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a)
$CuO + H_2SO_4 \to CuSO_4 + H_2O$
$n_{H_2SO_4} = n_{CuO} = \dfrac{1,6}{80} = 0,02(mol)$
$C\%_{H_2SO_4} = \dfrac{0,02.98}{100}.100\% = 1,96\%$
b)
$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{NaOH} = 2n_{H_2SO_4} = 0,04(mol)$
$m_{NaOH} = 0,04.40 = 1,6(gam)$
c)
$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + 2H_2O$
Cu dư nên $n_{SO_2} = \dfrac{1}{2}n_{H_2SO_4} = 0,05(mol)$
$V_{SO_2} = 0,05.22,4 = 1,12(lít)$
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ ..........0,15.......0,15.......0,15.......0,15\left(mol\right)\)
\(m_{Zn}=65\cdot0,15=9,75\left(g\right)\)
\(b,m_{H_2SO_4}=98\cdot0,15=14,7\left(mol\right)\\ c,m_{dd_{H_2SO_4}}=\dfrac{14,7\cdot100}{20}=\dfrac{147}{2}\left(g\right)\\ d,C\%_{dd_{ZnSO_4}}=\dfrac{0,15\cdot161}{\dfrac{147}{2}}\cdot100\approx32,86\%\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 0,2 0,2
\(a,\%m_{Fe}=\dfrac{0,2.56}{20}.100\%=56\%\)
\(\%m_{Cu}=100\%-56\%=44\%\)
\(b,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(1\) \(1\) \(1\)
\(0,2\) \(0,2\) \(0,2\)
\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(m_{Fe}=n.M=0,2.56=11,2\left(g\right)\)
\(^0/_0Fe=\dfrac{11,2}{20}.100^0/_0=56^0/_0\)
\(^0/_0Cu=100^0/_0-56^0/_0=44^0/_0\)
\(C_{M_{H_2SO_4}}=\dfrac{n}{V_{dd}}=\dfrac{0,2}{0,1}=2M\)
nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
nNa2O = 0,125 mol
a. Na2O + H2O --------> NaOH
0,125 mol ----------------> 0,125 mol
--> CM(NaOH) n/V = 0,125/ 0,25 = 0,5 M
b. H2SO4 + 2NaOH ------> Na2SO4 + H2O
....0,0625 <---0,125 mol
--> mH2SO4(nguyên chất) = 0,0625*98 = 6,125 g
--> mH2SO4(20%) = 6,125/20% = 30,625 g
suy ra V = m/D = 30,625 / 1,14 = 26,86 ml
Câu 1 :
Gọi $n_{SO_3} = a(mol)$
$SO_3 + H_2O \to H_2SO_4$
Sau khi pha :
$m_{dd} = 80a + 200(gam)$
$m_{H_2SO_4} = 98a + 200.9,8\% = 98a + 19,6(gam)$
Suy ra : $C\%_{H_2SO_4} = \dfrac{98a + 19,6}{200 + 80a}.100\% = 49\%$
$\Rightarrow a = 1,333(mol)$
$m_{SO_3} = 1,333.80 = 106,64(gam)$
Gọi $m_{oleum} = a(gam) ; m_{H_2SO_4} = b(gam)$
Ta có :
Sau khi trộn :
$m_{oleum} = a + b(gam)$
$m_{SO_3} = a.71\% = 0,71a(gam)$
$\Rightarrow \%SO_3 = \dfrac{0,71a}{a + b}.100\% = 62\%$
$\Rightarrow a + b = 0,4402a$
$\Rightarrow \dfrac{a}{b} = \dfrac{1}{1 - 0,4402} = 1,78$
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + H2SO4 → FeSO4 + H2
Mol: 0,1 0,1
\(C\%_{ddH_2SO_4}=\dfrac{0,1.98.100\%}{100}=9,8\%\)
