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\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
\(a,n_{Zn}=\dfrac{0,65}{65}=0,01(mol)\\ n_{HCl}=\dfrac{7,3}{36,5}=0,2(mol)\\ PTHH:Zn+2HCl\to ZnCl_2+H_2\)
Vì \(\dfrac{n_{Zn}}{1}<\dfrac{n_{HCl}}{2}\) nên \(HCl\) dư
\(\Rightarrow n_{HCl(dư)}=0,2-0,02=0,18(mol)\\ \Rightarrow m_{HCl(dư)}=0,18.36,5=6,57(g)\\ b,n_{H_2}=n_{Zn}=0,01(mol)\\ \Rightarrow V_{H_2}=0,01.22,4=0,224(l)\)
\(n_{Al}=\frac{2,7}{27}=o,1mol\)
n HCl = o,2 mol
2 Al +6 HCl →2AlCl3 + 3H2
bđ: 0,1
đang bận !
nFe = 2.8/56 = 0.05 (mol)
nHCl = 14.6/36.5 = 0.4 (mol)
Fe + 2HCl => FeCl2 + H2
1.........2
0.05......0.4
LTL : 0.05/1 < 0.4/2
=> HCl dư
mHCl (dư) = ( 0.4 - 0.1 ) * 36.5 = 10.95 (g)
VH2 = 0.05*22.4 = 1.12 (l)
nHCl (dư) = 0.4 - 0.1 = 0.3 (mol)
mFe cần thêm = 0.3/2 * 56 = 8.4 (g)
mFe= 8,4/56= 0,15 mol
m HCl = 14,6/36,5=0,4 mol
PTHH: Fe +2HCl →FeCl2 +H2
Bđ: 0,15 0,4 0 0 mol
Pứ: o,15→0,3 0,15 0,15 mol
Sau pứ:0 0,1 0,15 0,15 mol
a. HCl dư: m =0,1.36,5=3,65 g
b. m FeCl2 = 0,15.127=19,05 g
c. m H2 = 0,15.2= 0,3 g
V H2= 0,15.22,4=3,36 (l)
nZn = 0.65 / 65 = 0.01 (mol)
Zn + 2HCl => ZnCl2 + H2
0.01..................0.01......0.01
mZnCl2 = 0.01 * 136 = 1.36 (g)
VH2 = 0.01 * 22.4 = 0.224 (l)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right);n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,6}{2}\Rightarrow Zn.dư\\ n_{H_2}=n_{Zn\left(p.ứ\right)}=\dfrac{0,6}{2}=0,3\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ b,n_{Zn\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\Rightarrow m_{Zn\left(dư\right)}=0,1.65=6,5\left(g\right)\)
`n_(Zn)=m/M=(26)/65=0,4(mol)`
`n_(HCl)=m/M=(21,9)/36,5=0,6(mol)`
`PTHH:Zn+2HCl->ZnCl_2 +H_2`
tỉ lệ: 1 ; 2 : 1 : 1
n(mol) 0,3<----0,6---->0,3----->0,3
\(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\left(\dfrac{0,4}{1}>\dfrac{0,6}{2}\right)\)
`=>` `Zn` dư, `HCl` hết, tính theo `HCl`
`V_(H_2)=n*22,4=0,3*22,4=6,72(l)`
`n_(Zn(dư))=0,4-0,3=0,1(mol)`
`m_(Zn(dư))=n*M=0,1*65=6,5(g)`
a, Ta có: \(n_{Zn}=\dfrac{0,65}{65}=0,01\left(mol\right)\)
\(n_{HCl}=\dfrac{2,3}{36,5}=\dfrac{23}{365}\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,01}{1}< \dfrac{\dfrac{23}{365}}{2}\), ta được HCl dư.
Theo PT: \(n_{HCl\left(pư\right)}=2n_{Zn}=0,02\left(mol\right)\)
\(\Rightarrow n_{HCl\left(dư\right)}=\dfrac{23}{365}-0,02=\dfrac{157}{3650}\left(mol\right)\)
\(\Rightarrow m_{HCl\left(dư\right)}=\dfrac{157}{3650}.36,5=1,57\left(g\right)\)
b, Theo PT: \(n_{H_2}=n_{Zn}=0,01\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,01.22,4=0,224\left(l\right)\)
nZn=0.01 (mol)
nHCL=0.06 (mol)
pthh: Zn + 2HCL -> ZnCL2 +H2
PT: 1 2 1 1
ĐB: 0.01 0.06 / /
pứ: 0.01 0.02 0.01 0.01
spu: 0 0.04 0.01 0.01
a)vậy chất dư spu là HCL
-> mHCL = 1.46 (g)
b) V H2 đktc = 0.224 (L)