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a) 3Fe + 2O2 
Fe3O4
b) nFe = \(\dfrac{8,4}{56}\)= 0,15 mol
nFe3O4 = \(\dfrac{11,6}{232}\) = 0,05 mol
Ta thấy \(\dfrac{nFe}{3}\)= \(\dfrac{nFe_3O_4}{1}\)=> Fe phản ứng hết
<=> nO2 cần dùng = \(\dfrac{2nFe}{3}\)= 0,1 mol
<=> mO2 cần dùng = 0,1.32 = 3,2 gam
c) Oxi chiếm thể tích bằng 1/5 thể tích không khí.
Mà V O2 = 0,1.22,4 = 2,24 lít => V không khí = 2,24 . 5 = 11,2 lít
\(a) n_P = \dfrac{18,6}{31} = 0,6(mol)\\ n_{O_2} = \dfrac{20,16}{22,4} = 0,9(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ \dfrac{n_P}{4} = 0,15 < \dfrac{n_{O_2}}{5} = 0,18 \to O_2\ dư\\ n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,75(mol)\\ \Rightarrow m_{O_2\ dư} = (0,9-0,75).32 = 4,8(gam)\\ b) n_{Fe} = \dfrac{56}{56} = 1(mol)\)
\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ \dfrac{n_{Fe}}{3} = \dfrac{1}{3}<\dfrac{n_{O_2}}{2} = 0,45\to Fe\ cháy\ hết.\\ c)\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,9.2 = 1,8(mol)\\ \Rightarrow m_{KMnO_4} = 1,8.158 =284,4(gam)\)
a)
\(b)n_{Fe_3O_4} = \dfrac{6,96}{232} = 0,03(mol)\\ 3Fe + 2O_2 \xrightarrow{t^o}Fe_3O_4\\ n_{Fe} = 3n_{Fe_3O_4} = 0,09(mol)\\ m_{Fe} = 0,09.56 = 5,04(gam)\\ c) n_{O_2} = 2n_{Fe_3O_4} = 0,06(mol)\\ V_{O_2} = 0,06.22,4 = 1,344(lít)\\ d) 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,12(mol)\\ m_{KMnO_4} = 0,12.158 = 18,96(gam)\)
\(n_{Fe_3O_4}=\dfrac{6.96}{232}=0.03\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{t^0}Fe_2O_3\)
\(0.09.....0.06.......0.03\)
\(m_{Fe}=0.09\cdot56=5.04\left(g\right)\)
\(V_{O_2}=0.06\cdot22.4=1.344\left(l\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(0.12...............................................0.06\)
\(m_{KMnO_4}=0.12\cdot158=18.96\left(g\right)\)
n Fe3O4=\(\dfrac{13,92}{232}\)=0,06 mol
3Fe + 2O2 -to--> Fe3O4
0,18------0,12-------0,06
=>m Fe=0,18.56=10,08g
=>VO2=0,12.22,4=2,688l
2KMnO4-to>K2MnO4+MnO2+O2
0,24-------------------------------------0,12
=>m KMnO4=0,24.158=37,92g
nFe3O4 = 13,92 : 160= 0,087 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,087->0,058-->0,029 (mol)
=> mFe = 0,029 . 56 = 1,624 (g)
=> VO2 = 0,058 . 22,4 = 1,2992 (L)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 + O2
0,116<------------------------------0,058 (mol)
=> mKMnO4 = 0,116 . 158 = 18,328 (g)
a) \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,3<---0,2-------->0,1
=> m = 0,3.56 = 16,8 (g)
b) mFe3O4 = 0,1.232 = 23,2 (g)
c) Vkk = 4,48 : 20% = 22,4 (l)
nO2 = 4,48/22,4 = 0,2 (mol)
PTHH: 3Fe + 2O2 -> (t°) Fe3O4
Mol: 0,3 <--- 0,2 ---> 0,1
mFe = 0,3 . 56 = 16,8 (g)
mFe3O4 = 0,1 . 232 = 23,2 (g)
Vkk = 4,48 . 5 = 22,4 (l)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{33,6}{56}=0,6\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,2\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,2.232=46,4\left(g\right)\)
c, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,4\left(mol\right)\)
\(\Rightarrow V_{O_2}=0,4.22,4=8,96\left(l\right)\) \(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{21\%}\approx42,67\left(l\right)\)
d, PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,4}{4}\), ta được Fe3O4 dư.
Theo PT: \(n_{Fe_3O_4\left(pư\right)}=\dfrac{1}{4}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow n_{Fe_3O_4\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
a. \(3Fe+2O_2\rightarrow Fe_3O_4\)
b. Số mol Fe: \(n=\dfrac{m}{M}=\dfrac{33,6}{56}=0,6\left(mol\right)\)
PTHH: \(3Fe+2O_2\rightarrow Fe_3O_4\)
Theo PTHH: \(3\) \(2\) \(1\) (mol)
Theo đề: \(0,6\) \(\rightarrow0,2\) (mol)
Kl của \(Fe_3O_4\) là: \(m=n\cdot M=0,2\cdot\left(56\cdot3+16\cdot4\right)=736\left(g\right)\)
nFe3O4 = 17.4/232 = 0.075 (mol)
3Fe + 2O2 -to-> Fe3O4
0.225__0.15_____0.075
mFe = 0.225*56=12.6 (g)
VO2 = 0.15*22.4 = 3.36 (l)
2KClO3 -to-> 2KCl + 3O2
0.1________________0.15
mKClO3 = 0.1*122.5 = 12.25 (g)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\) ; \(n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,2 < 0,25 ( mol )
0,2 \(\dfrac{2}{15}\) \(\dfrac{1}{15}\) ( mol )
`->` Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,25-\dfrac{2}{15}\right).32=3,73\left(g\right)\)
\(V_{kk}=V_{O_2}.5=\dfrac{2}{15}.22,4.5=14,93\left(l\right)\)
\(m_{bôt.sắt}=\dfrac{11,2.100}{100-12}=12,72\left(g\right)\)