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\(n_{H_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(2A+2nH_2O\rightarrow2A\left(OH\right)_n+nH_2\)
\(\dfrac{0.1}{n}........................0.05\)
\(M_A=\dfrac{3.9}{\dfrac{0.1}{n}}=39n\)
Với : \(n=1\rightarrow A=39\)
\(A:K\)
\(m_{KOH}=0.1\cdot56=5.6\left(g\right)\)
\(m_{ddX}=3.9+46.2-0.05\cdot2=50\left(g\right)\)
\(C\%_{KOH}=\dfrac{5.6}{50}\cdot100\%=11.2\%\)
\(b.\)
\(K_2O+H_2O\rightarrow2KOH\)
\(0.1....................0.2\)
\(m_{KOH}=0.2\cdot56=11.2\left(g\right)\)
\(m_{dd_X}=\dfrac{11.2}{28\%\%}=40\left(g\right)\)
- Thấy Cu không phản ứng với HCl .
\(\Rightarrow m_{cr}=m_{Cu}=6,4\left(g\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
.x.......................................1,5x.........
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
.y....................................y.............
Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}27x+56y+6,4=17,4\\1,5x+y=0,4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\) ( mol )
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=5,4\\m_{Fe}=5,6\end{matrix}\right.\) ( g )
b, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
.......0,1.........0,2...............................
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
...0,2.......0,6..........................
\(\Rightarrow n_{NaOH}=0,2+0,6=0,8< 1\)
=> Trong B còn có HCl dư .
\(NaOH+HCl\rightarrow NaCl+H_2O\)
...0,2..........0,2....................
=> Dư 0,2 mol HCl .
\(\Rightarrow n_{HCl}=2n_{H_2}+0,2=1\left(mol\right)\)
\(\Rightarrow m_{ddB}=17,4+250-6,4-0,8=260,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{260,2}.100\%\approx2,8\%\\C\%_{FeCl_2}\approx4,88\%\\C\%_{AlCl_3}\approx10,26\%\end{matrix}\right.\)
Vậy ....
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
a) nHCl = 0,1.1 = 0,1 (mol)
PTHH: 2R + 2H2O --> 2ROH + H2
0,1<---------------0,1---->0,05
ROH + HCl --> RCl + H2O
0,1<--0,1
=> \(M_R=\dfrac{2,3}{0,1}=23\left(g/mol\right)\)
=> R là Na
b) VH2 = 0,05.22,4 = 1,12(l)
a)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
b)
PTHH: 2R + 2H2O --> 2ROH + H2
_____0,2<--------------0,2<----0,1
=> \(M_R=\dfrac{7,8}{0,2}=39\left(K\right)\)
c)
\(C_{M\left(KOH\right)}=\dfrac{0,2}{0,5}=0,4M\)
\(Zn+2HCl->ZnCl_2+H_2\\ Fe+2HCl->FeCl_2+H_2\\n_{Zn}=a;n_{Fe}=b\\ 65a+56b=2,1\\ 2\left(a+b\right)=0,4\\ a=-1,011;b=1,211\)
Đáp số ra số âm, không thoả mãn điều kiện thực tế a, b > 0.
\(\text{2R+2H2O->2ROH+H2}\)
\(\text{ROH+HCl->RCl+H2O}\)
nROH=nHCl=0,2.1=0,2(mol)
nH2=\(\frac{nROH}{2}\)=\(\frac{0,2}{2}\)=0,1(mol)
V=0,1.22,4=2,24(l)
\(\text{nR=nROH=0,2(mol)}\)
\(\text{=>MR=7,8/0,2=39(g)}\)
R là Kali(K)
\(\text{2KOH+CuSO4->Cu(OH)2+K2SO4}\)
\(\text{nCuSO4=0,3x0,5=0,15(mol)}\)
=>nCuSO4 dư=0,15-0,1=0,05(mol)
m kết tủa =0,1.98=9,8(g)
\(\left\{{}\begin{matrix}\text{CMK2SO4=0,1/0,5=0,2(M)}\\\text{CMCuSO4=0,05/0,5=0,1(M)}\end{matrix}\right.\)