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a,\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl → ZnCl2 + H2
Mol: 0,2 0,4 0,2
\(\Rightarrow\%m_{Zn}=\dfrac{0,2.65.100\%}{21,1}=61,61\%;\%m_{ZnO}=100-61,61=38,39\%\)
b,\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1\left(mol\right)\)
PTHH: ZnO + 2HCl → ZnCl2 + H2O
Mol: 0,1 0,2
\(m_{ddHCl}=\dfrac{\left(0,2+0,4\right).36,5.100\%}{7,3\%}=300\left(g\right)\)
c,
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,2 0,2
PTHH: ZnO + H2SO4 → ZnSO4 + H2O
Mol: 0,1 0,1
\(n_{H_2SO_4}=0,2+0,1=0,3\left(mol\right)\Rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{0,5}=0,6\left(l\right)=600\left(ml\right)\)
\(m_{ddH_2SO_4}=600.1,12=672\left(g\right)\)
\(n_{HCl}=0,8.0,5=0,4\left(mol\right);n_{H_2SO_4}=0,8.0,75=0,6\left(mol\right)\)
=> \(n_{Cl^-}=0,4\left(mol\right);n_{SO_4^{2-}}=0,6\left(mol\right)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Bảo toàn nguyên tố H:
\(n_{HCl}.1+n_{H_2SO_4}.2=n_{H_2}.2+n_{H_2O}.2\)
\(\Leftrightarrow0,4.1+0,6.2=0,2.2+n_{H_2O}.2\)
=>\(n_{H_2O}=0,6\left(mol\right)\)
=> \(n_O=0,6\left(mol\right)\)
\(m_{muối}=m_{kimloai}+m_{Cl^-}+m_{SO_4^{2-}}\)
=>\(m_{kimloai}=88,7-35,5.0,4-0,6.96=16,9\left(g\right)\)
=> \(m=m_{kimloai}+m_O=16,9+0,6.16=26,5\left(g\right)\)
a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 24x + 56y = 8 (1)
Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{Mg}=x\left(mol\right)\\n_{FeCl_2}=n_{Fe}=y\left(mol\right)\end{matrix}\right.\) ⇒ 95x + 127y = 22,2 (2)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1.24}{8}.100\%=30\%\\\%m_{Fe}=70\%\end{matrix}\right.\)
b, \(n_{HCl}=2n_{Mg}+2n_{Fe}=0,4\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,4}{1}=0,4\left(l\right)\)
Bảo toàn khối lượng :
\(m_{O_2}=3.43-2.15=1.28\left(g\right)\)
\(n_{O_2}=\dfrac{1.28}{32}=0.04\left(mol\right)\)
Bảo toàn O :
\(n_{H_2O}=2n_{O_2}=2\cdot0.04\cdot2=0.08\left(mol\right)\)
Bảo toàn H :
\(n_{HCl}=2n_{H_2O}=2\cdot0.08=0.16\left(mol\right)\)
\(V_{dd_{HCl}}=\dfrac{0.16}{0.5}=0.32\left(l\right)\)
Bảo toàn khối lượng :
\(m_{Muôi}=3.43+0.16\cdot36.5-0.08\cdot18=7.83\left(g\right)\)
Bảo toàn khối lượng:
m oxit = m kim loại + m O
=> mO = 3,43 – 2,15 = 1,28g
=> nO = 0,08 mol
Có nH+ = 2nO = 0,08 . 2 = 0,16 mol
V =\(\dfrac{0,16}{0,5}\)= 0,32 lít = 320ml
\(m_{muối}=m_{KL}+m_{Cl^-}=2,15+0,16.35,5=7,83\left(g\right)\)
Câu 5 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,15 0,3 0,15
a) \(n_{Mg}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Mg}=0,1.24=2,4\left(g\right)\)
\(m_{MgO}=8,4-2,4=6\left(g\right)\)
0/0Mg = \(\dfrac{2,4.100}{8,4}=28,57\)0/0
0/0MgO = \(\dfrac{6.100}{8,4}=71,43\)0/0
b) Có : \(m_{MgO}=6\left(g\right)\)
\(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{3,65}=500\left(g\right)\)
\(n_{MgCl2\left(tổng\right)}=0,1+0,15=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,15.95=14,25\left(g\right)\)
\(m_{ddspu}=8,4+500-\left(0,1.2\right)=508,2\left(g\right)\)
\(C_{MgCl2}=\dfrac{14,25.100}{508,2}=2,8\)0/0
Chúc bạn học tốt
Sửa đề: Sau phản ứng thu đc \(2240(cm^3)\) lít khí (đktc)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ b,n_{Zn}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%= 44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1(mol)\\ \Sigma n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1M\)
