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\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)
\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)
\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)
\(a)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)
Do đó, Oxi dư.
\(n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)\\ \Rightarrow m_{O_2\ dư} = (0,3 - 0,25).32 = 1,6(gam)\\ b)\\ n_{P_2O_5} = \dfrac{n_P}{2} = 0,1(mol)\\ \Rightarrow m_{P_2O_5} = 0,1.142 = 14,2(gam)\)
a) $n_P = \dfrac{12,4}{31} = 0,4(mol) ; n_{O_2} = \dfrac{13,44}{22,4} = 0,6(mol)$
$4P + 5O_2 \xrightarrow{t^o} 2P_2O_5$
Ta thấy :
$n_P : 4 < n_{O_2} : 5$ nên $O_2$ dư
Điphotpho pentaoxit được tạo thành
$n_{P_2O_5} = \dfrac{1}{2}n_P = 0,2(mol)$
$m_{P_2O_5} = 0,2.142 = 28,4(gam)$
nP= 7,44/31=0,24(mol)
nO2=6,16/22,4=0,275(mol)
PTHH:4 P + 5 O2 -to->2 P2O5
Ta có: 0,24/4 > 0,275/5
=> O2 hết, P dư, tính theo nO2
nP(p.ứ)= 0,275 x 4/5= 0,22(mol)
=>nP(dư)=0,24-0,22=0,02(mol)
=>mP(dư)=0,02.31= 0,62(g)
nP2O5= 2/5 x 0,275= 0,11(mol)
=> mP2O5= 142 x 0,11= 15,62(g)
\(n_P=\dfrac{7,44}{31}=0,24\left(mol\right)\)
\(n_{O_2}=\dfrac{6,16}{22,4}=0,275\left(mol\right)\)
PTHH : \(4P+5O_2\rightarrow2P_2O_5\)
Ban đầu : 0,24 0,275 (mol)
Phản ứng : 0,22 0,275 0,11 (mol)
Sau phản ứng : 0,02 0 0,11 (mol)
\(m_P=0,02.31=0,62\left(g\right)\)
\(m_{P_2O_5}=0,11.142=15,62\left(g\right)\)
\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)
\(n_{O_2}=\dfrac{7.84}{22.4}=0.35\left(mol\right)\)
\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)
\(4........5\)
\(0.2........0.35\)
\(LTL:\dfrac{0.2}{4}< \dfrac{0.35}{5}\Rightarrow O_2dư\)
\(m_{O_2\left(dư\right)}=\left(0.35-0.25\right)\cdot32=3.2\left(g\right)\)
\(m_{P_2O_5}=0.1\cdot142=14.2\left(g\right)\)
Tham khảo nha!!!
nP = 6,2/31 = 0,2 mol ; nO2 = 7,84/22,4 = 0,35 mol
a, PTHH : 4P + 5O2 (to) -> 2P2O5
0,2 0,35 mol
Ta thấy : 0,2/4 < 0,35/5 -> nO2 dư = 0,35 - 0,05*5 = 0,1 mol
-> mO2 dư = 0,1*32 = 3,2 gam
b, Theo pt : nP2O5 = 1/2*nP = 0,1 mol -> mP2O5 = 0,1*142 = 14,2 gam
nAl=\(\dfrac{5,4}{27}\)=0,2mol
nO2=\(\dfrac{4,48}{22,4}\)=0,2mol
PTHH:
4Al + 3O2--to->2Al2O3
Tỉ lệ \(\dfrac{0,2}{4}\) <\(\dfrac{0,2}{3}\)->Al hết O2 dưtính theo Al
=>m O2=\(\dfrac{1}{60}\).32=\(\dfrac{8}{15}\)g
2KMnO4-to>K2MnO4+MnO2+O2
0,4--------------------------------------0,2
m KMnO4=0,4.158=63,2g
.
nP = 6.2/31 = 0.2 (mol)
nO2 = 6.72/22.4 = 0.3 (mol)
4P + 5O2 -to-> 2P2O5
0.2___0.25_____0.1
mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g)
mP2O5 = 0.1*142 = 14.2 (g)
Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)
\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)
PTHH:
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
ta có:
\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)
=> \(O_2\) dư
\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
4 ----------->2
0.2---------->0.1=nP2O5
=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)
\(a.n_P=\dfrac{6,2}{31}=0,2\left(mol\right);n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{to}2P_2O_5\\ Vì:\dfrac{0,2}{4}< \dfrac{0,6}{5}\\ \rightarrow O_2dư.\\ n_{P_2O_5}=\dfrac{2}{4}.0,2=0,1\left(mol\right)\\ m_{P_2O_5}=142.0,1=14,2\left(g\right)\\ b.n_{O_2\left(dư\right)}=0,6-\dfrac{5}{4}.0,2=0,35\left(mol\right)\)
Số phân tử chất còn dư sau phản ứng là:
\(0,35.6.10^{23}=2,1.10^{23}\left(p.tử\right)\)