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\(n_{O_2}=\dfrac{16.8}{22.4}=0.75\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(1.5..............................................0.75\)
\(m_{KMnO_4}=1.5\cdot158=237\left(g\right)\)
\(n_{O_2}=\frac{6,72}{22,4}=0,3\left(mol\right)\\ PTHH:KClO_3\underrightarrow{t^o}KCl+\frac{3}{2}O_2\\ \left(mol\right)--0,2------0,3--\\ m_{KClO_3}=0,2.122,5=24,5\left(g\right)\)
a) nO2= 6,72/22,4=0,3(mol)
PTHH: 2 KClO3 -to-> 2 KCl + 3 O2
b) nKClO3= 2/3. nO2= 2/3. 0,3=0,2(mol)
=> mKClO3=122,5.0,2= 24,5(g)
nFe(Fe2O3)=0.1.2=0.2mol
nFe trc pứ=0.2+0.2=0.4mol
nFe[Fe2(SO4)3]=nFe trc pứ=0.4mol
=>nFe(SO4)3=0.4/2=0.2mol
mFe2(SO4)3=400.0.2=80g.
Vậy m=80g.
1.
2Fe + 6H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3SO2 + 6H2O (1)
Fe + 3H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3H2O (2)
Theo PTHH 1 ta có:
\(\dfrac{3}{2}\)nFe=nSO2=0,3(mol)
VSO2=22,4.0,3=6,72(lít)
2.
2Fe + 6H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3SO2 + 6H2O (1)
Fe2O3 + 3H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3H2O (2)
Theo PTHH 1 và 2 ta có:
\(\dfrac{1}{2}\)nFe=nFe2(SO4)3=0,1(mol)
nFe2O3=nFe2(SO4)3=0,1(mol)
mmuối=0,2.400=80(g)
\(n_{O_2} = \dfrac{0,72}{22,4} = \dfrac{9}{280}(mol)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = \dfrac{9}{140}(mol)\\ m_{KMnO_4} = \dfrac{9}{140}.158 = 10,16(gam)\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = \dfrac{3}{140}(mol)\\ m_{KClO_3} = \dfrac{3}{140}.122,5 = 2,625(gam)\)
\(n_{O_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.6..............................................0.3\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(0.2..........................0.3\)
\(m_{KMnO_4}=0.6\cdot158=94.8\left(g\right)\)
\(m_{KClO_3}=0.2\cdot122.5=24.5\left(g\right)\)
nFe(Fe2O3)=0.1.2=0.2mol
nFe trc pứ=0.2+0.2=0.4mol
nFe[Fe2(SO4)3]=nFe trc pứ=0.4mol
=>nFe(SO4)3=0.4/2=0.2mol
mFe2(SO4)3=400.0.2=80g.
Vậy m=80g.
a ) Fe3O4 + 4H2 \(\rightarrow\) 3Fe + 4H2O
b) \(nFe_3O_4=\frac{4,64}{232}=0,02\left(mol\right)\)
Theo PTHH \(nH_2=4nFe_3O_4=4\cdot0,02=0,08\left(mol\right)\)
\(\Rightarrow V_{H2}=0,08\cdot22,4=1,792\left(l\right)=1792\left(ml\right)\)
c)
Fe3O4 + 4CO \(\rightarrow\) 3Fe + 4CO2
...0,02.........0,08
\(V_{CO}=1792\left(ml\right)\)
m(rắn k tan)= mCu=1(g)
=> m(Fe,Al)= 16,4(g)
nH2SO4=(39,2%.100)/98=0,4(mol)
Đặt: nFe=a(mol); nAl=b(mol)
PTHH: Fe+ 2 HCl -> FeCl2 + H2
a_______2a_____a____a(mol)
2 Al + 6 HCl -> 2 AlCl3 +3 H2
b__3b_______b____1,5b(mol)
Ta được hpt:
\(\left\{{}\begin{matrix}2a+3b=0,4\\56a+27b=16,4\end{matrix}\right.\) Đến lúc này em cần xem lại số liệu đề bài nhé!
\(n_{Fe}=\dfrac{33.6}{56}=0.6\left(mol\right)\)
\(Fe_3O_4+4H_2\underrightarrow{^{t^0}}3Fe+4H_2O\)
\(0.2..........0.8........0.6\)
\(m_{Fe_3O_4}=0.2\cdot232=46.4\left(g\right)\)
\(V_{H_2}=0.2\cdot22.4=17.92\left(l\right)\)
n Fe = 33,6.56 = 0,6(mol)
$Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O$
Theo PTHH :
n H2 = 4/3 n Fe = 0,8(mol) => V H2 = 0,8.22,4 = 17,92 lít
n Fe3O4 = 1/3 n Fe = 0,2(mol) => m Fe3O4 = 0,2.232 = 46,4 gam