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2KClO3-to\xt->2KCl+3O2
0,1------------------0,1
n KClO3=\(\dfrac{12,25}{122,5}\)=0,1 mol
=>m KCl=0,1.74,5=7,45g
H=\(\dfrac{6,8}{7,45}.100\)=91,275%
b)
2KClO3-to\xt->2KCl+3O2
0,2-------------------------0,3 mol
n O2=\(\dfrac{6,72}{22,4}\)=0,3 mol
H=85%
=>m KClO3=0,2.122,5.\(\dfrac{100}{85}\)=28,82g
c)
2KClO3-to\xt->2KCl+3O2
0,2------------------------0,3
n KClO3=\(\dfrac{24,5}{122,5}\)=0,2 mol
H=80%
=>m O2=0,3.32.\(\dfrac{80}{100}\)=10,4g
a) 2KClO3 --to--> 2KCl + 3O2
b) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,1<----------0,1<---0,15
=> \(m_{KClO_3}=0,1.122,5=12,25\left(g\right)\)
c) \(m_{KCl}=0,1.74,5=7,45\left(g\right)\)
a) \(2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\)
b)
\(n_{KClO_3} = \dfrac{36,75}{122,5} = 0,3(mol)\)
Theo PTHH :
\(n_{KCl} = n_{KClO_3} = 0,3(mol)\\ \Rightarrow m_{KCl} = 0,3.74,5 = 22,35(gam)\\ \Rightarrow m_{O_2} = m_{KClO_3} - m_{KCl} = 14,4(gam)\)
c)
Bảo toàn khối lượng :
\(m_{O_2} = 25 - 15,4 = 9,6(gam)\\ \Rightarrow n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{KClO_3} = 0,2.122,5 = 24,5(gam)\\ \%m_{tạp\ chất}= \dfrac{25-24,5}{25}.100\% = 2\%\)
\(a.\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(b.\)
\(n_{KClO_3}=\dfrac{36.75}{122.5}=0.3\left(mol\right)\)
\(\Rightarrow n_{O_2}=\dfrac{3}{2}n_{KClO_3}=\dfrac{3}{2}\cdot0.3=0.45\left(mol\right)\)
\(m_{O_2}=0.45\cdot32=14.4\left(g\right)\)
\(m_{KCl}=0.3\cdot74.5=22.35\left(g\right)\)
\(c.\)
\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)
\(a.............a\)
\(m_{Cr}=m_{KCl}+m_{tc}=25-122.5a+74.5a=15.4\left(g\right)\)
\(\Rightarrow a=0.2\)
\(m_{O_2}=\dfrac{3}{2}\cdot0.2\cdot32=9.6\left(g\right)\)
\(m_{KClO_3}=0.2\cdot122.5=24.5\left(g\right)\)
\(m_{tc}=25-24.5=0.5\left(g\right)\)
\(\%m_{Tc}=\dfrac{0.5}{25}\cdot100\%-2\%\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\left(1\right)\\ PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\left(2\right)\)
\(Gọi.số.mol.của.O_2.là:a\)
\(Theo.PTHH\left(1\right):n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.a=\dfrac{2a}{3}\\ m=m_{KClO_3}=n.M=\dfrac{2a}{3}.122,5=\dfrac{245a}{3}\left(g\right)\)
\(Theo.PTHH\left(2\right):n_{KMnO_4}=2.n_{O_2}=2.a=2a\\ x=m_{KMnO_4}=n.M=2a.158=316a\left(g\right)\)
\(Tỉ.lệ:m:x:\dfrac{m}{x}=\dfrac{\dfrac{245a}{3}}{316a}=\dfrac{245}{948}\)
Câu 6.
\(n_{O_2}=\dfrac{16,8}{22,4}=0,75mol\)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
1,5 0,75
\(m_{KMnO_4}=1,5\cdot158=237g\)
Câu 7.
\(n_{Fe_3O_4}=\dfrac{4,64}{232}=0,02mol\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
0,04 0,02
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)
\(\dfrac{2}{75}\) 0,04
\(m_{KClO_3}=\dfrac{2}{75}\cdot122,5=\dfrac{49}{15}\approx3,27g\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\\ n_{O_2}=\dfrac{V_{\left(đktc\right)}}{22,4}=\dfrac{67,2}{22,4}=3\left(mol\right)\\ Theo.PTHH:n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.3=2\left(mol\right)\\ m_{KClO_3}=n.M=2.122,5=245\left(g\right)\)
