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a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow n_{ZnO}=\dfrac{20-0,1\cdot65}{81}=\dfrac{1}{6}\left(mol\right)\)
\(\Rightarrow n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{4}{15}\left(mol\right)\)
Mặt khác: \(m_{H_2}=0,1\cdot2=0,2\left(g\right)\)
\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=119,8\left(g\right)\) \(\Rightarrow C\%_{ZnCl_2}=\dfrac{\dfrac{4}{15}\cdot136}{119,8}\cdot100\%\approx30,27\%\)
c) Giả sử khí là SO2
PTHH: \(Zn+H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}ZnSO_4+SO_2\uparrow+H_2O\)
Theo PTHH: \(n_{SO_2}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)
Ta có: \(n_{HCl}=\dfrac{200}{1000}.2=0,4\left(mol\right)\)
\(PTHH:Mg+2HCl--->MgCl_2+H_2\uparrow\left(1\right)\)
a. Theo PT(1): \(n_{Mg}=n_{H_2}=n_{MgCl_2}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,2.24=4,8\left(g\right)\\V_{H_2}=0,2.22,4=4,48\left(lít\right)\end{matrix}\right.\)
b. \(PTHH:2NaOH+MgCl_2--->Mg\left(OH\right)_2\downarrow+2NaCl\left(2\right)\)
Ta có: \(n_{NaOH}=\dfrac{\dfrac{20\%.100}{100\%}}{40}=0,5\left(mol\right)\)
Ta thấy: \(\dfrac{0,5}{2}>\dfrac{0,2}{1}\)
Vậy NaOH dư.
Theo PT(2): \(n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{Mg\left(OH\right)_2}=0,2.58=11,6\left(g\right)\)
a: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
200ml=0,2 lít
\(n_{HCl}=0.2\cdot22.4=4.48\left(mol\right)\)
\(\Leftrightarrow n_{H_2}=2.24\left(mol\right)\)
\(\Leftrightarrow m_{H_2}=n_{H_2}\cdot M=2.24\cdot1=2.24\left(g\right)\)
\(n_{MgCl_2}=2.24\left(mol\right)\)
\(\Leftrightarrow n_{Mg}=2.24\left(mol\right)\)
\(\Leftrightarrow m_{Mg}=2.24\cdot24=53.76\left(g\right)\)
a. PTHH:
\(Ag+HCl--\times-->\)
\(Zn+2HCl--->ZnCl_2+H_2\)
b. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) (phần này mình sửa lại phần số mol)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(\Rightarrow m_{Ag}=25,8-6,5=19,3\left(g\right)\)
c. \(\%_{m_{Zn}}=\dfrac{6,5}{25,8}.100\%=25,19\%\)
\(\%_{m_{Ag}}=100\%-25,19\%=74,81\%\)
a)
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH :
$n_{Fe} = n_{H_2} = \dfrac{11,2}{22,4} = 0,5(mol)$
$A = 0,5.56 = 28(gam)$
b) $n_{HCl} = 2n_{H_2} = 1(mol)$
$m_{HCl} = 1.36,5 = 36,5(gam)$
c) $m_{dd\ HCl} = 36,5 : 20\% = 182,5(gam)$
$m_{dd\ sau\ pư} = 28 + 182,5 - 0,5.2 = 209,5(gam)$
$C\%_{FeCl_2} = \dfrac{0,5.127}{209,5}.100\% = 30,3\%$
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,4--->0,8------>0,4--->0,4
=> VH2 = 0,4.22,4 = 8,96(l)
c) mHCl = 0,8.36,5 = 29,2 (g)
=> \(m_{dd\left(HCl\right)}=\dfrac{29,2.100}{7,3}=400\left(g\right)\)
mdd (sau pư) = 22,4 + 400 - 0,4.2 = 421,6 (g)
=> \(C\%\left(FeCl_2\right)=\dfrac{127.0,4}{421,6}.100\%=12,05\%\)
a) \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,2 0,4 0,2 0,2
b) \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c) \(C\%_{ddHCl}=\dfrac{0,4.36,5.100\%}{300}=4,87\%\)
d) mdd sau pứ = 11,2 + 300 - 0,2.2 = 310,8 (g)
\(C\%_{ddFeCl_2}=\dfrac{0,2.127.100\%}{310,5}=8,17\%\)
\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.1.......0.2......................0.1\)
Chất rắn X : Cu
\(m_{Zn}=0.1\cdot65=6.5\left(g\right)\Rightarrow m_{Cu}=19.3-6.5=12.8\left(g\right)\)
\(n_{Cu}=\dfrac{12.8}{64}=0.2\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)
\(2Cu+O_2\underrightarrow{^{^{t^o}}}2CuO\)
\(0.2........0.1\)
\(m_{tăng}=m_{O_2}=0.1\cdot32=3.2\left(g\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{HCl}=\dfrac{200\cdot71\%}{36,5}=\dfrac{284}{73}\left(mol\right)\)
\(\Rightarrow n_{Fe}=n_{FeCl_2}=n_{H_2}=\dfrac{142}{73}\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=\dfrac{142}{73}\cdot56\approx108,93\left(g\right)\\m_{FeCl_2}=\dfrac{142}{73}\cdot127\approx247,04\left(g\right)\\m_{H_2}=\dfrac{142}{73}\cdot2\approx3,89\left(g\right)\\V_{H_2}=\dfrac{142}{73}\cdot22,4\approx43,57\left(l\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=305,04\left(g\right)\)
\(\Rightarrow C\%_{FeCl_2}=\dfrac{247,04}{305,04}\cdot100\%\approx80,99\%\)
Fe + 2HCl ➝ FeCl2 + H2
mHCl = 200.71% = 142 (g) => nHCl = \(\dfrac{284}{73}\) (mol)
nFe = \(\dfrac{1}{2}\) nHCl = \(\dfrac{142}{73}\) (mol) => m ≃ 108,9 (g)
nH2 = nFe => V ≃ 43,57 (l)
nFeCl2 = nFe => C% ≃ 80%
(Mk nghĩ bạn nên kiểm tra lại đề vì số liệu không được đẹp cho lắm)