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\(n_{Al}=\dfrac{21,6}{27}=0,8\left(mol\right)\)
Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O|\)
2 3 1 3
0,8 1,2 0,4 1,2
a) \(n_{H2}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=1,2.22,4=26,88\left(l\right)\)
b) \(n_{H2SO4}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)
⇒ \(m_{H2SO4}=1,2.98=117,6\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{117,6.100}{29,4}=400\left(g\right)\)
c) \(n_{Al2\left(SO4\right)3}=\dfrac{1,2.1}{3}=0,4\left(mol\right)\)
⇒ \(m_{Al2\left(SO4\right)3}=0,4.342=136,8\left(g\right)\)
\(m_{ddspu}=21,6+400-\left(1,2.2\right)=419,2\left(g\right)\)
\(C_{Al2\left(SO4\right)3}=\dfrac{136,8.100}{419,2}=32,63\)0/0
Chúc bạn học tốt
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ PTHH:Zn+2HCl\to ZnCl_2+H_2\\ \Rightarrow n_{Zn}=n_{H_2}=0,1(mol)\\ a,\%_{Zn}=\dfrac{0,1.65}{9,7}.100\%=67,01\%\\ \Rightarrow \%_{Cu}=100\%-67,01\%=32,99\%\\ b,n_{HCl}=2n_{H_2}=0,2(mol)\\ \Rightarrow C\%_{HCl}=\dfrac{0,2.36,5}{50}.100\%=14,6\%\\ c,PTHH:Zn+H_2SO_4\to ZnSO_4+H_2\\ \Rightarrow n_{H_2SO_4}=n_{H_2}=0,1(mol)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{0,1}{0,2}=0,5(l)\)
nZn= 19,5/65=0,3(mol); nFe2O3=19,2/160=0,12(mol)
PTHH: Zn + 2 HCl -> ZnCl2 + H2
Fe2O3 + 3 H2 -to-> 2 Fe +3 H2O
nH2=nZnCl2= nZn=0,3(mol) => V(H2,đktc)=0,3.22,4= 6,72(l)
b) nHCl= 2.0,3=0,6(mol) => mHCl=0,6.36,5=21,9(g)
=>mddHCl=(21,9.100)/20=109,5(g)
=>m=109,5(g)
c) mH2=0,3.2=0,6(mol)
mddZnCl2=19,5+109,5 - 0,6= 128,4(g)
mZnCl2=0,3. 136= 40,8(g)
=>C%ddZnCl2= (40,8/128,4).100=31,776%
d) Ta có: 0,3/3 < 0,12/1
=> H2 hết, Fe2O3 dư, tính theo nH2
=> nFe= 2/3. nH2= 2/3. 0,3= 0,2(mol)
=>mFe=0,2.56=11,2(g)
a, nZn = 19,5/65=0,3 (mol)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,3 0,15 0,3 0,3
=> \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b,mHCl=0,15.36,5=5,475 (g)
=> m=mddHCl=5,475:20%=27,375 (g)
c,mdd sau pứ =19,5+27,375=46,875 (g)
\(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{46,875}.100\%=87,04\%\)
d,\(n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\)
PTHH: Fe2O3 + 3H2 → 2Fe + 3H2O
Mol: 0,3 0,2
Tỉ lệ: 0,12/1>0,3/3 ⇒ Fe2O3 dư,H2 pứ hết
=> mFe=0,2.56=11,2 (g)
a) \(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
PTHH: Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
0,2------------------>0,4---->0,2
mdd sau pư = 200 + 21,2 - 0,2.44 = 212,4(g)
=> \(C\%\left(NaCl\right)=\dfrac{0,4.58,5}{212,4}.100\%=11,017\%\)
$PTHH:Na_2CO_3+2HCl\to 2NaCl+H_2O+CO_2\uparrow$
$n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2(mol)$
Theo PT: $n_{NaCl}=n_{CO_2}=0,2(mol)$
$\Rightarrow m_{NaCl}=0,4.58,5=23,4(g);m_{CO_2}=0,2.44=8,8(g)$
$\Rightarrow C\%_{NaCl}=\dfrac{23,4}{21,2+200-8,8}.100\%\approx 11,01\%$
a, \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
\(m_{HCl}=200.14,6\%=29,2\left(g\right)\Rightarrow n_{HCl}=\dfrac{29,2}{36,5}=0,8\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,3}{1}< \dfrac{0,8}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{ZnCl_2}=n_{Zn}=0,3\left(mol\right)\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c, \(n_{HCl\left(pư\right)}=2n_{Zn}=0,6\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 19,5 + 200 - 0,3.2 = 218,9 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{218,9}.100\%\approx3,33\%\\C\%_{ZnCl_2}=\dfrac{40,8}{218,9}.100\%\approx18,64\%\end{matrix}\right.\)
\(a)n_{Zn}=\dfrac{19,5}{65}=0,3mol\\ n_{HCl}=\dfrac{200.14,6}{100.36,5}=0,8mol\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,8}{2}\Rightarrow HCl.dư\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,3mol\\ V_{H_2}=0,3.22,4=6,72l\\ b)m_{ZnCl_2}=0,3.136=40,8g\\ c)n_{HCl.pư}=0,3.2=0,6mol\\ C_{\%ZnCl_2}=\dfrac{40,8}{200+19,5-0,3.2}\cdot100=18,64\%\\ C_{\%HCl.dư}=\dfrac{\left(0,8-0,6\right).36,5}{200+19,5-0,3.2}\cdot100=3,33\%\)
a,\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)
PTHH: 2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mol: 0,1 0,15 0,05 0,15
\(m_{H_2}=0,15.2=0,3\left(g\right)\)
\(V_{H_2}=0,15.24,79=3,7185\left(l\right)\)
b, \(m_{ddH_2SO_4}=\dfrac{0,15.98.100\%}{200}=7,35\%\)
c, mdd sau pứ = 2,7 + 200 - 0,3 = 202,4 (g)
\(C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{0,05.342.100\%}{202,4}=8,45\%\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(m_{HCl}=21,9g\Rightarrow n_{HCl}=\dfrac{21,9}{36,5}=0,6\)
=> HCl dư
\(\Rightarrow n_{H_2}=0,2mol\)
\(\Rightarrow V_{H_2}=0,2.22,4=4,48l\)
bổ sung ý b)
Khối lượng dung dịch sau phản ứng = mZn + mHCl - mH2 thoát ra = 13 +150 - 0,2 .2 = 162,6 gam
Dung dịch thu được sau phản ứng gồm \(\left\{{}\begin{matrix}ZnCl_2\\HCl_{dư}\end{matrix}\right.\)
nZnCl2 = nZn = 0,2 mol => mZnCl2 = 0,2 . 136 = 27,2 gam
=> C% ZnCl2 = \(\dfrac{27,2}{162,6}\).100= 16,72%
nHCl dư = 0,6 - 0,4 = 0,2 mol
mHCl dư= 0,2.36,5 = 7,3 gam
=> C% HCl dư = \(\dfrac{7,3}{162,6}\).100 = 4,5%