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a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b, Ta có: \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,2}{1}\), ta được H2 dư.
Theo PT: \(n_{H_2\left(pư\right)}=n_{Cu}=n_{H_2O}=n_{CuO}=0,15\left(mol\right)\)
\(\Rightarrow n_{H_2\left(dư\right)}=0,2-0,15=0,05\left(mol\right)\Rightarrow m_{H_2\left(dư\right)}=0,05.2=0,1\left(g\right)\)
\(m_{Cu}=0,15.64=9,6\left(g\right)\)
\(m_{H_2O}=0,15.18=2,7\left(g\right)\)
\(a.n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ b.n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ CuO+H_2-^{t^o}\rightarrow Cu+H_2O\\ LTL:\dfrac{0,15}{1}< \dfrac{0,2}{1}\\ \Rightarrow H_2dưsauphảnứng\\ n_{Cu}=n_{H_2\left(pứ\right)}=n_{H_2O}=n_{CuO}=0,15\left(mol\right)\\ m_{Cu}=0,15.64=9,6\left(g\right)\\ m_{H_2\left(dư\right)}=\left(0,2-0,15\right).2=0,1\left(g\right)\\ m_{H_2O}=0,15.18=2,7\left(g\right)\)
nZn = 13/65 = 0,2 (mol)
PTHH: Zn + 2HCl -> ZnCl2 + H2
Mol: 0,2 ---> 0,4 ---> 0,2 ---> 0,2
mZnCl2 = 0,2 . 136 = 27,2 (g)
VH2 = 0,2 . 22,4 = 4,48 (l)
nCuO = 12/80 = 0,15 (mol)
PTHH: CuO + H2 -> (t°) Cu + H2O
LTL: 0,15 < 0,2 => H2 dư
nCuO (p/ư) = nCu = nH2O = nCuO = 0,15 (mol)
mCu = 0,15 . 64 = 9,6 (g)
mH2O = 0,15 . 18 = 2,7 (g)
mCuO (dư) = (0,2 - 0,15) . 80 = 4 (g)
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{18,56}{232}=0,08\left(mol\right)\)
PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Xét tỉ lệ: \(\dfrac{0,08}{1}>\dfrac{0,2}{4}\), ta được Fe3O4 dư.
Theo PT: \(n_{Fe}=\dfrac{3}{4}n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(n_{KMnO_4}=\dfrac{31,6}{158}=0,2mol\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,2 0,1 0,1 0,1
a)\(V_{O_2}=0,1\cdot22,4=2,24l\)
b)\(m_{CRắn}=m_{K_2MnO_4}+m_{MnO_2}=0,1\cdot197+0,1\cdot87=28,4g\)
c)\(n_{CH_4}=\dfrac{11,2}{22,4}=0,5mol\)
\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
0,5 0,1 0 0
0,05 0,1 0,05 0,1
0,45 0 0,05 0,1
\(V_{CO_2}=0,05\cdot22,4=1,12l\)
\(m_{H_2O}=0,1\cdot18=1,8g\)
PTHH: 2KMnO4--to-> K2MnO4+MnO2+O2
0,2----------------0,1---------0,1-----0,1
b, nKMnO4= \(\dfrac{31,6}{158}\)=0,2 mol
Theo pt: nO2=\(\dfrac{1}{2}\).0,2=0,1 mol
=> VO2= 0,1.22,4= 2,24 l
=>m cr=0,1.197+0,1.87=28,4g
CH4+2O2-to>CO2+2H2O
0,5-----0,25-----0,5
n CH4=\(\dfrac{11,2}{22,4}\)=0,5 mol
=>Oxi du
=>V CO2=0,25.22,4=5,6l
=>m H2O=0,5.18=9g
mMg = 3.6/24 = 0.15 (mol)
2Mg + O2 -to-> 2MgO
0.15__0.075____0.15
mMgO= 0.15*40 = 6 (g)
VO2 = 0.075*22.4 = 1.68 (l)
2KClO3 -to-> 2KCl + 3O2
0.05_______________0.075
mKClO3 = 0.05*122.5 = 6.125 (g)
PTHH: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
a+b) Ta có: \(n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{O_2}=0,075\left(mol\right)\\n_{MgO}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{O_2}=0,075\cdot22,4=1,68\left(l\right)\\m_{MgO}=0,15\cdot40=6\left(g\right)\end{matrix}\right.\)
c) PTHH: \(2KClO_3\xrightarrow[MnO_2]{t^o}2KCl+3O_2\uparrow\)
Theo PTHH: \(n_{KClO_3}=0,05\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=0,05\cdot122,5=6,125\left(g\right)\)
1.\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,2 ( mol )
\(V_{H_2}=0,2.22,4=4,48l\)
2.\(n_{CuO}=\dfrac{12}{80}=0,15mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,15 < 0,2 ( mol )
0,15 0,15 ( mol )
\(m_{Cu}=0,15.64=9,6g\)
a.b.\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1mol\)
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,1 0,05 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12l\)
c.\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)
0,05 0,025 ( mol )
\(m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=0,025.232=5,8g\)
a) nKClO3 = 24,5/122,5 = 0,2 (mol)
PTHH: 2KClO3 -> (t°, MnO2) 2KCl + 3O2
Mol: 0,2 ---> 0,2 ---> 0,3
VO2 = 0,3 . 22,4 = 6,72 (l)
b) mKCl = 0,2 . 74,5 = 14,9 (g)
c) nZn = 13/65 = 0,2 (mol)
PTHH: 2Zn + O2 -> (t°) 2ZnO
LTL: 0,2/2 < 0,3 => O2 dư
nZnO = 0,2 (mol)
mZnO = 0,2 . 81 = 16,2 (g)