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\(n_{NaOH}=\dfrac{16.10\%}{40}=0,04\left(mol\right)\\ 2NaOH+SO_2\rightarrow Na_2SO_3+H_2O\\ NaOH+SO_2\rightarrow NaHSO_3\\ Đặt:n_{NaHSO_3}=a\left(mol\right);n_{Na_2SO_3}=1,5a\left(mol\right)\\ \Rightarrow n_{NaOH\left(tổng\right)}=3a+a=4a=0,04\left(mol\right)\\ \Leftrightarrow a=0,01\left(mol\right)\\ n_{SO_2\left(tổng\right)}=n_{Na_2SO_3}+n_{NaHSO_3}=2,5a=0,025\left(mol\right)\\ V_{SO_2\left(đktc\right)}=0,025.22,4=0,56\left(lít\right)\)
a)
$KOH + SO_2 \to KHSO_3$
Theo PTHH : $n_{KOH} = n_{KHSO_3} = n_{SO_2} = 0,4.0,5 = 0,2(mol)$
$V_{SO_2} = 0,2.22,4 = 4,48(lít)$
$C_{M_{KHSO_3}} = \dfrac{0,2}{0,4} = 0,5M$
b)
$2KOH + SO_2 \to K_2SO_3 + H_2O$
$n_{K_2SO_3} = n_{SO_2} = \dfrac{1}{2}n_{KOH} = 0,1(mol)$
$V_{SO_2} = 0,1.22,4 = 2,24(lít)$
$C_{M_{K_2SO_3}} = \dfrac{0,1}{0,4} = 0,25M$
Hòa tan với một lượng xút chứ hk phải súp bạn ơi.
Gọi x là nHCl, y là nH2SO4
nNaOH=0.5.0.04=0.02mol
=>nOH-=0.02mol
PT:
H(+)+OH(-)-->H2O
0.02<0.02
=>nH+ trong 10ml hh axit=0.02
=>nH+ trong 100ml hh axit=0.02.10=0.2mol
PT:
H(+)+OH(-)-->H2O
0.2->0.2
=>nNaOH=0.2mol
m muối=mNa(+)+mCl(-)+mSO4(2-)=23.0.2+35.5x...
< = > 35.5x+96y=8.6 (1)
Ta lại có: nH+=x+2y=0.2 (2)
Từ (1)(2)=>x=0.08, y=0.06.
Vậy [HCl]=0.08M, [H2SO4]=0.06M.
a)
Gọi $n_{Na_2CO_3} = a(mol) \Rightarrow n_{K_2CO_3}= 2a(mol)$
$Na_2CO_3 + 2HCl \to 2NaCl + CO_2 + H_2O$
$K_2CO_3 + 2HCl \to 2KCl + CO_2 + H_2O$
$CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O$
Theo PTHH :
$n_{Na_2CO_3} + n_{K_2CO_3} = n_{CO_2} = n_{CaCO_3} $
$\Rightarrow a + 2a = 0,3$
$\Rightarrow a = 0,1$
$\Rightarrow m_{hh} = 0,1.106 + 0,1.2.138 = 38,2(gam)$
b)
$n_{HCl} =2 n_{Na_2CO_3} + 2n_{K_2CO_3} = 0,6(mol)$
$V_{dd\ HCl} = \dfrac{0,6}{1,5} = 0,4(lít)$
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
______0,2---->0,3------------>0,1------>0,3______(mol)
=> VH2 = 0,3.22,4= 6,72(l)
b) \(C_{M\left(H_2SO_4\right)}=\dfrac{0,3}{0,1}=3M\)
\(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,1}{0,1}=1M\)
Câu 3:
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3(mol)\\ PTHH:Mg+2HCl\to MgCl_2+H_2\\ MgO+2HCl\to MgCl_2+H_2O\\ \Rightarrow n_{Mg}=n_{H_2}=0,3(mol)\\ \Rightarrow \%_{Mg}=\dfrac{0,3.24}{15,2}.100\%=47,37\%\\ \Rightarrow \%_{MgO}=100\%-47,37\%=52,63\%\)
\(n_{MgO}=\dfrac{15,2-0,3.24}{40}=0,2(mol)\\ \Rightarrow \Sigma n_{HCl}=0,3.2+0,2.2=1(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{1.36,5}{10\%}=365(g)\\ \Sigma n_{MgCl_2}=0,2+0,3=0,5(mol)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{0,5.95}{15,2+365}.100\%=12,49\%\)
\(PTHH:Mg+2H_2SO_{4(đ)}\to MgSO_4+2H_2O+SO_2\uparrow\\ MgO+H_2SO_4\to MgSO_4+H_2O\\ \Rightarrow n_{SO_2}=n_{Mg}=0,3(mol)\\ \Rightarrow V_{SO_2}=0,3.22,4=6,72(l)\)
a) \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
\(n_{KOH}=\dfrac{200.11,2\%}{56}=0,4\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,2\left(mol\right)\)
\(m_{ddH_2SO_4}=\dfrac{0,2.98}{10\%}=196\left(g\right)\)
b) \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,2\left(mol\right)\)
\(m_{ddsaupu}=200+196=396\left(g\right)\)
=> \(C\%_{K2SO4}=\dfrac{0,2.174}{396}.100=8,79\%\)
c) \(3KOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3KCl\)
\(n_{FeCl_3}=n_{Fe\left(OH\right)_3}=\dfrac{1}{3}n_{KOH}=\dfrac{2}{15}\left(mol\right)\)
=>\(V_{FeCl_3}=\dfrac{2}{15}=0,13\left(l\right)\)
\(m_{Fe\left(OH\right)_3}=\dfrac{2}{15}.107=14,27\left(g\right)\)
nNaOH=0,2mol
a) PTHH: 2NaOH+H2SO4=> Na2SO4+2H2O
0,2=>0,1
=> V H2SO4=0,1:0,5=0,2l=200ml
b) 2NaOH+SO2=>Na2SO3+H2O
2/15=>1/15
NaOH+SO2=>NaHSO3
1/15=>1/15
=> VSO2=2.1/15.22,4=2,98l