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Ta có: \(C_{\%_{KOH}}=\dfrac{m_{KOH}}{112}.100\%=56\%\)
=> mKOH = 62,72(g)
=> \(n_{KOH}=\dfrac{62,72}{56}=1,12\left(mol\right)\)
a. PTHH: 2KOH + MgCl2 ---> Mg(OH)2↓ + 2KCl
Theo PT: \(n_{Mg\left(OH\right)_2}=\dfrac{1}{2}.n_{KOH}=\dfrac{1}{2}.1,12=0,56\left(mol\right)\)
=> \(m_{Mg\left(OH\right)_2}=0,56.58=32,48\left(g\right)\)
b. Theo PT: \(n_{MgCl_2}=n_{Mg\left(OH\right)_2}=0,56\left(mol\right)\)
=> \(m_{MgCl_2}=0,56.95=53,2\left(g\right)\)
=> \(C_{\%_{MgCl_2}}=\dfrac{53,2}{200}.100\%=26,6\%\)
a)PTHH: ZnCl2+2KOH---->Zn(OH)2+2KCl
b)
mZnCl2=204.10100=20,4(g)ZnCl2=204.10100=20,4(g)
nZnCl2=20,4136=0,15(mol)ZnCl2=20,4136=0,15(mol)
nKOH=112.20%56=0,4(mol)KOH=112.20%56=0,4(mol)
=> 0,15/1 < 0,4/1=> KOH dư
Theo pthh, ta có :
nCu(OH)2=nZnCl2=0,15(mol)Cu(OH)2=nZnCl2=0,15(mol)
mCu(OH)2=0,15.98=14,7(g)Cu(OH)2=0,15.98=14,7(g)
c) m dd sau pư=204+112=316(g)
Theo pthh
nKOH=2nZnCl2=0,3(mol)KOH=2nZnCl2=0,3(mol)
C% KOH=0,3.56326.100%=5,32%0,3.56326.100%=5,32%
nKCl=2nZnCl2=0,3(mol)KCl=2nZnCl2=0,3(mol)
C% KCl=0,3.74,5316.100%=7,07%
Gọi: \(\left\{{}\begin{matrix}n_{FeCl_3}=x\left(mol\right)\\n_{MgCl_2}=y\left(mol\right)\end{matrix}\right.\)
PT: \(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_{3\downarrow}+3KCl\)
______x_________3x_________x (mol)
\(MgCl_2+2KOH\rightarrow Mg\left(OH\right)_{2\downarrow}+2KCl\)
____y_________2y_________y (mol)
Ta có: \(n_{KOH}=0,2.2,5=0,5\left(mol\right)\)
⇒ 3x + 2y = 0,5 (1)
m kết tủa = 16,5 ⇒ 107x + 58y = 16,5 (2)
Từ (1) và (2) ⇒ x = y = 0,1 (mol)
\(\Rightarrow C_{M_{FeCl_3}}=C_{M_{MgCl_2}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)
\(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_3\downarrow+3KCl\\ MgCl_2+2KOH\rightarrow Mg\left(OH\right)_2\downarrow+2KCl\)
\(n_{KOH}=0,2\cdot2,5=0,5\left(mol\right)\)
Đặt nFeCl₃ trong 500ml X là a mol, nMgCl₂ trong 500ml X là b mol
\(\Rightarrow\left\{{}\begin{matrix}3a+2b=0,5\\107a+58b=16,5\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(\Rightarrow C_MFeCl_3=\dfrac{0,1}{0,5}=0,2\left(M\right)\\ C_MMgCl_2=\dfrac{0,1}{0,5}=0,2\left(M\right)\)
\(a,\left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\\ PTHH:H_2SO_4+BaCl_2\rightarrow2HCl+BaSO_4\downarrow\)
Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên sau phản ứng \(H_2SO_4\) dư
\(\Rightarrow n_{BaSO_4}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\)
\(b,n_{HCl}=2n_{BaCl_2}=0,5\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,5\cdot36,5=18,25\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{18,25}{441,75}\cdot100\%\approx4,13\%\)
PTHH: \(K_2SO_3+2HCl\rightarrow2KCl+H_2O+SO_2\uparrow\)
a+b+c) Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KCl}=0,5\left(mol\right)=n_{HCl}\\n_{K_2SO_3}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_3}=0,25\cdot158=39,5\left(g\right)=a\\m_{KCl}=0,5\cdot74,5=37,25\left(g\right)\\m_{ddHCl}=\dfrac{0,5\cdot36,5}{10,95\%}\approx166,67\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{SO_2}=0,25\cdot64=16\left(g\right)\)
\(\Rightarrow m_{dd}=m_{K_2SO_3}+m_{ddHCl}-m_{SO_2}=190,17\left(g\right)\) \(\Rightarrow C\%_{KCl}=\dfrac{37,25}{190,17}\cdot100\%\approx19,59\%\)
d) PTHH: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Theo PTHH: \(n_{NaOH}=n_{HCl}=0,5\left(mol\right)\) \(\Rightarrow V_{NaOH}=\dfrac{0,5}{0,5}=1\left(l\right)\)
nKOH = 0,075 nMgCl2 = 0,05 => MgCl2 dư
2KOH + MgCl2 => 2KCl + Mg(OH)2
=> n Mg(OH)2 = 1/2nKOH = 0,0375
=> m Mg(OH)2 = 2,175 (g)
c% MgCl2 dư = 0,95%
C% KCl = 4,47%
Sao lại không tính C% của Mg(OH)2