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\(m_{FeCl_2}=0,5.127=63,5g\)
\(C\%_{FeCl_2}=\dfrac{63,5}{300}.100\%=21,16\%\)
\(m_{FeCl_2}=n.M=0,5.127=63,5\left(g\right)\)
\(C_{\%_{ddFeCl_2}}=\dfrac{m_{FeCl_2}}{m_{ddFeCl_2}}.100\%=\dfrac{63,5}{300}.100\%=21,2\%\)
Ta có : \(n_{CaCl_2.6H_2O}=n_{CaCl_2}=\dfrac{5,475}{219}=0,025\left(mol\right)\)
=> CM CaCl2= \(\dfrac{0,025}{0,1}=0,25M\)
\(n_{Na_2CO_3}=\dfrac{21,2}{106}=0,2\left(mol\right)\)
=> \(C_M=\dfrac{0,2}{0,3}=0,667M\)
\(m_{dd}=300.1,05=315\left(g\right)\)
=> \(C\%=\dfrac{21,2}{315}.100\%=6,73\%\)
\(n_{CuSO_4}=\dfrac{50}{250}=0.2\left(mol\right)\)
\(n_{FeSO_4}=\dfrac{27.8}{278}=0.1\left(mol\right)\)
\(C_{M_{CuSO_4}}=C_{M_{FeSO_4}}=\dfrac{0.1}{0.1964}=0.5\left(M\right)\)
\(m_{dd_A}=50+27.8+196.4=274.2\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{0.1\cdot160}{274.2}\cdot100\%=6.47\%\)
\(C\%_{FeSO_4}=\dfrac{0.1\cdot152}{274.2}\cdot100\%=5.54\%\)
\(n_{CuSO_4.5H_2O}=\dfrac{50}{250}=0,2\left(mol\right)\)
=> \(m_{CuSO_4}=0,2.160=32\left(g\right)\)
\(m_{H_2O}=0,2.5.18=18\left(g\right)\)
\(n_{FeSO_4.7H_2O}=\dfrac{27,8}{278}=0,1\left(mol\right)\)=> \(m_{FeSO_4}=0,1.152=15,2\left(g\right)\)
\(m_{H_2O}=0,1.7.18=12,6\left(g\right)\)
\(m_{dd}=196,4+50+27,8=274,2\left(g\right)\)
\(V_{dd}=\dfrac{196,4+18+12,6}{1000}=0,227\left(l\right)\)
=> \(CM_{CuSO_4}=\dfrac{0,2}{0,227}=0,72M\)
\(C\%_{CuSO_4}=\dfrac{32}{274,2}.100=11,67\%\)
\(CM_{FeSO_4}=\dfrac{0,1}{0,227}=0,44M\)
\(C\%_{CuSO_4}=\dfrac{15,2}{274,2}.100=5,54\%\)
a, \(n_{KOH}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\)
b, \(n_{KOH\left(trong300mlA\right)}=0,3.0,3=0,09\left(mol\right)\)
Gọi: VH2O = a (l)
\(\Rightarrow C_{M_A}=0,2=\dfrac{0,09}{a+0,3}\Rightarrow a=0,15\left(l\right)=150\left(ml\right)\)
\(n_{Na_2CO_3.10H_2O}=\dfrac{28,6}{286}=0,1\left(mol\right)\)
=> nNa2CO3 = 0,1(mol)
=> \(C_M=\dfrac{0,1}{0,2}=0,5M\)
mdd sau pư = 1,05.200 = 210 (g)
=> \(C\%=\dfrac{0,1.106}{210}.100\%=5,05\%\)
\(n_{NaOH}=\dfrac{12.75}{40}=\dfrac{51}{160}\left(mol\right)\)
\(C_{M_{NaOH}}=\dfrac{\dfrac{51}{160}}{0.3}=1.0625\left(M\right)\)