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\(a.\\ C\%_{sau}=\dfrac{5}{100}=\dfrac{32.0,1}{32+m_{H_2O}}\\ m_{H_2O}=32\left(g\right)\\ b.\\ C_{M\left(sau\right)}=1=\dfrac{0,2.2}{0,2+V_{H_2O}}\\ V_{H_2O}=0,2\left(L\right)=200\left(mL\right)\)
Áp dụng sơ đồ đường chéo, ta có:
\(\dfrac{V_{ddKOH\left(0,5M\right)}}{V_{ddKOH\left(3M\right)}}=\dfrac{3-2}{2-0,5}=\dfrac{2}{3}\\ \rightarrow V_{ddKOH\left(0,5M\right)}=\dfrac{2}{3}.150=100\left(ml\right)\)
`n_[KOH]=0,4.4=1,6(mol)`
`V_[KOH]=[1,6]/[3,2]=0,5(l)=500(ml)`
`=>V_[H_2 O]=500-400=100(mol)`
a, \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
\(m_{CuCl_2}=270.10\%=27\left(g\right)\Rightarrow n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\)
Ta có: \(\dfrac{0,15}{1}< \dfrac{0,2}{1}\) ⇒ Fe hết, CuCl2 dư
PTHH: Fe + CuCl2 ---> FeCl2 + Cu
Mol: 0,15 0,15 0,15 0,15
\(a=m_{Cu}=0,15.64=9,6\left(g\right)\)
b, \(m_{dd.sau.pứ}=8,4+270-9,6=268,8\left(g\right)\)
\(m_{CuCl_2dư}=\left(0,2-0,15\right).135=6,75\left(g\right)\)
\(\left\{{}\begin{matrix}C\%_{CuCl_2dư}=\dfrac{6,75.100\%}{268,8}=2,51\%\\C\%_{FeCl_2}=\dfrac{0,15.127.100\%}{268,8}=7,09\%\end{matrix}\right.\)
c, \(V_{ddCuCl_2}=\dfrac{270}{1,35}=200\left(ml\right)=0,2\left(l\right)\)
\(\left\{{}\begin{matrix}C_{M_{CuCl_2dư}}=\dfrac{0,2-0,15}{0,2}=0,25M\\C_{M_{FeCl_2}}=\dfrac{0,15}{0,2}=0,75M\end{matrix}\right.\)
Bài 1:
Ta có: \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
BTNT H, có: \(n_{HCl}=2n_{H_2O}\Rightarrow n_{H_2O}=0,05\left(mol\right)\)
Theo ĐL BTKL, có: m oxit + mHCl = mmuối + mH2O
⇒ mmuối = 2,8 + 0,1.36,5 - 0,05.18 = 5,55 (g)
Bài 2:
\(m_{KOH}=200.5,6\%=11,2\left(g\right)\Rightarrow n_{KOH}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(2KOH+CuCl_2\rightarrow2KCl+Cu\left(OH\right)_2\)
Theo PT: \(n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
\(m_{CuCl_2}=\dfrac{270\cdot10\%}{100\%}=27g\Rightarrow n_{CuCl_2}=0,2mol\)
\(Fe+CuCl_2\rightarrow FeCl_2+Cu\)
0,15 0,2 0,15 0,15
\(a=m_{Cu}=0,15\cdot64=9,6g\)
\(m_{FeCl_2}=0,15\cdot127=19,05g\)
\(m_{ddFeCl_2}=8,4+270-0,15\cdot64=268,8g\)
\(C\%=\dfrac{19,05}{268,8}\cdot100\%=7,09\%\)
\(n_{NaCl}=4.0,4=1,6mol\)
\(V_{NaCl}=\dfrac{1,6}{3,2}=0,5l=500ml\)
\(V_{H_2O}=500-400=100ml\)
\(m_{CuCl_2}=0,5.135=67,5\left(g\right)\\ C\%_{CuCl_2}=\dfrac{67,5}{542}.100\%=12,45\%\)
Ta có: nCuCl2 (4M) = 0,22.4 = 0,88 (mol)
Gọi: VCuCl2 (1,2M) = a (l)
⇒ nCuCl2 (1,2M) = 1,2a (mol)
\(\Rightarrow\dfrac{0,88+1,2a}{0,22+a}=2\)
⇒ a = 0,55 (l) = 550 (ml)