Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
\(n_{Fe}=\dfrac{6,5}{56}=\dfrac{13}{112}mol\)
\(m_{CH_3COOH}=\dfrac{90\cdot20\%}{100\%}=18g\Rightarrow n_{CH_3COOH}=0,3mol\)
\(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\uparrow\)
\(\dfrac{13}{112}\) 0,3 0 0
\(\dfrac{13}{112}\) \(\dfrac{13}{56}\) \(\dfrac{13}{112}\) \(\dfrac{13}{112}\)
0 \(\dfrac{19}{280}\) \(\dfrac{13}{112}\) \(\dfrac{13}{112}\)
a)\(m_{\left(CH_3COO\right)_2Fe}=\dfrac{13}{112}\cdot174=20,2g\)
\(m_{H_2}=\dfrac{13}{112}\cdot2=\dfrac{13}{56}g\)
\(m_{dd\left(CH_3COO\right)_2Fe}=6,5+90-\dfrac{13}{56}=96,27g\)
\(C\%=\dfrac{20,2}{96,27}\cdot100\%=20,98\%\)
PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
a) Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{6,2}{62}=0,2\left(mol\right)\) \(\Rightarrow C\%_{NaOH}=\dfrac{0,2\cdot40}{6,2+193,8}\cdot100\%=4\%\)
b) Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{CuSO_4}=\dfrac{200\cdot16\%}{160}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,2}{1}\) \(\Rightarrow\) CuSO4 còn dư, tính theo NaOH
\(\Rightarrow n_{Cu\left(OH\right)_2}=0,1\left(mol\right)=n_{CuO}\) \(\Rightarrow m_{CuO}=0,1\cdot80=8\left(g\right)\)
c) PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
Theo PTHH: \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(l\right)=100\left(ml\right)\)
1 ) a, Số mol Na= 4,6:23=0,2 (mol)
ptpứ:
2Na + 2H2O--> 2NaOH + H2
số mol Na=số mol NaOH=0,2mol
số gam CuSO4= 30x16:100=4,8g
số mol CuSO4=4,8:160=0,03mol
ptpứ:
2NaOH + CuSO4--> Cu(OH)2 + Na2SO4
0,06 0,03 0,03 0,03 (mol)
khối lượng Na2SO4=0,03x142=4,26(g)
cứ 50g dd A tác dụng với 30g dd CuSO4 thu được 4,26g dd C
cứ 100g dd A ..................xg ...................................yg .......
x= 100x30:50=60g
y=100x4,26:50=8,52g
khối lượng dd C=100+60=160g
C%dd Na2SO4 trong dd C= 8,52:160x100=5,325%
khối lượng NaOH còn dư trong 100g dd A= (0,2-0,06x2)x40=3,2g
C% dd NaOH trong dd C=3,2:160x100=2%
C% dd NaOH trong dd A= 0,2x40:100x100=8%
b, trong 50g dd Atac dung voi 30g dd CuSO4 16% thu duoc ket tua B va dd C.
Cu(OH)2-->(nhiệt độ) CuO+H2O
0,03 0,03
khối lượng CuO=0,03x80=2,4g
a, \(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{MgCO_3}=n_{CO_2}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,2.84}{64,8}.100\%\approx25,93\%\\\%m_{MgSO_4}\approx74,07\%\end{matrix}\right.\)
b, - Dung dịch C gồm: MgCl2, MgSO4 và HCl dư.
Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{CO_2}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{CO_2}=0,4\left(mol\right)\end{matrix}\right.\)
Ta có: \(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,5-0,4=0,1\left(mol\right)\)
\(m_{MgSO_4}=64,8-0,2.84=48\left(g\right)\Rightarrow n_{MgSO_4}=\dfrac{48}{120}=0,4\left(mol\right)\)
Có: m dd sau pư = 64,8 + 100 - 0,2.44 = 156 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,2.95}{156}.100\%\approx12,18\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{156}.100\%\approx2,34\%\\C\%_{MgSO_4}=\dfrac{48}{156}.100\%\approx30,77\%\end{matrix}\right.\)
c, PT: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(HCl+NaOH\rightarrow NaCl+H_2O\)
\(MgSO_4+2NaOH\rightarrow Na_2SO_4+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}+n_{MgSO_4}=0,6\left(mol\right)\)
\(\Rightarrow m_{cr}=m_{MgO}=0,6.40=24\left(g\right)\)
a,\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(n_{HCl}=0,5.0,4=0,2\left(mol\right)\)
PTHH: 2K + 2H2O ---> 2KOH + H2 (Fe và Cu ko tan trong nước)
0,2 0,1
Fe + 2HCl ---> FeCl2 + H2 (Cu ko phản ứng với HCl)
0,1 0,2
mChất rắn còn lại = mCu = 6,6 (g)
\(\rightarrow\left\{{}\begin{matrix}m_K=39.0,2=7,8\left(g\right)\\m_{Fe}=56.0,1=5,6\left(g\right)\\m_{Cu}=6,6\left(g\right)\end{matrix}\right.\)
\(\rightarrow m_{\text{hhkimloại}}=7,8+5,6+6,6=20\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}\%m_K=\dfrac{7,8}{20}=39\%\\\%m_{Fe}=\dfrac{5,6}{20}=28\%\\\%m_{Cu}=100\%-39\%-28\%=33\%\end{matrix}\right.\)
b, PTHH: FexOy + yH2 --to--> xFe + yH2O
\(n_{O\left(\text{trong oxit}\right)}=n_{H_2O}=n_{H_2}=0,1\left(mol\right)\\ \rightarrow n_{Fe\left(\text{trong oxit}\right)}=\dfrac{5,8-0,1.16}{56}=0,075\left(mol\right)\)
\(\rightarrow x:y=n_{Fe}:n_O=0,075:0,1=3:4\)
CTHH của oxit sắt Fe3O4
Sửa đề thành 2,24 l khí C nhé :)
\(a) n_{CH_3COOH} = \dfrac{200.12\%}{60} = 0,4(mol)\\ 2CH_3COOH + CaCO_3 \to (CH_3COO)_2Ca + CO_2 + H_2O\\ n_{CaCO_3} = n_{CO_2} = \dfrac{1}{2}n_{CH_3COOH} = 0,2(mol)\\ \Rightarrow a = \dfrac{0,2.100}{100\%-20\%} =25(gam)\\ V_B = 0,2.22,4 = 4,48(lít)\\ b) m_{dd\ sau\ pư} = m_{CaCO_3} + m_{dd\ CH_3COOH} - m_{CO_2} = 0,2.100 + 200 - 0,2.2 = 219,6(gam)\\ C\%_{(CH_3COO)_2Ca} = \dfrac{0,2.158}{219,6}.100\% = 36\%\)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)
\(n_{BaSO_4}=\dfrac{11,65}{233}=0,05\left(mol\right)\)
\(Mg+CuSO_4\rightarrow MgSO_4+Cu\)
x------>x--------->x------------>x
\(2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\)
y------>1,5y-------->0,5y-------->1,5y
Có hệ \(\left\{{}\begin{matrix}24x+27y=0,78\\x+1,5y=\dfrac{2,56}{64}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,01\\y=0,02\end{matrix}\right.\)
Giả sử \(CuSO_4\) phản ứng hết, dung dịch C có: \(\left\{{}\begin{matrix}n_{MgSO_4}=x=0,01\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,5y=0,5.0,02=0,01\left(mol\right)\end{matrix}\right.\)
\(MgSO_4+BaCl_2\rightarrow MgCl_2+BaSO_4\) (1)
0,01-------------------------------->0,01
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow3BaSO_4+2AlCl_3\) (2)
0,01------------------------>0,03
Từ PTHH (1), (2) có: \(\Sigma n_{BaSO_4}=0,01+0,03=0,04\left(mol\right)< 0,05\left(mol\right)_{theo.đề}\)
=> Giả sử sai, \(CuSO_4\) dư
\(CuSO_4+BaCl_2\rightarrow BaSO_4+CuCl_2\)
0,01<-----------------0,01
\(CM_{CuSO_4}=a=\dfrac{x+1,5y+0,01}{0,2}=\dfrac{0,01+1,5.0,02+0,01}{0,2}=0,25\left(M\right)\)
Trong A:
\(n_{Al}=0,02\left(mol\right)\\ n_{Mg}=0,01\left(mol\right)\)
m(ZnCl2)= 170*12/100=20,4g
n(ZnCl2)= 0,15mol
n(Zn(OH)2)=0,1mol < n(ZnCl2) =0,15
=> ZnCl2 dư
2NaOH + ZnCl2-> 2NaCl+Zn(OH)2
Số mol NaOH=2n(Zn(OH)2)=0,2 MOL
m(NaOH)= 8(g)
m(ddnaoh)=8*100/10=80(g)
\(n_{ZnCl_2}=\dfrac{170\cdot12\%}{136}=0.15\left(mol\right)\)
\(n_{Zn\left(OH\right)_2}=\dfrac{9.9}{99}=0.1\left(mol\right)\)
\(ZnCl_2+2NaOH\rightarrow Zn\left(OH\right)_2+2NaCl\)
TH1 : Kết tủa không bị hòa tan.
\(n_{NaOH}=2n_{Zn\left(OH\right)_2}=2\cdot0.1=0.2\left(mol\right)\)
\(m_{dd_{NaOH}}=\dfrac{0.2\cdot40}{10\%}=80\left(g\right)\)
TH2 : Kết tủa bị hòa tan một phần.
\(ZnCl_2+2NaOH\rightarrow Zn\left(OH\right)_2+2NaCl\)
\(0.15............0.3...........0.15\)
\(2NaOH+Zn\left(OH\right)_2\rightarrow Na_2ZnO_2+2H_2O\)
\(2x...........x\)
\(n_{Zn\left(OH\right)_2}=0.15-x=0.1\left(mol\right)\)
\(\Rightarrow x=0.05\)
\(n_{NaOH}=0.3+2\cdot0.05=0.4\left(mol\right)\)
\(m_{dd_{NaOH}}=\dfrac{0.4\cdot40}{10\%}=160\left(g\right)\)
