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a. \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH : 3Fe + 2O2 -to> Fe3O4
0,3 0,2 0,1
b. \(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c. \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
a \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b \(\Rightarrow n_{Fe}=\dfrac{16,8}{56}=0,3mol\) \(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1mol\Rightarrow m_{Fe_3O_4}=0,1\cdot232=2,32g\)
c \(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2mol\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_{\text{4}}\)
0,15 0,1 0,05
\(m_{Fe_2O_4}=0,05.232=11,6\left(g\right)\\
V_{O_2}=0,1.11,4=2,24\left(l\right)\\
pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1
\(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ pthh:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,15 0,1 0,05
\(m_{Fe_3O_{\text{ 4}}}=0,05.232=11,6\left(g\right)\\ V_{O_2}=0,1.22,4=2,24\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
0,1 0,05
\(m_{KMnO_4}=0,1.158=15,8\left(g\right)\)
\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\a,3 Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ b,n_{O_2}=\dfrac{2}{3}.0,2=\dfrac{2}{15}\left(mol\right)\\ V_{O_2\left(đktc\right)}=\dfrac{2}{15}.22,4=\dfrac{224}{75}\left(lít\right)\)
Bài 3 :
PTHH : \(6Fe+4O_2\left(t^o\right)->2Fe_3O_4\) (1)
\(n_{Fe_3O_4}=\dfrac{m}{M}=\dfrac{2,32}{56.3+16.4}=0,01\left(mol\right)\)
Từ (1) => \(3n_{Fe_3O_4}=n_{Fe}=0,03\left(mol\right)\)
=> \(m_{Fe}=n.M=1,68\left(g\right)\)
Từ (1) => \(2n_{Fe_3O_4}=n_{O_2}=0,02\left(mol\right)\)
=> \(V_{O_2\left(đktc\right)}=n.22,4=0,448\left(l\right)\)
Bài 4 :
PTHH : \(4P+5O_2\left(t^o\right)->2P_2O_5\) (1)
\(n_P=\dfrac{m}{M}=\dfrac{6,2}{31}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{6,72}{32}=0,21\left(mol\right)\)
Có : \(n_P< n_{O_2}\left(0,2< 0,21\right)\)
-> P hết ; O2 dư
Từ (1) -> \(\dfrac{1}{2}n_P=n_{P_2O_5}=0,1\left(mol\right)\)
=> \(m_{P_2O_5}=n.M=14,2\left(g\right)\)
Bài 3:
\(n_{Fe_3O_4}=\dfrac{2,32}{232}=0,01\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to→ Fe3O4
Mol: 0,03 0,02 0,01
\(m_{Fe}=0,03.56=1,68\left(g\right);V_{O_2}=0,02.22,4=0,448\left(l\right)\)
a) \(n_{Fe}=\dfrac{3,36}{56}=0,06\left(mol\right)\)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,06->0,04------->0,02
=> mFe3O4 = 0,02.232 = 4,64 (g)
b) VO2 = 0,04.22,4 = 0,896 (l)
PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,2mol\\n_{Fe_3O_4}=0,1mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_3O_4}=0,1\cdot232=23,2\left(g\right)\\V_{O_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
\(n_{O_2}=\dfrac{0.896}{22.4}=0.04\left(mol\right)\)
\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)
\(0.06......0.04.......0.02\)
\(m_{Fe}=0.06\cdot56=3.36\left(g\right)\)
\(m_{Fe_2O_3}=0.02\cdot232=4.64\left(g\right)\)
\(n_{Fe}=\dfrac{25,2}{56}=0,45\left(mol\right)\\ a,PTHH:3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ b,n_{O_2}=\dfrac{2}{3}.0,45=0,3\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.0,2=24,5\left(g\right)\)
3Fe + 2O3 \(\rightarrow\)Fe3O4
Ta có: nFe=\(\frac{16,8}{56}\)=0,3 mol
Theo ptpu: nO2=\(\frac{2}{3}\)nFe=\(\frac{2}{3}\) .0,3=0,2 mol
\(\rightarrow\)\(\text{V O2=0,2.22,4=4,48 lít}\)