_3}=0,1\left(mol\right)\\n_{H_2}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{AlCl_3}=0,1\cdot133,5=13,35\left(g\right)\\V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\m_{H_2}=0,15\cdot2=0,3\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Al}+m_{ddHCl}-m_{H_2}=111,9\left(g\right)\)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{13,35}{111,9}\cdot100\%\approx11,93\%\)
nAl = \(\frac{4,05}{27}=0,15mol\)
2Al + 6HCl ----> 2AlCl3 + 3 H2
0,15 0,45 0,15 0,225 (mol)
a) nHCl = 0,45 mol
=> mHCl = 0,45 . 36,5 = 16,425 g
b) nAlCl3 = 0,15 mol
=> mAlCl3 = 0,15 . 133,5 = 20,025 g
c) nH2 = 0,225 mol
=> mH2 = 0,225 . 2 = 0,45 g
=> VH2 = 0,225 . 22,4 = 5,04 lit
Nếu đề cho thể tích sau pư thay đổi không đáng kể thì đó chính là thể tích dd AlCl3 luôn bạn nhé. Còn nếu đề không cho thì ta cũng thường lấy như vậy luôn.