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\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\
pthh:Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(V_{H_2}=0,1.22,4=2,24\left(l\right)\\
m_{HCl}=\dfrac{\left(0,2.36,5\right).100}{24,5}=29,795\left(g\right)\\
m_{\text{dd}}=5,6+29,795-\left(0,1.2\right)=35,195\left(g\right)\\
C\%=\dfrac{0,1.127}{35,195}.100\%=36\%\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1---->0,1----------------->0,1
=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\end{matrix}\right.\)
PTHH: CuO + H2 --to--> Cu + H2O
LTL: 0,25 > 0,1 => CuO dư
Theo pthh: nCu = nH2 = 0,1 (mol)
=> mCu = 0,1.64 = 6,4 (g)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,2
\(V_{H_2}=0,2.22,4=4,48l\\
C_M=\dfrac{0,2}{0,2}=1M\\
n_{CuO}=\dfrac{20}{80}=0,25\left(G\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:0,25>0,1\)
=>CuO dư
\(n_{Cu}=n_{H_2}=0,1\left(mol\right)\\
m_{Cu}=0,1.64=6,4g\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
n H2 = n Fe = 11,2/56 = 0,2(mol)
V H2 = 0,2.22,4 = 4,48(lít)
b)
n HCl = 2n Fe = 0,2.2 = 0,4(mol)
=> CM HCl = 0,4/0,4 = 1M
c)
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
Ta thấy :
n CuO = 64/80 = 0,8 > n H2 = 0,2 nên CuO dư
Theo PTHH :
n CuO pư = n Cu = n H2 = 0,2(mol)
n Cu dư = 0,8 - 0,2 = 0,6(mol)
Vậy :
%m Cu = 0,2.64/(0,2.64 + 0,6.80) .100% = 21,05%
%m CuO = 100% -21,05% = 78,95%
\(n_K=\dfrac{39}{39}=1\left(mol\right)\\ 2K+2H_2O\rightarrow2KOH+H_2\\ n_{H_2}=\dfrac{1}{2}=0,5\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,5.22,4=11,2\left(l\right)\\ b,n_{KOH}=n_K=1\left(mol\right)\\ C_{MddKOH}=\dfrac{1}{0,2}=5\left(M\right)\\ c,2H_2+O_2\rightarrow\left(t^o\right)2H_2O\\ n_{O_2}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\)
a,\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1--------------->0,1------>0,1
b, => \(\left\{{}\begin{matrix}C_{M\left(ZnCl_2\right)}=\dfrac{0,1}{\dfrac{6}{1000}}=\dfrac{50}{3}M\\V_{H_2}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)
c, \(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
LTL: \(\dfrac{0,1}{2}< 0,1\)=> O2 dư
Theo pt: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\left(0,1-0,05\right).32=1,6\left(g\right)\\V_{O_2\left(dư\right)}=\left(0,1-0,05\right).22,4=1,12\left(l\right)\end{matrix}\right.\)
\(a) Fe + 2HCl \to FeCl_2 + H_2\\ n_{FeCl_2} = n_{H_2} = n_{Fe} = \dfrac{5,6}{56} = 0,1(mol)\\ V_{H_2} = 0,1.22,4 = 2,24(lít)\\ b)m_{FeCl_2} = 0,1.127 = 12,7(gam)\\ c) n_{HCl} =2 n_{Fe} = 0,2(mol)\\ C_{M_{HCl}} = \dfrac{0,2}{0,2} = 1M\)
1) 50ml=0,05(l)
200ml=0,2(l)
0,05(l)\(_{dd}HNO_3\) \(\underrightarrow{ }8\left(M\right)\)
0,2(l)\(_{dd}HNO_3\left(lo\text{ã}ng\right)\underrightarrow{ }?\)
\(C_{M\left(HNO_3\right)\left(lo\text{ã}ng\right)}=\dfrac{0,2.8}{0,05}=32\left(M\right)\)
2) \(n_{CuSO_4}=\dfrac{m}{M}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(V_{dd\left(CuSO_4\right)}=20\left(ml\right)=0,02\left(l\right)\)
\(C_{M\left(CuSO_4\right)}=\dfrac{n}{V_{dd}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
3) \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(Fe+2HCl\underrightarrow{ }FeCl_2+H_2\)
mol 1 2 1 1
mol 0,1 0,2 0,1 0,1
a)\(V_{H_2}=n.22,4=0,1.22,4=2,24\left(l\right)\)
b) \(m_{FeCl_2}=n.M=0,1.127=12,7\left(g\right)\)
\(n_{CuO}=\dfrac{m}{M}=\dfrac{8}{80}=0,1\left(mol\right)\)
c) \(H_2+CuO\underrightarrow{t^0}Cu+H_2O\)
mol 1 1 1 1
mol 0,1 0,1 0,1 0,1
\(m_{Cu}=n.M=0,1.64=6,4\left(g\right)\)