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Ta có: \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{NaOH}=0,2.1=0,2\left(mol\right)\)
\(\Rightarrow\dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\)
→ Pư tạo NaHCO3 và Na2CO3
PT: \(CO_2+NaOH\rightarrow NaHCO_3\)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Theo PT: \(\left\{{}\begin{matrix}n_{CO_2}=n_{NaHCO_3}+n_{Na_2CO_3}=0,15\\n_{NaOH}=n_{NaHCO_3}+2n_{Na_2CO_3}=0,2\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaHCO_3}=0,1\left(mol\right)\\n_{Na_2CO_3}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{NaHCO_3}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{Na_2CO_3}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\end{matrix}\right.\)
1.nCO2=0,1 (mol )
TH1: Số mol của CO2 dư => Khối lượng muối khan tối đa tạo được là:
mmuối=0,1.84=8,4<9,5 (loại )
TH2: CO2 hết
Gọi số mol CO2 tạo muối Na2CO3;NaHCO3 lần lượt là x, y
2NaOH+CO2→Na2CO3+H2O
NaOH+CO2→NaHCO3
Ta có : \(\left\{{}\begin{matrix}x+y=0,1\\106x+84y=9,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,05\\y=0,05\end{matrix}\right.\)
⇒nNaOH=2.0,05+0,05=0,15 (mol)
⇒CMNaOH=\(\dfrac{0,15}{0,1}\)=1,5M
a) \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: CO2 + 2NaOH → Na2CO3 + H2O
Mol: 0,15 0,3 0,15
\(C_{M_{ddNaOH}}=\dfrac{0,3}{0,2}=1,5M\)
b) Na2CO3: natri cacbonat
\(m_{Na_2CO_3}=0,15.106=15,9\left(g\right)\)
c)
PTHH: 2NaOH + H2SO4 → Na2SO4 + 2H2O
Mol: 0,15 0,075
\(V_{ddH_2SO_4}=\dfrac{0,075}{1}=0,075\left(l\right)=75\left(ml\right)\)
PTHH: \(SO_2+2NaOH\rightarrow Na_2SO_3+H_2O\)
Ta có: \(n_{NaOH}=0,4\cdot2=0,8\left(mol\right)\)
\(\Rightarrow n_{SO_2}=0,4\left(mol\right)=n_{Na_2SO_3}\) \(\Rightarrow\left\{{}\begin{matrix}V_{SO_2}=0,4\cdot22,4=8,96\left(l\right)\\m_{Na_2SO_3}=0,4\cdot126=50,4\left(g\right)\\C_{M_{Na_2SO_3}}=\dfrac{0,4}{0,4}=1\left(M\right)\end{matrix}\right.\)
PT: \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
Ta có: \(n_{CO_2}=\dfrac{1,2395}{24,79}=0,05\left(mol\right)\)
a, Theo PT: \(n_{Na_2CO_3}=n_{CO_2}=0,05\left(mol\right)\Rightarrow m_{Na_2CO_3}=0,05.106=5,3\left(g\right)\)
b, \(n_{NaOH}=2n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{NaOH}}=\dfrac{0,1}{0,1}=1\left(M\right)\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
____0,1______0,2_____0,1____0,1 (mol)
a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)
\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)
\(a/ CO_2+2NaOH \to Na_2CO_3+H_2O\\ n_{CO_2}=0,1(mol)\\ b/\\ n_{NaOH}=0,1.2=0,2(mol)\\ CM_{NaOH}=\frac{0,2}{0,2}=1M\\ c/\\ n_{Na_2CO_3}=n_{CO_2}=0,1(mol)\\ m_{Na_2CO_3}=0,1.106==10,6(g)$\)
\(n_{CO_2}=0,15mol\)
\(n_{NaOH}=0,35mol\)
\(T=\dfrac{n_{OH^-}}{n_{CO_2}}=\dfrac{0,35}{0,15}=\dfrac{7}{3}>2\)\(\Rightarrow\) tạo muối \(Na_2CO_3\)
\(NaOH+CO_2\rightarrow Na_2CO_3+H_2O\)
0,35 0,15 0,15 0,15
\(\Rightarrow\)\(OH^-dư\) 0,2mol.
\(m_{ddsau}=0,35\cdot40+0,15\cdot44-0,15\cdot18=17,9g\)
\(C\%_{saup}\)\(_ư\)\(=\dfrac{15,9}{17,9}\cdot100=88,83\%\)
\(n_{CO2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Pt : \(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O|\)
1 2 1 1
0,3 0,6
\(n_{NaOH}=\dfrac{0,3.2}{1}=0,6\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddNaOH}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
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