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\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ Mol:0,1\rightarrow0,075\rightarrow0,05\\ \rightarrow\left\{{}\begin{matrix}V_{kk}=\dfrac{0,075.22,4}{20\%}=8,4\left(l\right)\\m_{Al_2O_3}=0,05.102=5,1\left(g\right)\end{matrix}\right.\)
nFe = 46,4/56 = 29/35 (mol)
PTHH: 4Fe + 3O2 -> (t°) 2Fe2O3
Mol: 29/35 ---> 87/140 ---> 29/70
mFe2O3 = 29/70 . 160 = 464/7 (g)
Vkk = 87/140 . 5 . 22,4 = 69,6 (l)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,6\left(mol\right)\Rightarrow V_{O_2}=0,6.22,4=13,44\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,3\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,3.232=69,6\left(g\right)\)
d, \(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=0,4\left(mol\right)\Rightarrow m_{KClO_3}=0,4.122,5=49\left(g\right)\)
\(n_{Fe}=\dfrac{m}{M}=\dfrac{50,4}{56}=0,9\left(mol\right)\)
\(a.PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
3 2 1
0,9 0,6 0,3
\(b.V_{O_2}=n.24,79=0,6.24,79=14,874\left(l\right)\)
\(c.m_{Fe_3O_4}=n.M=0,3.\left(56.3+16.4\right)=69,6\left(g\right)\)
\(d.V_{O_2}=14,874\left(l\right)\\ \Rightarrow n_{O_2}=\dfrac{V}{24,79}=\dfrac{14,874}{24,79}=0,6\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
2 2 3
0,6 0,6 0,9
\(m_{KClO_3}=n.M=0,6.\left(39+35,5+16.3\right)=55,5\left(g\right).\)
$a\big)$
$n_{Fe}=\frac{16,8}{56}=0,3(mol)$
$3Fe+2O_2\xrightarrow{t^o}Fe_3O_4$
Theo PT: $n_{Fe_3O_4}=\frac{1}{3}n_{Fe}=0,1(mol)$
$\to m_{Fe_3O_4}=0,1.232=23,2(g)$
$b\big)$
Theo PT: $n_{O_2}=\frac{2}{3}n_{Fe}=0,2(mol)$
$\to V_{O_2}=0,2.22,4=4,48(l)$
$\to V_{kk}=4,48.5=22,4(l)$
$c\big)$
$2KMnO_4\xrightarrow{t^o}K_2MnO_4+MnO_2+O_2$
Theo PT: $n_{KMnO_4}=2n_{O_2}=0,4(mol)$
$\to m_{KMnO_4(dùng)}=\frac{0,4.158}{80\%}=79(g)$
a, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to→ Fe3O4
Mol: 0,3 0,2 0,1
\(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
b, \(V_{O_2}=0,2.22,4=4,48\left(l\right)\Rightarrow V_{kk}=4,48.5=22,4\left(l\right)\)
c,
PTHH: 2KMnO4 ---to→ K2MnO4 + MnO2 + O2
Mol: 0,4 0,2
\(m_{KMnO_4\left(lt\right)}=0,4.158=63,2\left(g\right)\)
\(\Rightarrow m_{KMnO_4\left(tt\right)}=\dfrac{63,2}{80\%}=79\left(g\right)\)
nFe = 16.8/56 = 0.3 (mol)
3Fe + 2O2 -to-> Fe3O4
0.3......0.2...........0.1
VO2 = 0.2*22.4 = 4.48 (l)
mFe3O4 = 0.1*232 = 23.2 (g)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ Mol:0,4\rightarrow\dfrac{4}{15}\rightarrow\dfrac{2}{15}\)
\(\rightarrow\left\{{}\begin{matrix}V_{O_2}=\dfrac{4}{15}.22,4=\dfrac{448}{75}\left(l\right)\rightarrow V_{kk}=\dfrac{448}{75}.5=\dfrac{448}{15}\left(l\right)\\m_{Fe_3O_4}=\dfrac{2}{15}.232=\dfrac{464}{15}\left(g\right)\end{matrix}\right.\)
2KClO3 --to--> 2KCl + 3O2
\(\dfrac{8}{45}\) \(\dfrac{4}{15}\)
\(m_{KClO_3}=\dfrac{8}{45}.122,5=\dfrac{196}{9}\left(g\right)\)
a, \(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
PTHH: 3Fe + 2O2 ---to---> Fe3O4
Mol: 0,4 \(\dfrac{0,8}{3}\) \(\dfrac{0,4}{3}\)
b, \(V_{O_2}=\dfrac{0,8}{3}.22,4=5,973\left(l\right)\)
c, \(V_{kk}=\dfrac{448}{75}.5=29,867\left(l\right)\)
d, \(m_{Fe_3O_4}=\dfrac{0,4}{3}.232=30,93\left(g\right)\)
e,
PTHH: 2KClO3 ---to---> 2KCl + 3O2
Mol: \(\dfrac{0,16}{9}\) \(\dfrac{0,8}{3}\)
\(m_{KClO_3}=\dfrac{0,16}{9}.122,5=2,178\left(g\right)\)
\(n_{Fe}=\dfrac{33,6}{56}=0,6mol\)
\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,6 0,4 0,2 ( mol )
\(V_{kk}=0,4.22,4.5=44,8l\)
\(m_{Fe_3O_4}=0,2.232=46,4g\)
nFe = 33,6 : 56 = 0,6 (mol)
pthh : 3Fe + 2O2 -t--> Fe3O4
0,6--> 0,4------->0,2 (mol)
=> vO2 = 0,4.22,4 = 8,96 (mol)
=> mFe3O4 = 0,2.232 = 46,4 (g)
pthh : 2KClO3 -t--> 2KClO3 + 3O2
0,267<-----------------------0,4(mol)
mKClO3= 0,267 .122,5 = 32,67 (g)
a, \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2\left(mol\right)\Rightarrow V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1\left(mol\right)\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H2 dư.
Theo PT: \(n_{Cu}=n_{CuO}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)
nFe = 16,8/56 = 0,3 (mol)
PTHH: 3Fe + 2O2 -> (t°) Fe3O4
Mol: 0,3 ---> 0,2 ---> 0,1
mFe3O4 = 0,1 . 232 = 23,2 (g)
Vkk = 0,2 . 5 . 22,4 = 22,4 (l)
\(n_{Fe}=\dfrac{16,8}{56}=0,3mol\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,3 0,2 0,1
a)\(m_{Fe_3O_4}=0,1\cdot232=23,2g\)
b)\(V_{O_2}=0,2\cdot22,4=4,48l\)
\(\Rightarrow V_{kk}=5V_{O_2}=5\cdot4,48=22,4l\)