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a) \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
_____0,1<-0,2------<0,1<---0,1
=> mMgCl2 = 0,1.95 = 9,5 (g)
b) \(C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\)
PTHH: \(K_2SO_3+2HCl\rightarrow2KCl+H_2O+SO_2\uparrow\)
a+b+c) Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KCl}=0,5\left(mol\right)=n_{HCl}\\n_{K_2SO_3}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_3}=0,25\cdot158=39,5\left(g\right)=a\\m_{KCl}=0,5\cdot74,5=37,25\left(g\right)\\m_{ddHCl}=\dfrac{0,5\cdot36,5}{10,95\%}\approx166,67\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{SO_2}=0,25\cdot64=16\left(g\right)\)
\(\Rightarrow m_{dd}=m_{K_2SO_3}+m_{ddHCl}-m_{SO_2}=190,17\left(g\right)\) \(\Rightarrow C\%_{KCl}=\dfrac{37,25}{190,17}\cdot100\%\approx19,59\%\)
d) PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Theo PTHH: \(n_{NaOH}=n_{HCl}=0,5\left(mol\right)\) \(\Rightarrow V_{NaOH}=\dfrac{0,5}{0,5}=1\left(l\right)\)
\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH :
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,25 0,5 0,25
\(a,m_{Fe}=0,25.56=14\left(g\right)\)
\(b,C_{M\left(HCl\right)}=\dfrac{0,5}{0,2}=2,5\left(M\right)\)
\(Fe+H_2SO_4 \to FeSO_4+H_2\\ n_{H_2}=0,15(mol)\\ a/\\ n_{Fe}=n_{H_2}=0,15(mol)\\ m_{Fe}=0,15.56=8,4(g)\\ b/\\ n_{H_2SO_4}=n_{H_2}=0,15(mol)\\ CM_{H_2SO_4}=\dfrac{0,15}{2}=0,75M c/\\ n_{FeSO_4}=n_{H_2}=0,15(mol)\\ CM_{FeSO_4}=\dfrac{0,15}{0,2}=0,75M\\\)
200ml = 0,2l
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,3 0,6 0,3 0,3
a) \(n_{ZnCl2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(C_{M_{ZnCl2}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
b) \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,3.22,4=6,72\left(l\right)\)
c) Pt : \(NaOH+HCl\rightarrow NaCl+H_2O|\)
1 1 1 1
0,6 0,6
\(n_{NaOH}=\dfrac{0,6.1}{1}=0,6\left(mol\right)\)
\(m_{NaOH}=0,6.40=24\left(g\right)\)
\(m_{ddNaOH}=\dfrac{24.100}{20}=120\left(g\right)\)
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