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\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\) \(\Rightarrow n_{Na}=0,6\left(mol\right)\)
\(\Rightarrow\%m_{Na}=\dfrac{0,6\cdot23}{26,2}\cdot100\%\approx52,67\left(g\right)\) \(\Rightarrow\%m_{Na_2O}=47,33\%\)
Mặt khác: \(n_{Na_2O}=\dfrac{26,2-0,6\cdot23}{62}=0,2\left(mol\right)\)
Theo PTHH: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=1\left(mol\right)\) \(\Rightarrow m_{NaOH}=1\cdot40=40\left(g\right)\)
2Na + 2H2O ---> 2NaOH + H2 (1)
Na2O + H2O ---> 2NaOH (2)
a) nH2 = 0,3 (mol)
Theo pthh (1) : nNa = 2nH2 = 0,6 (mol)
=> mNa = 0,6.23 = 13,8 (g)
=> mNa2O = 26,2 - 13,8 = 12,4 (g)
=> nNa2O = 0,2 (mol)
BTNa : nNaOH = nNa + 2nNa2O = 0,6 + 2.0,2 = 1 (mol)
=> mNaOH = 1.40 = 40(g)
b) %mNa = 13,8.100%/26,2 = 52,67%
%mNa2O = 100% - 52,67% = 47,33%
\(a,n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH: Ba + 2H2O ---> Ba(OH)2 + H2
0,3<-------------0,3<---------0,3
=> mBa = 0,3.137 = 41,1 (g)
=> mK2O = 59,9 - 41,1 = 18,8 (g)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Ba}=\dfrac{41,1}{59,9}.100\%=68,61\%\\\%m_{K_2O}=100\%-68,61\%=31,39\%\end{matrix}\right.\)
\(b,n_{K_2O}=\dfrac{18,8}{94}=0,2\left(mol\right)\)
PTHH: K2O + H2O ---> 2KOH
0,2----------------->0,4
Các chất tan trong dd sau phản ứng: KOH, Ba(OH)2
\(\rightarrow\left\{{}\begin{matrix}m_{KOH}=0,4.56=22,4\left(g\right)\\m_{Ba\left(OH\right)_2}=0,3.171=51,3\left(g\right)\end{matrix}\right.\)
nH2 = 2.24/22.4 = 0.1 (mol)
Na + H2O => NaOH + 1/2 H2
0.2....................0.2..........0.1
mNa = 0.2 * 23 = 4.6 (g)
mNa2O = 17 - 4.6 = 12.4 (g)
nNa2O = 12.4/62 = 0.2 (mol)
Na2O + H2O => 2NaOH
0.2........................0.4
nNaOH = 0.2 + 0.4 = 0.6 (mol)
mNaOH = 0.6 * 40 = 24 (g)
nCuO = 24/80 = 0.3 (mol)
CuO + H2 -t0-> Cu + H2O
1...........1
0.3.........0.1
LTL : 0.3/1 > 0.1/1
=> CuO dư
nCu = nH2 = 0.1 (mol)
mCu = 0.1 * 64 = 6.4 (g)
a, \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Na}=2n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Na}=0,3.23=6,9\left(g\right)\)
\(\Rightarrow m_{Na_2O}=13,1-6,9=6,2\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
Theo PT: \(n_{NaOH}=n_{Na}+2n_{Na_2O}=0,5\left(mol\right)\)
Ta có: m dd sau pư = 13,1 + 200 - 0,15.2 = 212,8 (g)
\(\Rightarrow C\%_{NaOH}=\dfrac{0,5.40}{212,8}.100\%\approx9,4\%\)
a, PTHH : 2K + 2H2O -> 2KOH + H2 (1)
2Na + 2H2O -> 2NaOH + H2 (2)
Khí A là H2
Dung dịch B : KOH , NaOH
mNa =8,5 . 54,12% = 4,6 (g) -(chỗ này có làm tròn xíu lát tính cho dễ )
=>nNa=4,6 /23 = 0,2(mol)
Theo (2) nH2= 1/2 nNa = 0,1 (mol)
Theo (2), nNaOH= nNa = 0,2 (mol)=> mNaOH= 0,2 . 40 = 8(g)
=> mK = 8,5 - 4,6= 3,9 (g)
=>nK = 3,9 / 39 = 0,1 (mol)
Theo (1) , nH2= 1/2 nK = 0,05 (mol)
Theo (1) ,n KOH= nK = 0,1 (mol)=> mKOH = 0,1 . 56=5,6 (g)
\(\Sigma\)nH2= 0,1 + 0,05 = 0,15 (mol)=> VA= 3,36 (l)
a) mNa=4,6g;mK=3,9g ( cái này bạn bik)
pt:\(2Na+2H_2O->2NaOH+H_2\uparrow\)
0,2 ---------------------> 0,2--------->0,1 (mol)
\(2K+2H_2O->2KOH+H_2\uparrow\)
01,------------------->0,1-------------->0,05 ( mol)
VH2= (0,1+0,05).22,4=3,36lit
mNaOH=0,2.40=8g
mKOH=0,156=5,6g
b làm tương tự câu a