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a) \(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
PTHH: CuO + 2HCl --> CuCl2 + H2O
0,05---->0,1----->0,05--->0,05
=> \(C\%\left(HCl\right)=\dfrac{0,1.36,5}{150}.100\%=2,433\%\)
b) \(C\%\left(CuCl_2\right)=\dfrac{0,05.135}{4+150}.100\%=4,383\%\)
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(n_{H_2}=\dfrac{7,437}{24,79}=0,3\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)
b, \(n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)\Rightarrow C\%_{H_2SO_4}=\dfrac{0,3.98}{120}.100\%=24,5\%\)
c, m dd sau pư = 16,8 + 120 - 0,3.2 = 136,2 (g)
d, \(n_{FeSO_4}=n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{FeSO_4}=\dfrac{0,3.152}{136,2}.100\%\approx33,48\%\)
\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
0,3mol 0,6mol 0,3mol
\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)
Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)
\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
Dung dịch A gồm: CuSO4 và H2SO4 dư
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)
Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?
\(n_{CuO}=\dfrac{8}{80}=0.1\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(0.1...........0.1.........0.1\)
\(n_{NaOH}=0.24\cdot0.5=0.12\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.12..........0.06\)
\(n_{H_2SO_4}=0.1+0.06=0.16\left(mol\right)\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.16}{1}=0.16\left(l\right)\)
\(C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0.06}{0.16}=0.375\left(M\right)\)
\(C_{M_{CuSO_4}}=\dfrac{0.1}{0.16}=0.625\left(M\right)\)
\(a,PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\\ \Rightarrow m_{CuSO_4}=0,1\cdot160=16\left(g\right)\\ b,n_{H_2SO_4}=n_{CuO}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{H_2SO_4}}=0,1\cdot98=9,8\left(g\right)\\ \Rightarrow C\%_{H_2SO_4}=\dfrac{9,8}{200}\cdot100\%=4,9\%\)