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a,Fe + 2HCl → FeCl + H2 (1)
FeO + 2HCl → FeCl + H2O (2)
nH2 = 3,36/ 22,4 = 0,15 ( mol)
Theo (1) nH2 = nFe = 0,15 ( mol)
mFe = 0,15 x 56 = 8.4 (g)
m FeO = 12 - 8,4 = 3,6 (g)
a, \(n_{H_2}=\frac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl->FeCl_2+H_2\left(1\right)\)
\(FeO+2HCl->FeCl_2+H_2O\left(2\right)\)
theo (1) \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
=> \(m_{Fe}=0,15.56=8,4\left(g\right)\)
=> \(m_{FeO}=12-8,4=3,6\left(g\right)\)
ta thấy : nFe =nH2 = 0,15
=> mFe =0,15 x 56 = 8,4g
%Fe=8,4/12 x 100 = 70%
=>%FeO = 100 - 70 = 30%
b) BTKLra mdd tìm mct of HCl
c) tìm mdd sau pứ -mH2 nha bạn
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{HCl}=2n_{H_2}=0,2\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\)
\(n_{Fe}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)
\(\Rightarrow m_{Cu}=20-5,6=14,4\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{5,6}{20}.100\%=28\%\\\%m_{Cu}=72\%\end{matrix}\right.\)
Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\ m_{HCl}=200.27,375\%=54,75\left(g\right)\\ n_{HCl}=\dfrac{54,75}{36,5}=1,5\left(mol\right)\)
PTHH:
Zn + 2HCl ---> ZnCl2 + H2
a ----> 2a --------> a -----> a
Fe + 2HCl ---> FeCl2 + H2
b ---> 2b -------> b ------> b
Hệ pt \(\left\{{}\begin{matrix}65a+56b=43,7\\a+b=0,7\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Zn}=0,5.65=32,5\left(g\right)\\m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)
\(m_{dd}=43,7+200-0,7.2=242,3\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,5.136}{242,3}=28,06\%\\C\%_{FeCl_2}=\dfrac{0,2.127}{242,3}=10,48\%\\C\%_{HCl\left(dư\right)}=\dfrac{\left(1,5-0,5.2-0,2.2\right).36,5}{242,3}=1,51\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\\
pthh:\left\{{}\begin{matrix}Zn+H_2SO_4->ZnSO_4+H_2\\Fe+H_2SO_4->FeSO_{\text{ 4 }}+H_2\end{matrix}\right.\)
gọi số mol Zn là x , số mol Fe là y
=> 65x+56y=43,7
=> a+b=0,7
=>a=0,5 , b =0,2
=> \(m_{Zn}=0,5.65=32,5\\ m_{Fe}=43,7-32,5=11,2\left(G\right)\)
\(a,Đặt:n_{Mg}=g\left(mol\right);n_{Fe}=j\left(mol\right)\left(g,j>0\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ \Rightarrow\left\{{}\begin{matrix}24g=56j=9,2\\22,4g+22,4j=5,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}g=0,15\\j=0,1\end{matrix}\right.\\ \Rightarrow\%m_{Mg}=\dfrac{0,15.24}{9,2}.100\approx39,13\%\\ \Rightarrow\%m_{Fe}\approx60,87\%\\ b,n_{HCl}=2n_{H_2}=\dfrac{2.5,6}{22,4}=0,5\left(mol\right)\\ \Rightarrow C_{MddHCl}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\ c,m_{muối}=m_{FeCl_2}+m_{MgCl_2}=95g+127j=95.0,15+127.0,1=26,95\left(g\right)\)
Fe+2HCl->FeCl2+H2
x-----------------------x mol
Mg+2HCl->MgCl2+H2
y-------------------------y mol
ta có\(\left\{{}\begin{matrix}56x+24y=9,2\\x+y=0,25\end{matrix}\right.\)
=>\(\left\{{}\begin{matrix}x=0,1\\y=0,15\end{matrix}\right.\)
=>%mFe=\(\dfrac{0,1.56}{9,2}.100\)=60,87%
=>%m Mg=39,13%
Ta có : n HCl=0,1.2+0,15.2=0,5 mol
=>CMHCl=\(\dfrac{0,5}{0,2}\)=2,5M
=>m muối =0,1.127+0,15.95=26,95g
