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2KMnO4-to>K2MnO4+MnO2+O2
0,3-----------------0,15-----0,15------0,15 mol
n KMnO4=\(\dfrac{47,4}{158}\)=0,3 mol
=>mcr=0,15.197.0,15.87=42,6g
=>VO2=0,15.22,4=3,36l
b) 4P+5O2-to>2P2O5
0,1--------------0,05
nP=\(\dfrac{3,1}{31}\)=0,1 mol
->O2 dư
=>m P2O5=0,05.142=7,1g
mKMnO4 = 47,4/158 = 0,3 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: 0,3 ---> 0,15 ---> 0,15 ---> 0,15
m = 0,15 . 197 + 0,15 . 87 = 85,2 (g)
V = VO2 = 0,15 . 22,4 = 3,36 (l)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,1/4 < 0,15/5 => O2 dư
nP2O5 = 0,1/2 = 0,05 (mol)
mP2O5 = 0,05 . 142 = 7,1 (g)
2KMnO4-to>K2MnO4+MnO2+O2
1------------------0,5---------0,5----0,5 mol
n O2=\(\dfrac{11,2}{22,4}\)=0,5 mol
=>x =m KMnO4=1.158=158g
=>mA=m K2MnO4+mMnO2=0,5.197+0,5.87=142g
a)
2KMnO4 --to--> K2MnO4 + MnO2 + O2
2Cu + O2 --to--> 2CuO
b)
\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
=> \(n_{O_2}=0,1\left(mol\right)\)
=> \(V_{O_2}=0,1.22,4=2,24\left(l\right)\)
c) \(n_{KMnO_4}=0,2\left(mol\right)\)
=> \(m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
Gọi a , b là số mol của KClO3 và KMnO4
TH1: Y có CO2 , N2 , O2 dư
2KClO3 ➝ 2KCl + 3O2
2KMnO4 ➝ K2MnO4 + MnO2 + O2
Gọi nO2 = x => \(\dfrac{nO_{2_{ }}}{_{ }kk}\) = 3x . 0,2 = 0,6x
nN2 = 3x.0,8 = 2,4x
C + O2 ➝ CO2
nCO2 = nC = \(\dfrac{0,528}{12}\) = 0,044
hh khí gồm : nCO2 = 0,044 ; nO2 = 1,6x - 0,044 ; nN2 = 2,4x
=> 0,044 + 1,6x - 0,044 + 2,4x = \(\dfrac{0,044.100}{22,92}\)
<=> x = 0,048
=> mhh đầu = mY + mO2 = \(\dfrac{0,894.100}{8,132}\) + 0,048.32 = 12,53
TH 2 : Y có CO , CO2 ; N2
Bảo toàn C : nCO + nCO2 = nC = 0,044 => nCO = 0,044 - nCO2
Bảo toàn O : 0,5.nCO + nCO2 = nO2 = 1,6a
⇒ 0,5.( 0,044 - nCO2 ) + nCO2 = 1,6a => nCO2 = 3,2a - 0,044
Tổng mol hh : nCO + nCO2 + nN2 = 0,044 + 2,4a
=> \(\dfrac{3,2a-0,044}{0,044+2,4a}\) = \(\dfrac{22,92}{100}\)
a ≈0.02
=> m = m rắn + mO2 = \(\dfrac{0,894.100}{8,132}\) + 0,02 . 32 = 11,646 ( g )
a)nO2=\(\dfrac{3.36}{22.4}\)=0,15(mol)
2KMnO4(to)→K2MnO4+MnO2+O2
Theo PT: nKMnO4=2nO2=0,3(mol)
→m=mKMnO4=0,3.158=47,4(g)
b)nH2=\(\dfrac{8.96}{22.4}\)=0,4(mol)
2H2+O2(to)→2H2O
Vì \(\dfrac{nH_2}{2}\)<nO2→O2nH2 dư
Theo PT: nH2O=nH2=0,4(mol)
→mH2O=0,4.18=7,2(g)
a.\(n_{Al}=\dfrac{m_{Al}}{M_{Al}}=\dfrac{5,4}{27}=0,2mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
4 3 2 ( mol )
0,2 0,1
\(m_{Al_2O_3}=n_{Al_2O_3}.M_{Al_2O_3}=0,1.102=10,2g\)
b.\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2mol\)
\(n_{O_2}=\dfrac{V}{22,4}=\dfrac{2,24}{22,4}=0,1mol\)
\(4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\)
4 3 2
0,2 < 0,1 ( mol )
0,1 1/15
\(m_{Al_2O_3}=n.M=\dfrac{1}{15}.102=6,8g\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH : 4Al + 3O2 -> 2Al2O3
0,2 0,1
\(m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)
b. \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH : 4Al + 3O2 -> 2Al2O3
0,1 \(\dfrac{0,2}{3}\)
Xét tỉ lệ : \(\dfrac{0,2}{4}>\dfrac{0,1}{3}\) => Al dư , O2 đủ
\(m_{Al_2O_3}=\dfrac{0,2}{3}.102=6,8\left(g\right)\)
a) Gọi số mol KMnO4, KClO3 là a, b (mol)
=> \(\left\{{}\begin{matrix}n_K=a+b\left(mol\right)\\n_{Mn}=a\left(mol\right)\\n_{Cl}=b\left(mol\right)\\n_O=4a+3b\left(mol\right)\end{matrix}\right.\)
Có \(n_O=\dfrac{9}{14}\Sigma_n\)
=> \(4a+3b=\dfrac{9}{14}\left(a+b+a+b+4a+3b\right)\)
=> \(\dfrac{1}{7}a-\dfrac{3}{14}b=0\) (1)
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
a------------------------------->0,5a
2KClO3 --to--> 2KCl + 3O2
b------------------>1,5b
=> \(0,5a+1,5b=\dfrac{10,08}{22,4}=0,45\) (2)
(1)(2) => a = 0,3 (mol); b = 0,2 (mol)
=> m = 0,3.158 + 0,2.122,5 = 71,9 (g)
b) \(\left\{{}\begin{matrix}\%m_{KMnO_4}=\dfrac{0,3.158}{71,9}.100\%=65,925\%\\\%m_{KClO_3}=\dfrac{0,2.122,5}{71,9}.100\%=34,075\%\end{matrix}\right.\)
2KMnO4-to>K2MnO4+MnO2+O2
0,2--------------------------------------0,1 mol
n O2=\(\dfrac{2,24}{22,4}\)=0,1 mol
=>m KMnO4=0,2.158=31,6g
nO2 = 2,24/22,4 = 0,1 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: 0,2 <--- 0,1 <--- 0,1 <--- 0,1
mKMnO4 = 0,2 . 158 = 31,6 (g)