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a, \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
b, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
Theo PT: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=0,2\left(mol\right)\Rightarrow m_{Fe_2O_3}=0,2.160=32\left(g\right)\)
c, \(n_{H_2}=\dfrac{3}{2}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{H_2}=0,6.22,4=13,44\left(l\right)\)
d, \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{H_2}=0,3\left(mol\right)\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)
\(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{20\%}=33,6\left(l\right)\)
a)
$Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O$
b) $n_{Fe} = \dfrac{22,4}{56} = 0,4(mol)$
Theo PTHH : $n_{Fe_2O_3} = \dfrac{1}{2}n_{Fe} = 0,2(mol)$
$m_{Fe_2O_3} = 0,2.160 = 32(gam)$
c) $n_{H_2} = \dfrac{3}{2}n_{Fe} = 0,6(mol)$
$V_{H_2} = 0,6.22,4 = 13,44(lít)$
d) $2H_2 + O_2 \xrightarrow{t^o} 2H_2O$
$V_{O_2} = \dfrac{1}{2}V_{H_2} = 6,72(lít)$
$V_{kk} = 6,72 : 20\% = 33,6(lít)$
\(n_{Fe}=\dfrac{16,8}{56}=0,3mol\)
\(n_{O_2}=\dfrac{5,6}{22,4}=0,25mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
\(\dfrac{0,3}{3}\) < \(\dfrac{0,25}{2}\) ( mol )
0,3 0,2 0,1 ( mol )
Chất dư là O2
\(m_{O_2\left(dư\right)}=\left(0,25-0,2\right).32=1,6g\)
\(m_{Fe_3O_4}=0,1.232=23,2g\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2 dư.
Theo PT: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
\(n_{Fe_2O_3=}=\dfrac{24}{160}=0,15mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
0,15 0,45 0,3 0,45
\(V_{H_2}=0,45\cdot224,=10,08l\)
\(m_{Fe}=0,3\cdot56=16,8g\)
2)
nH2 = 6.72/22.4 = 0.3 (mol)
Fe2O3 + 3H2 -to-> 2Fe + 3H2O
0.1______0.3______0.2
mFe2O3 = 0.1*160 = 16 (g)
mFe = 0.2*56 = 11.2 (g)
3)
nFe3O4 = 11.6/232 = 0.05 (mol)
3Fe + 2O2 -to-> Fe3O4
0.15___0.1______0.05
mFe = 0.15*56 = 8.4 (g)
VO2 = 0.1*22.4 = 2.24 (l)
2KClO3 -to-> 2KCl + 3O2
1/15______________0.1
mKClO3 = 1/15 * 122.5 = 8.167 (g)
a)
3H2 + Fe2O3 --to--> 2Fe + 3H2O
b) nH2 = 6,72/22,4 = 0,3 mol
Từ pt => nFe3O4 = 0,1 mol
=> mFe3O4 = 0,1. 232 = 23,2 g
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
a) 3H2+ Fe2O3→ 3H2O+ 2Fe
(mol) 0,9 0,3 0,6
b) nFe=\(\dfrac{m}{M}=\dfrac{33,6}{56}=0,6\left(mol\right)\)
→ \(V_{H_2}=n.22,4=0,9.22,4=20,16\left(lít\right)\)
\(m_{Fe_2O_3}=n.M=0,3.160=48\left(g\right)\)
c) 3Fe+ 2O2→ Fe3O4
(mol) 0,3 0,2 \(n_{O_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Xét tỉ lệ:
Fe O2
\(\dfrac{0,6}{3}\) > \(\dfrac{0,2}{2}\)
→ Fe dư, O2 phản ứng hết.
→nFe(còn lại)=nFe(ban đầu)-nFe(phản ứng)=0,6-0,3=0,3
=> mFe(còn lại)=n.M=0,3.56=16,8(g)
Vậy sau khi phản ứng Fe dư và dư 16,8g.