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\(GS:n_{CaCO_3}=a\left(mol\right),n_{MgCO_3}=b\left(mol\right)\)
\(n_{CO_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
\(m_{hh}=100a+84b=13.4\left(g\right)\left(1\right)\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
\(n_{CO_2}=a+b=0.15\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.05,b=0.1\)
\(\%CaCO_3=\dfrac{0.05\cdot100}{13.4}\cdot100\%=37.31\%\)
\(\%MgCO_3=100-37.31=62.69\%\)
\(n_{HCl}=2n_{CO_2}=2\cdot0.15=0.3\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.3}{0.2}=1.5\left(M\right)\)
a. \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,25 ..... 0,5 ................... 0,25 (mol)
\(m_{Mg}=0,25.24=6\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{6}{10}.100\%=60\%\\\%m_{MgO}=100\%-60\%=40\%\end{matrix}\right.\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
0,1 ....... 0,2 (mol)
\(n_{HCl}=0,25+0,1=0,35\left(mol\right)\)
\(C_M\left(HCl\right)=\dfrac{0,35}{0,1}=3,5\left(M\right)\)
\(n_{H_2}=\dfrac{1,344}{22,4}=0,06\left(mol\right)\) \(n_{H_2SO_4}=0,3.0,25=0,075\left(mol\right)\)
\(X+H_2SO_{4\left(l\right)}\rightarrow XSO_4+H_2\uparrow\)
0,06 0,06 0,06 0,06 (mol)
dư:0 0,015 0 0 (mol)
b/
m\(M_X=\dfrac{3,36}{0,06}=56\left(g\right)\)
\(\rightarrow Fe\)
c/
\(2Fe+6H_2SO_{4\left(đn\right)}\rightarrow Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
0,06 0,09 (mol)
V\(_{SO_2}=0,09.22,4=2,016\left(l\right)\)
a)
2A+2H2O\(\rightarrow\)2AOH+H2
nH2=\(\frac{1,68}{22,4}\)=0,075(mol)
\(\rightarrow\)nA=0,075.2=0,15(mol)
MA=\(\frac{5,05}{0,15}\)=33,6
\(\rightarrow\)2 kim loại là Na và K
b)
mdd spu=5,05+95,1-0,075.2=100(g)
Gọi a là số mol Na b là số mol K
Ta có
\(\left\{{}\begin{matrix}\text{23a+39b=5,05}\\\text{a+b=0,15}\end{matrix}\right.\rightarrow\left\{{}\begin{matrix}\text{a=0,05}\\b=0,1\end{matrix}\right.\)
C%NaOH=\(\frac{\text{0,05.40}}{100}.100\%\)=2%
C%KOH=\(\frac{\text{0,1.56}}{100}.100\%\)=5,6%
Gọi V là thể tích dd B
Ta có
V+2.0,5V=0,05+0,1
\(\rightarrow\)V=0,075(l)=75 ml
1.
2M + 2xHCl \(\rightarrow\)2MClx + xH2
nH2=\(\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PTHH ta có:
nM=\(\dfrac{2}{x}\)nH2=\(\dfrac{0,6}{x}\)
MM=\(\dfrac{5,4}{\dfrac{0,6}{x}}=9x\)
Với x=3 thì MM=27
Vậy M là Al
Mg + 2 H2SO4 (đ) -to-> MgSO4 + SO2 + 2 H2O
x_________2x__________________x(mol)
2 Fe + 6 H2SO4(đ) -to-> Fe2(SO4)3 + 3 SO2 + 6 H2O
y______3y_____________________1,5y(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}24x+56y=18,4\\x+1,5y=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)
=> mMg= 0,3.24=7,2(g)
=> %mMg= (7,2/18,4).100=39,13%
=>%mFe= 60,87%
b) nH2SO4(tổng)=2x+3y=2.0,3+3.0,2=1,2(mol)
VddH2SO4=1,2/2=0,6(l)
a) Đặt \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow56a+24b=18,4\) (1)
Ta có: \(n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Bảo toàn electron: \(3a+2b=0,6\cdot2\) (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2\cdot56}{18,4}\cdot100\%\approx60,87\%\\\%m_{Mg}=39,13\%\end{matrix}\right.\)
b) Ta có: \(\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Fe}=0,1\left(mol\right)\\n_{MgSO_4}=n_{Mg}=0,3\left(mol\right)\end{matrix}\right.\)
Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{SO_2}+3n_{Fe_2\left(SO_4\right)_3}+n_{MgSO_4}=1,2\left(mol\right)\)
\(\Rightarrow V_{H_2SO_4}=\dfrac{1,2}{2}=0,6\left(l\right)=600\left(ml\right)\)
Goi M la nguyen tu khoi trung binh cua A va B
2M + 2H2O--> 2MOH+ H2
0,3 mol <-- 0,15 mol
MM=11,2/0,3=37,3
Na<37,3<K
2Na + 2H2O --> 2NaOH + H2
x mol 1/2x mol
2K + 2H2O --> 2KOH + H2
y mol 1/2y mol
23x + 39y=11,2
1/2x+1/2y=0,15
x=1/32 y=43/160
Co duoc so mol cua Na va K ta tinh duoc cau a va cau b