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PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
a) Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{6,2}{62}=0,2\left(mol\right)\) \(\Rightarrow C\%_{NaOH}=\dfrac{0,2\cdot40}{6,2+193,8}\cdot100\%=4\%\)
b) Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{CuSO_4}=\dfrac{200\cdot16\%}{160}=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,2}{1}\) \(\Rightarrow\) CuSO4 còn dư, tính theo NaOH
\(\Rightarrow n_{Cu\left(OH\right)_2}=0,1\left(mol\right)=n_{CuO}\) \(\Rightarrow m_{CuO}=0,1\cdot80=8\left(g\right)\)
c) PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
Theo PTHH: \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(l\right)=100\left(ml\right)\)
Na2O+H2O->2NaOH
0,1 0,1 0,2
2NaOH+CuSO4->Na2SO4+Cu(OH)2
0,2 0,1 0,1 0,1
a.mNaOH=0,2.40=8(g)
mdd NaOH=6,2+193,8=200(g)
C%dd NaOH=8/200.100%=4%
b.mCu(OH)2=0,1.98=9,8(g)
c.Cu(OH)2->CuO+H2O
0,1 0,1 0,1
CuO+2HCl->CuCl2+H2O
0,1 0,2
VddHCl=0,2/2=0,1(l)
Câu c mình ko biết làm đúng hay ko
\(a.n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\\ Na_2O+H_2O\rightarrow NaOH\\ m_{ddNaOH}=193,8+6,2=200\left(g\right)\\C\%_{ddX}=C\%_{ddNaOH}=\dfrac{0,1.2.40}{200}.100=4\%\\ b.2NaOH+CuSO_4\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\ a=m_{Cu\left(OH\right)_2}=\dfrac{0,2}{2}.98=9,8\left(g\right)\\ c.Cu\left(OH\right)_2\underrightarrow{to}CuO+H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{HCl}=2.n_{CuO}=2.n_{Cu\left(OH\right)_2}=2.0,1=0,2\left(mol\right)\\ V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(lít\right)=100\left(ml\right)\)
\(C\%_X=\frac{40}{240}.100\%=16,7\left(\%\right)\)
\(PTHH:2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
\(n_X=\frac{200.16,7}{100.40}=0,835\left(mol\right)\)
\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
\(m_{CuO}=0,835.80=66,8\left(g\right)\)
\(C\%_Y=\frac{0,835.142}{200+100-0,835.98}.100\%=42,17\left(\%\right)\)
( k chắc :>>)
