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`Fe + H_2 SO_4 -> FeSO_4 + H_2`
`0,25` `0,25` `0,25` `(mol)`
`a)n_[Fe]=[22,4]/56=0,4(mol)`
`n_[H_2 SO_4]=[24,5]/98=0,25(mol)`
Có: `[0,4]/1 > [0,25]/1=>Fe` hết, `H_2 SO_4`
`=>m_[Fe(dư)]=(0,4-0,25).56=8,4(g)`
`b)V_[H_2]=0,25.22,4=5,6(l)`
Ko được ghi `Fe+H_2 SO_4->Fe_2 (SO_4)_3+H_2` vì đây là `H_2 SO_4` loãng
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right);n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\ PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,25}{1}\Rightarrow Fe.dư\\ n_{H_2}=n_{Fe\left(p.ứ\right)}=n_{H_2SO_4}=0,25\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b,n_{Fe\left(dư\right)}=0,4-0,25=0,15\left(g\right)\\ m_{Fe\left(dư\right)}=0,14.56=8,4\left(g\right)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\
n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\
pthh:Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(LTL:\dfrac{0,2}{1}< \dfrac{0,25}{1}\)
=> H2SO4 dư
\(n_{H_2}=n_{H_2SO_4\left(p\text{ư}\right)}=n_{Fe}=0,2\left(mol\right)\\
V_{H_2}=0,2.22,4=4,48l\\
m_{H_2SO_4\left(d\right)}=\left(0,25-0,2\right).98=4,9g\)
nFe=11,2/56=0,2 mol
nH2SO4=24,5/98=0,25
PTPƯ: Fe + H2SO4 ---> FeSO4 + H2
0,2 mol ----> 0,2 mol --------------------> 0,2 mol
Ta có Fe:H2SO4=0,2/1<0,25/1 (nên H2SO4 dư)
a, mH2SO4=(0,25-0,2).98=4,9 g
b, VH2=0,2.22,4=4,48 l
PTHH: \(Fe+H_2SO_{4\left(l\right)}\rightarrow FeSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Sắt còn dư, Axit p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,25\left(mol\right)\\n_{Fe\left(dư\right)}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,25\cdot22,4=5,6\left(l\right)\\m_{Fe\left(dư\right)}=0,15\cdot56=8,4\left(g\right)\end{matrix}\right.\)
Gọi x, y lần lượt là số mol Al, Fe
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ n_{H_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\\ Tacó:\left\{{}\begin{matrix}27x+56y=0,83\\1,5x+y=0,025\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,01\\y=0,01\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=0,27\left(g\right)\\m_{Fe}=0,56\left(g\right)\end{matrix}\right.\)
\(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{11,2}{65}=0,1723mol\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,1723 0,1723 ( mol )
\(V_{H_2}=n_{H_2}.22,4=0,1723.22,4=3,85952l=38595,21ml\)
a)\(n_{Fe}=\dfrac{44,8}{56}=0,8mol\)
\(n_{H_2SO_4}=\dfrac{49}{98}=0,5mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
0,8 0,5 0,5 0,5
b)\(V_{H_2}=0,5\cdot22,4=11,2l\)
c)\(CuO+H_2\rightarrow Cu+H_2O\)
0,5 0,5 0,5
\(m_{CuO}=0,5\cdot80=40g\)
nH2SO4= 0,125(mol)
nFe=0,2(mol)
PTHH: Fe + H2SO4 -> FeSO4 + H2
Vì: 0,125/1 < 0,2/1
=> Fe dư, H2SO4 hết, tính theo nH2SO4
-> nH2=nH2SO4=0,125(mol)
=>V(H2,đktc)=0,125.22,4=2,8(l)