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\(n_{BaSO_4}=\dfrac{23.3}{233}=0.1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4+H_2O\)
\(n_{BaO}=n_{Ba\left(OH\right)_2}=n_{BaSO_4}=0.1\left(mol\right)\)
\(m_{BaO}=0.1\cdot153=15.3\left(g\right)\)
\(m_{Na_2O}=24.6-15.3=9.3\left(g\right)\)
\(n_{Na_2O}=\dfrac{9.3}{62}=0.15\left(mol\right)\)
\(\%BaO=62.2\%\)
\(\%Na_2O=37.8\%\)
\(2.\)
\(m_{ddX}=24.6+73.7=98.3\left(g\right)\)
\(n_{H_2SO_4}=\dfrac{0.15}{2}+0.1=0.175\left(mol\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{0.175\cdot98\cdot100}{19.6}=87.5\left(g\right)\)
\(m_{ddY}=m_{ddX}+m_{ddH_2SO_4}-m_{\downarrow}=98.3+87.5-23.3=162.5\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{0.075\cdot142}{162.5}\cdot100\%=6.55\%\)
nCH4 = 11.2/22.4 = 0.5 (mol)
CH4 + 2O2 -to-> CO2 + 2H2O
0.5____________0.5
CO2 + Ca(OH)2 => CaCO3 + H2O
0.5_______________0.5
mCaCO3 = 0.5*100 = 50 (g)
\(\text{1. BaCO3-->BaO+Co2}\)
\(\text{ MgCO3-->MgO+CO2}\)
Đặt số mol BaCO3 và MgCO3 là a và b
Ta có :
\(\left\{{}\begin{matrix}\text{197a+84b=3.23}\\\text{153a+40b=2.13}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}\text{a=0.01}\\\text{ b=0.015}\end{matrix}\right.\)
\(\text{->%mBaCO3=0.01*197/3.23=60.99%}\)
\(\text{%mMgCO3=39.11%}\)
\(\text{nCO2=a+b=0.025 nCaCO3=0.02}\)
\(\text{CO2+Ca(OH)2-->CaCO3+H2O}\)
x ...............x.....................x
\(\text{2CO2+Ca(OH)2-->Ca(HCO3)2 }\)
y..............0.5y......................... y
\(\text{x+y=0.025}\Rightarrow\text{x=0.02}\)
->x=0.02 y=0.005
-->nCa(OH)2=0.0225-->cM Ca(OH)2=0.0225/0.5=0.045
2.Thiếu đề
nSO2 = 7.84 / 22.4 = 0.35 (mol)
Ca(OH)2 + SO2 => CaSO3 + H2O
0.35............0.35
C M Ca(OH)2 = 0.35 / 0.25 = 1.4 (M)
a) \(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PTHH: \(n_{Ca\left(OH\right)_2}=n_{CO_2}=0,1\left(mol\right)\)
\(V_{Ca\left(OH\right)_2}=200ml=0,2l\)
\(\Rightarrow C_{MCa\left(OH\right)_2}=\dfrac{n_{Ca\left(OH\right)_2}}{V_{Ca\left(OH\right)_2}}=\dfrac{0,1}{0,2}=0,5M\)
b) Theo PTHH có: \(n_{CaCO_3}=n_{CO_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=n_{CaCO_3}.M_{CaCO_3}=0,1.74=7,4\left(g\right)\)
Bài 8. Trong 300 ml dd Ca(OH)2 có hoà tan 5,18 gam Ca(OH)2. Tính nồng độ mol của dung dịch thu được?
nCa(OH)2 = 0,07(mol)
=> CM Ca(OH)2 = n/V = 0,07 / 0,3 = 0,233(M)
1.\(n_{Ca\left(OH\right)2}=0,09\left(mol\right)\)
\(n\downarrow=n_{CaCO3}=0,04\left(mol\right)\)
\(\Rightarrow n_{CO2}=n_{CaCO3}=0,04\left(mol\right)\)
\(\Rightarrow m_{CO2}=0,04.44=1,76\left(g\right)\)
\(\Rightarrow\)mdd tăng =mCO2+mH2O-m\(\downarrow\)
\(\Leftrightarrow\) 1,82=1,76+mH2O-4
\(\Rightarrow m_{H2O}=4,06\left(g\right)\)
2.
\(n_{NaOH}=0,2\left(mol\right)\)
\(n_{Ba\left(OH\right)2}=0,15\left(mol\right)\)
\(n_{BaCO3}=m_{Ba\left(OH\right)2}=0,15\left(mol\right)\)
\(\Rightarrow n_{OH^-}=0,2+0,15.2=0,5\left(mol\right)\)
\(CO2+OH^-\rightarrow HCO3^-\)
0,2.............0,2
\(CO2+2OH^-\rightarrow CO3^{2-}+H2O\)
0,15......0,3.............0,15
\(n_{CO2}=0,2+0,15=0,35\left(mol\right)\)
\(\Rightarrow V_{CO2}=0,35.22,4=7,84l\)
B1/
nCO2= 2.24/22.4=0.1 mol
Ca(OH)2 + CO2 --> CaCO3 + H2O
0.1_______0.1_______0.1
mCa(OH)2=0.1*74=7.4g
mddCa(OH)2= 7.4*100/5=148g
mCaCO3= 0.1*100=10g
1)
n CO2 = 280/1000.22,4 = 0,0125(mol)
n Ca(OH)2 = 750.0,148%/74 = 0,015(mol)
Vì n CO2 / n Ca(OH)2 = 0,0125/0,015 = 0,83 < 1 nên Ca(OH)2 dư
CO2 + Ca(OH)2 → CaCO3 + H2O
n CaCO3 = n CO2 = 0,0125(mol)
=> m CaCO3 = 0,0125.100 = 1,25(gam)
2)
Ta có :
m CO2 - m CaCO3 = 0,0125.44 -1,25 = -0,7
Suy ra khối lượng dung dịch giảm 0,7 gam
3)
n Ca(OH)2 dư = 0,015 - 0,0125 = 0,0025(mol)
Sau phản ứng :
m dd = 0,0125.44 + 750 - 1,25 = 749,3(gam)
C% Ca(OH)2 = 0,0025.74/749,3 .100% = 0,025%