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\(n_{OH^-}=0,5.0,2+0,2.2.0,3=0,22\left(mol\right)\Rightarrow\left[OH^-\right]=\dfrac{0,22}{0,5}=0,44M\)
\(n_{Na^+}=0,5.0,2=0,1\left(mol\right)\Rightarrow\left[Na^+\right]=\dfrac{0,1}{0,5}=0,2M\)
\(n_{Ba^{2+}}=0,2.0,3=0,06\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,06}{0,5}=0,12M\)
a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)
b, Để trung hòa dung dịch A thì:
\(n_{H^+}=n_{OH^-}\)
\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)
\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)
\(n_{HNO_3}=0.25\cdot2=0.5\left(mol\right)\)
\(n_{Ca\left(OH\right)_2}=0.25\cdot1=0.25\left(mol\right)\)
\(Ca\left(OH\right)_2+2HNO_3\rightarrow Ca\left(NO_3\right)_2+2H_2O\)
\(0.25...............0.5.................0.25\)
\(\left[Ca^{2+}\right]=\dfrac{0.25}{0.25+0.25}=0.5\left(M\right)\)
\(\left[NO_3^-\right]=\dfrac{0.25\cdot2}{0.25+0.25}=1\left(M\right)\)
\(n_{Ba\left(OH\right)_2}=0,05.0,04=0,002mol\\ n_{HCl}=0,15.0,06=0,009mol\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ \Rightarrow\dfrac{0,002}{1}< \dfrac{0,009}{2}\Rightarrow HCl.dư\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)
0,002 0,004 0,002
\(C_{M_{BaCl_2}}=\dfrac{0,002}{0,05+0,15}=0,01M\\ C_{M_{HCl.dư}}=\dfrac{0,009-0,004}{0,05+0,15}=0,025M\)
a, \(\left[Ca^{2+}\right]=\dfrac{0,15.0,5}{0,15+0,05}=0,375M\)
\(\left[Na^+\right]=\dfrac{0,05.2}{0,15+0,05}=0,5M\)
\(\left[Cl^-\right]=\dfrac{0,15.2.0,5+0,05.2}{0,15+0,05}=1,25M\)
\(n_{NaOH}=0.25\cdot2=0.5\left(mol\right)\)
\(n_{H_2SO_4}=0.25\cdot1=0.25\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.5..............0.25................0.25\)
\(\left[Na^+\right]=\dfrac{0.25\cdot2}{0.25+0.25}=1\left(M\right)\)
\(\left[SO_4^{2-}\right]=\dfrac{0.25}{0.25+0.25}=0.5\left(M\right)\)
