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\(\left(-C_6H_{10}O_5-\right)_n+nH_2O\rightarrow nC_6H_{12}O_6\\ C_6H_{12}O_6\underrightarrow{\text{men rượu}}2C_2H_5OH+2CO_2\\ C_2H_5OH+O_2\underrightarrow{\text{men giấm}}CH_3COOH+H_2O\\ CH_3COOH+C_2H_5OH\xrightarrow[t^o]{H_2SO_{4\left(đ\right)}}CH_3COOC_2H_5+H_2O\)
\(4FeS_2+11O_2\rightarrow2Fe_2O_3+8SO_2\)
\(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(2Fe\left(OH\right)_3\rightarrow Fe_2O_3+3H_2O\)
\(H_2O+BaO\rightarrow Ba\left(OH\right)_2\)
Câu 1 :
$2Fe(OH)_3 \xrightarrow{t^o} Fe_2O_3 + 3H_2O$
$Fe_2O_3 + 3CO \xrightarrow{t^o} 2Fe + 3CO_2$
$Fe + 2HCl \to FeCl_2 + H_2$
$FeCl_2 + 2KOH \to Fe(OH)_2 + 2KCl$
Câu 2 :
$a) Zn + 2HCl \to ZnCl_2 + H_2$
b) Theo PTHH : $n_{H_2} = n_{Zn} = \dfrac{32,5}{65} = 0,5(mol)$
$V_{H_2} = 0,5.22,4 = 11,2(lít)$
c) $n_{ZnCl_2} = 0,5(mol) \Rightarrow m_{ZnCl_2} = 136.0,5 = 68(gam)$
d) $n_{HCl} = 2n_{Zn} = 1(mol) \Rightarrow C_{M_{HCl}} = \dfrac{1}{0,4} = 2,5M$
`a)`
`FeCl_3 + 3KOH -> Fe(OH)_3 + 3KCl`
`2Fe(OH)_3 -> (t^o) Fe_2O_3 + 3H_2O`
`Fe_2O_3 + 3CO -> (t^o) 2Fe + 3CO_2`
`3Fe + 2O_2 -> (t^o) Fe_3O_4`
`b)`
`2Al + 6HCl -> 2AlCl_3 + 3H_2O`
`AlCl_3 + 3KOH -> Al(OH)_3 + 3KCl`
`2Al(OH)_3 -> (t^o) Al_2O_3 + 3H_2O`
`2Al_2O_3 -> (đpnc, Criolit) 4Al + 3O_2`
Bs đề câu a: \(Fe_2O_3\xrightarrow{(4)}Fe\)
\(a,(1)2Fe+3Cl_2\xrightarrow{t^o}2FeCl_3\\ (2)FeCl_3+3NaOH\to Fe(OH)_3\downarrow+3NaCl\\ (3)2Fe(OH)_3\xrightarrow{t^o}Fe_2O_3+3H_2O\\ (4)Fe_2O_3+3CO\xrightarrow{t^o}2Fe+3CO_2\)
\(b,(1)4Al+3O_2\xrightarrow{t^o}2Al_2O_3\\ (2)Al_2O_3+6HCl\to 2AlCl_3+3H_2\\ (3)AlCl_3+3NaOH\to Al(OH)_3\downarrow+3NaCl\\ (4)2Al(OH)_3\xrightarrow{t^o}Al_2O_3+3H_2O\)
1)
a)
$C_2H_4 + H_2O \xrightarrow{t^o,xt} C_2H_5OH$
$C_2H_5OH + O_2 \xrightarrow{men\ giấm} CH_3COOH + H_2O$
$CH_3COOH + NaOH \to CH_3COONa + H_2O$
b)
$CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O$
2)
a) $n_{CO_2} = \dfrac{16,8}{22,4} = 0,75(mol)$
$C_6H_{12}O_6 \xrightarrow{men\ rượu} 2CO_2 + 2C_2H_5OH$
$n_{glucozo} = \dfrac{1}{2}n_{CO_2} = 0,375(mol)$
$m_{glucozo} = 0,375.180 = 67,5(gam)$
b) $n_{C_2H_5OH} = n_{CO_2} = 0,75(mol)$
$m_{C_2H_5OH} = 0,75.46 = 34,5(gam)$
$V_{C_2H_5OH} = \dfrac{34,5}{0,8}= 43,125(ml)$
Câu 1:
a, \(C_2H_4+H_2O\underrightarrow{t^o,xt}C_2H_5OH\)
\(C_2H_5OH+O_2\underrightarrow{mengiam}CH_3COOH+H_2O\)
\(CH_3COOH+Na\rightarrow CH_3COOH+\dfrac{1}{2}H_2\)
b, \(CH_3COOH+C_2H_5OH⇌CH_3COOC_2H_5+H_2O\) (xt: H2SO4 đặc, to)
Câu 2:
a, \(n_{CO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
\(C_6H_{12}O_6\underrightarrow{t^o,xt}2C_2H_5OH+2CO_2\)
Theo PT: \(n_{C_6H_{12}O_6}=\dfrac{1}{2}n_{CO_2}=0,375\left(mol\right)\)
\(\Rightarrow m_{C_6H_{12}O_6}=0,375.180=67,5\left(g\right)\)
b, \(n_{C_2H_5OH}=n_{CO_2}=0,75\left(mol\right)\Rightarrow m_{C_2H_5OH}=0,75.46=34,5\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{34,5}{0,8}=43,125\left(ml\right)\)
\(a) 2Fe(OH)_3 \xrightarrow{t^o} Fe_2O_3 + 3H_2O\\ Fe_2O_3 + 3CO \xrightarrow{t^o} 2Fe + 3CO_2\\ 2Fe + 3Cl_2 \xrightarrow{t^o} 2FeCl_3\\ 2FeCl_3 + Fe \rightarrow 3FeCl_2\)
\(b) 6nCO_2 + 5nH_2O \xrightarrow[\text{chất diệp lục}]{\text{ánh sáng}} (-C_6H_{10}O_5-)_n + 6nO_2\\ (-C_6H_{10}O_5-)_n + nH_2O \xrightarrow{axit} nC_6H_{12}O_6\\ C_6H_{12}O_6 \xrightarrow{\text{men rượu}} 2CO_2 + 2C_2H_5OH\\ C_2H_5OH + O_2 \xrightarrow{\text{men giấm}} CH_3COOH + H_2O\)