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22 tháng 12 2023

Sửa đề: 3,785 (l) → 3,7185 (l)

a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)

Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)

c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)

Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)

\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)

d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)

\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)

e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)

 

21 tháng 12 2023

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\)

\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\left(2\right)\)

\(n_{H_2}=\dfrac{3.785}{24.79}=0.15\left(mol\right)\Rightarrow n_{Al}=\dfrac{2}{3}\cdot0.15=0.1\left(mol\right),n_{HCl\left(1\right)}=0.15\cdot2=0.3\left(mol\right)\)

\(m_{Al}=0.1\cdot27=2.7\left(g\right)\Rightarrow m_{Al_2O_3}=40-2.7=37.3\left(g\right)\Rightarrow n_{Al_2O_3}=\dfrac{37.3}{102}=0.36\left(mol\right)\)

\(\Rightarrow n_{HCl\left(2\right)}=0.36\cdot6=2.16\left(mol\right)\)

\(n_{HCl}=0.3+2.16=2.46\left(mol\right)\)

\(V_{dd_{HCl}}=\dfrac{2.46}{2}=1.23\left(l\right)\)

3 tháng 11 2023

\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

a) \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

  \(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)

b) \(n_{Fe}=n_{H2}=n_{H2SO4}=0,1\left(mol\right)\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)

\(\Rightarrow m_{Al2O3}=15,8-5,6=10,2\left(g\right)\)

c) Ta có : \(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\Rightarrow n_{H2SO4}=3n_{Al2O3}=0,3\left(mol\right)\)

\(C_{MddH2SO4}=\dfrac{0,1+0,3}{0,2}=2M\)

a) 2Al + 6HCl -> 2AlCl3 + 3H2

Al2O3 + 6HCl -> 2AlCl3 + 3H2O

nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol

=>%mAl=20,93% =>%mAl2O3 = 79,07%

b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g

mddY=12,9+100-0,15.2=112,6g

mAlCl3=22,5g=>C%=19,98%

22 tháng 12 2021

a) PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2

b) \(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)

PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2

_____0,02<---0,03<---------------------0,03

=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,02.27}{2,16}.100\%=25\%\\\%Cu=100\%-25\%=75\%\end{matrix}\right.\)

c) mH2SO4 = 0,03.98 = 2,94 (g)

=> \(C\%\left(H_2SO_4\right)=\dfrac{2,94}{200}.100\%=1,47\%\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

            \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)

a) Ta có: \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)=n_{Zn}\)

\(\Rightarrow\%m_{Zn}=\dfrac{0,4\cdot65}{36,2}\cdot100\%\approx71,23\%\) \(\Rightarrow\%m_{Al_2O_3}=28,77\%\)

c) Ta có: \(n_{Al_2O_3}=\dfrac{36,2-0,4\cdot65}{102}=0,1\left(mol\right)\)

Theo PTHH: \(n_{HCl}=2n_{Zn}+6n_{Al_2O_3}=1,4\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{1,4\cdot36,5}{10\%}=511\left(g\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{511}{1,1}\approx464,5\left(ml\right)=0,4645\left(l\right)\)

c) Theo PTHH: \(\left\{{}\begin{matrix}n_{ZnCl_2}=0,4\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,4}{0,4645}\approx0,86\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4645}\approx0,43\left(M\right)\end{matrix}\right.\)

 

 

28 tháng 8 2021

a) \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b) Gọi x,y là số mol Al, Fe

\(n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\)

Ta có hệ : \(\left\{{}\begin{matrix}27x+56y=0,83\\\dfrac{3}{2}x+y=0,02\end{matrix}\right.\)

=> \(x=\dfrac{29}{5700};y=\dfrac{47}{3800}\)

\(\%m_{Al}=\dfrac{\dfrac{27}{5700}.27}{0,83}.100=16,55\%\)\(\%m_{Fe}=100-16,55=83,45\%\)

c)Bảo toàn nguyên tố H: \(n_{H_2SO_4}=n_{H_2}=0,02\left(mol\right)\)

=> \(C\%_{H_2SO_4}=\dfrac{0,02.98}{200}.100=0,98\%\)

 

11 tháng 10 2021

a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

                \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow n_{ZnO}=\dfrac{20-0,1\cdot65}{81}=\dfrac{1}{6}\left(mol\right)\)

\(\Rightarrow n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{4}{15}\left(mol\right)\) 

Mặt khác: \(m_{H_2}=0,1\cdot2=0,2\left(g\right)\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=119,8\left(g\right)\) \(\Rightarrow C\%_{ZnCl_2}=\dfrac{\dfrac{4}{15}\cdot136}{119,8}\cdot100\%\approx30,27\%\)

c) Giả sử khí là SO2

PTHH: \(Zn+H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}ZnSO_4+SO_2\uparrow+H_2O\)

Theo PTHH: \(n_{SO_2}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)