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PTHH: 2Na + 2H2O --> H2 + 2NaOH
Na2O + H2O -> 2NaOH
Ta có: nH2= \(\dfrac{3,36}{22,4}\) = 0,15(mol)
Theo pthh(1) ta có: nNa = 2nH2= 0,3(mol)
=> mNa = 0,323=6,9(g)
ta có: mNa2O= 13,1-6,9= 6,2(g)
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
Do HNO3 nóng dư nên Fe, Cu pứ hết --> Fe3+ & Cu2+
M(B) = 36 --> nNO : nNO2 = 5:3
Khi cho đ sau pứ tác dụng vs NH3 dư thì --> Fe(OH)3 ko tan, Cu(NH3)4(OH)2 tan
--> Chất rắn sau nung: Fe2O3: n = 0,05 --> nFe = 0,1 -->mFe = 5,6, mCu = 6,4g
Từ nFe, nCu, bảo toàn electron --> nNO, nNO2 --> V
c, Dung dịch kiềm> Vì trong dd D có NH4NHO3, nên cho kiềm vào sẽ sinh ra NH3.
2Na+2H2O->2NaOH+H2
0,5-----0,5-----------0,5----0,25
Na2O+H2O->2NaOH
0,1--------0,1-----------0,2
n H2=0,25 mol
=>m Na =0,5.23=11,5g
=>m Na2O=6,2g=>n Na2O=0,1 mol
=>m NaOH=0,7.40=28g
=>VH2O=0,6.22,4=13,44l
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)
\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)
Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)
Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)
2Na + 2H2O ---> 2NaOH + H2 (1)
Na2O + H2O ---> 2NaOH (2)
a) nH2 = 0,3 (mol)
Theo pthh (1) : nNa = 2nH2 = 0,6 (mol)
=> mNa = 0,6.23 = 13,8 (g)
=> mNa2O = 26,2 - 13,8 = 12,4 (g)
=> nNa2O = 0,2 (mol)
BTNa : nNaOH = nNa + 2nNa2O = 0,6 + 2.0,2 = 1 (mol)
=> mNaOH = 1.40 = 40(g)
b) %mNa = 13,8.100%/26,2 = 52,67%
%mNa2O = 100% - 52,67% = 47,33%
nH2 = 2.24/22.4 = 0.1 (mol)
Na + H2O => NaOH + 1/2 H2
0.2....................0.2..........0.1
mNa = 0.2 * 23 = 4.6 (g)
mNa2O = 17 - 4.6 = 12.4 (g)
nNa2O = 12.4/62 = 0.2 (mol)
Na2O + H2O => 2NaOH
0.2........................0.4
nNaOH = 0.2 + 0.4 = 0.6 (mol)
mNaOH = 0.6 * 40 = 24 (g)
nCuO = 24/80 = 0.3 (mol)
CuO + H2 -t0-> Cu + H2O
1...........1
0.3.........0.1
LTL : 0.3/1 > 0.1/1
=> CuO dư
nCu = nH2 = 0.1 (mol)
mCu = 0.1 * 64 = 6.4 (g)
1 ) CAO +H2O => CA(OH)2 (1)
2K + 2H2O => 2KOH + H2(2)
n (H2) =1,12/22,4 =0,05
theo ptpư 2 : n(K) = 2n (h2) =2.0.05=0,1(mol)
=> m (K) =39.0,1=3,9 (g)
% K= 3,9/9,5 .100% =41,05%
%ca =100%-41,05%=58,95%
xo + 2hcl =>xcl2 +h2o
10,4/X+16 15,9/x+71
=> giải ra tìm đc X bằng bao nhiêu thì ra
a, \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Na}=2n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Na}=0,3.23=6,9\left(g\right)\)
\(\Rightarrow m_{Na_2O}=13,1-6,9=6,2\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
Theo PT: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=0,5\left(mol\right)\)
Ta có: m dd sau pư = 13,1 + 200 - 0,15.2 = 212,8 (g)
\(\Rightarrow C\%_{NaOH}=\dfrac{0,5.40}{212,8}.100\%\approx9,4\%\)