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a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 24x + 56y = 8 (1)
Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{Mg}=x\left(mol\right)\\n_{FeCl_2}=n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 95x + 127y = 22,2 (2)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1.24}{8}.100\%=30\%\\\%m_{Fe}=70\%\end{matrix}\right.\)
b, \(n_{HCl}=2n_{Mg}+2n_{Fe}=0,4\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,4}{1}=0,4\left(l\right)\)
a,\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,4 0,2
\(\Rightarrow\%m_{Zn}=\dfrac{0,2.65.100\%}{21,1}=61,61\%;\%m_{ZnO}=100-61,61=38,39\%\)
b,\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1\left(mol\right)\)
PTHH: ZnO + 2HCl → ZnCl2 + H2O
Mol: 0,1 0,2
\(m_{ddHCl}=\dfrac{\left(0,2+0,4\right).36,5.100\%}{7,3\%}=300\left(g\right)\)
c,
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,2 0,2
PTHH: ZnO + H2SO4 → ZnSO4 + H2O
Mol: 0,1 0,1
\(n_{H_2SO_4}=0,2+0,1=0,3\left(mol\right)\Rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{0,5}=0,6\left(l\right)=600\left(ml\right)\)
\(m_{ddH_2SO_4}=600.1,12=672\left(g\right)\)
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Pt : \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2|\)
1 1 1 1
0,1 0,1 0,1
\(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O|\)
1 1 1 1
0,1 0,1
a) \(n_{Zn}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Zn}=0,1.65=6,5\left(g\right)\)
\(m_{ZnO}=14,6-6,5=8,1\left(g\right)\)
b) Có : \(m_{MgO}=8,1\left(g\right)\)
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(n_{H2SO4\left(tổng\right)}=0,1+0,1=0,2\left(mol\right)\)
\(V_{ddH2SO4}=\dfrac{0,2}{2}=0,1\left(l\right)\)
Chúc bạn học tốt
\(a.Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{Zn}=n_{H_2}=0,2\left(mol\right)\\ \Rightarrow\%m_{Zn}=\dfrac{0,2.65}{25.8}.100=50,39\%\\ \%m_{Cu}=100-50,39=49,61\%\\ b.m_{ddsaupu}=0,2.65+200-0,2.2=212,6\left(g\right)\\ n_{ZnSO_4}=n_{H_2}=0,2\left(mol\right)\\ C\%_{ZnSO_4}=\dfrac{0,2.161}{212,6}.100=15,15\%\)
Ta có:
n H2 = 0,05 ( mol )
1.PTHH
Fe + H2SO4 ====> FeSO4 + H2
FeO + H2SO4 ====> FeSO4 + H2O
theo pthh: n Fe = n H2 = 0,05 ( mol )
=> m Fe = 2,8 ( g )
=> m FeO = 7,2 ( g ) => n FeO = 0,1 ( mol )
2.
theo pthh: n H2SO4 = 0,05 + 0,1 = 0,15
=> m H2SO4 = 14,7 ( g )
=> m dd H2SO4 9,8% = 150 ( g )
$a\big)$
$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$
$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$
Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$
$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$
$\to \%m_{ZnO}=100-61,61=38,39\%$
$b\big)$
$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$
Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$
$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,2 ( mol )
\(m_{Zn}=0,2.65=13g\)
\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)
\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,4 ( mol )
\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)
\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)
0,1 0,2 ( mol )
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)
\(n_{H2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2|\)
1 1 1 1
0,05 0,05 0,05 0,05
\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O|\)
1 1 1 1
0,1 0,1 0,1
1) \(n_{Fe}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)
\(m_{Fe}=0,05.56=2,8\left(g\right)\)
\(m_{FeO}=10-2,8=7,2\left(g\right)\)
2) Có : \(m_{FeO}=7,2\left(g\right)\)
\(n_{FeO}=\dfrac{7,2}{72}=0,1\left(mol\right)\)
\(n_{H2SO4\left(tổng\right)}=0,05+0,1=0,15\left(mol\right)\)
\(m_{H2SO4}=0,15.98=14,7\left(g\right)\)
\(m_{ddH2SO4}=\dfrac{14,7.100}{9,8}=150\left(g\right)\)
3) \(n_{FeSO4\left(tổng\right)}=0,05+0,1=0,15\left(mol\right)\)
⇒ \(m_{FeSO4}=0,15.152=22,8\left(g\right)\)
\(m_{ddspu}=10+150-\left(0,05.2\right)=159,9\left(g\right)\)
\(C_{FeSO4}=\dfrac{22,8.100}{159,9}=14,26\)0/0
Chúc bạn học tốt
pthh: Zn+H2SO4→ZnSO4+H2 (1)
ZnO+H2SO4→ZnSO4+H2O (2)
n H2=0,2 (mol)
theo pt1 ta có nZn=nH2=0,2 (mol)
⇒ mZn=0,2 .65=13 (g)→mZnO=21,1-13=8,1 (g) →nZnO=0,1 (mol)
Theo pt 1 nH2SO4=nZn=0,2(mol) (3)
Theo pt2 nH2SO4=nZnO=0,2 (mol) (4)
Từ 3,4 ⇒nHCl=0,4 (mol)
V H2SO4=0,4\1=0,4l =400ml
Cái đoạn tính VH2SO4 là gì vậy????