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a, \(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
b, Ta có: \(m_{H_2SO_4}=200.9,8\%=19,6\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)
Theo PT: \(n_{MgO}=n_{MgSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,2.40=8\left(g\right)\)
c, Ta có: m dd sau pư = 8 + 200 = 208 (g)
\(\Rightarrow C\%_{MgSO_4}=\dfrac{0,2.120}{208}.100\%\approx11,54\%\)
Quy đổi Fe3O4 thành FeO, Fe2O3
\(n_{FeCl_2}=\dfrac{7,62}{127}=0,06\left(mol\right)\)
PTHH: FeO + 2HCl --> FeCl2 + H2O
0,06<------------0,06
=> \(n_{Fe_2O_3}=\dfrac{9,12-0,06.72}{160}=0,03\left(mol\right)\)
PTHH: Fe2O3 + 6HCl --> 2FeCl3 + 3H2O
0,03-------------->0,06
=> \(m_{FeCl_3}=0,06.162,5=9,75\left(g\right)\)
\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)
\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)
\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)
Bài 1:
Ta có: \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
BTNT H, có: \(n_{HCl}=2n_{H_2O}\Rightarrow n_{H_2O}=0,05\left(mol\right)\)
Theo ĐL BTKL, có: m oxit + mHCl = mmuối + mH2O
⇒ mmuối = 2,8 + 0,1.36,5 - 0,05.18 = 5,55 (g)
Bài 2:
\(m_{KOH}=200.5,6\%=11,2\left(g\right)\Rightarrow n_{KOH}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PT: \(2KOH+CuCl_2\rightarrow2KCl+Cu\left(OH\right)_2\)
Theo PT: \(n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,1.98=9,8\left(g\right)\)
a, PT: \(R+H_2SO_4\rightarrow RSO_4+H_2\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b, Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{H_2}=0,4\left(mol\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,4}{2}=0,2\left(l\right)\)
Theo ĐLBT KL, có: mKL + mH2SO4 = m muối + mH2
⇒ m muối = 7,8 + 0,4.98 - 0,4.2 = 46,2 (g)
c, Gọi: nR = x (mol) → nAl = 2x (mol)
Theo PT: \(n_{H_2}=n_R+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}.2x=0,4\left(mol\right)\Rightarrow x=0,1\left(mol\right)\)
⇒ nR = 0,1 (mol)
nAl = 0,1.2 = 0,2 (mol)
⇒ 0,1.MR + 0,2.27 = 7,8 ⇒ MR = 24 (g/mol)
Vậy: R là Mg.
Bổ sung: \(D_{HCl}=1,18\left(g/ml\right)\)
a) PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}n_{MgO}=\dfrac{2}{40}=0,05\left(mol\right)\\n_{HCl}=\dfrac{100\cdot1,18\cdot20\%}{36,5}=\dfrac{236}{365}\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,05}{1}< \dfrac{\dfrac{236}{365}}{2}\) \(\Rightarrow\) HCl còn dư, MgO p/ứ hết
\(\Rightarrow n_{MgCl_2}=0,05\left(mol\right)\) \(\Rightarrow C_{M_{MgCl_2}}=\dfrac{0,05}{0,1}=0,5\left(M\right)\)
\(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)
\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Có nH2O = nH2SO4 = a (mol)
Theo ĐLBTKL: 2,66 + 98a = 6,66 + 18a
=> a = 0,05 (mol)
=> \(V_{ddH_2SO_4}=\dfrac{0,05}{0,1}=0,5\left(l\right)=500\left(ml\right)\)