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\(n_{CO2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
a) Pt : \(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O|\)
1 2 1 1 1
a 0,2 1a
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O|\)
1 2 1 1 1
b 0,2 1b
b) Gọi a là số mol của BaCO3
b là số mol của CaCO3
\(m_{BaCO3}+m_{CaCO3}=29,7\left(g\right)\)
⇒ \(n_{BaCO3}.M_{BaCO3}+n_{CaCO3}.M_{BaCO3}=29,7g\)
⇒ 197a + 100b = 29,7g (1)
Theo phương trình : 1a + 1b = 0,2(2)
Từ (1),(2),ta có hệ phương trình :
197a + 100b = 29,7g
1a + 1b = 0,2
⇒ \(\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)
\(m_{BaCO3}=0,1.197=19,7\left(g\right)\)
\(m_{CaCO3}=0,1.100=10\left(g\right)\)
0/0BaCO3 = \(\dfrac{19,7.100}{29,7}=66,33\)0/0
0/0CaCO3 = \(\dfrac{10.100}{29,7}=33,67\)0/0
c) \(n_{HCl\left(tổng\right)}=0,2+0,2=0,4\left(mol\right)\)
\(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(m_{ddHCl}=\dfrac{14,6.100}{20}=73\left(g\right)\)
Chúc bạn học tốt
CuO + 2HCl -> CuCl2 + H2O (1)
Fe2O3 + 6HCl -> 2FeCl3 + 3H2O (2)
nHCl=0,2.3,5=0,7(mol)
Đặt nCuO=a
nFe2O3=b
Ta có hệ:
80a+160b=20
2a+6b=0,7
=>a=0,05;b=0,1
mCuO=80.0,05=4(g)
mFe2O3=20-4=16(g)
Theo PTHH 1 và 2 ta có:
nCuCl2=nCuO=0,05(mol)
nFeCl3=2nFe2O3=0,2(mol)
mCuCl2=135.0,05=6,75(g)
mFeCl3=162,5.0,2=32,5(g)
mdd =20+200.1,1=240(g)
C% dd CuCl2=6,72\240 .100%=2,8125%
C% dd FeCl3= 32,5\240 .100%=13,54%
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a_____2a______a_____a (mol)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b_____3b_______b_____\(\dfrac{3}{2}\)b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)
b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
x_____2x_____________x (mol)
\(Al_2\left(CO_3\right)_3+6HCl\rightarrow2AlCl_3+3H_2O+3CO_2\uparrow\)
y_____6y______________________3y (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56x+234y=29\\x+3y=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=56\cdot0,1=5,6\left(g\right)\\m_{Al_2\left(CO_3\right)_3}=23,4\left(g\right)\end{matrix}\right.\)
b) Theo PTHH: \(n_{HCl}=2n_{Fe}+6n_{Al_2\left(CO_3\right)_3}=0,8\left(mol\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{0,8}{2}=0,4\left(l\right)=400\left(ml\right)\)
c) Kết tủa sau phản ứng không có Al(OH)3
Bảo toàn Sắt: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=0,05\left(mol\right)\) \(\Rightarrow m_{Fe_2O_3}=0,05\cdot160=8\left(g\right)\)
2Fe(OH)3 -----to---> Fe2O3 + 3H2O
Mg(OH)2 ----to---> MgO + H2O
Gọi x, y lần lượt là số mol Fe(OH)3 và Mg(OH)2
\(\left\{{}\begin{matrix}107x+58y=16,5\\\dfrac{1}{2}.160x+y.40=12\end{matrix}\right.\)
=> x=0,1 ; y=0,1
\(\%m_{Fe\left(OH\right)_3}=\dfrac{107.0,1}{16,5}.100=64,85\%\)
%Mg(OH)2 = 35,15%
b) \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
0,1----------------------------------->0,05
\(Mg\left(OH\right)_2+H_2SO_4\rightarrow MgSO_4+2H_2O\)
0,1------------------------------------>0,1
\(m_{ddsaupu}=16,5+200=216,5\left(g\right)\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,05.400}{216,5}.100=9,24\%\)
\(C\%_{MgSO_4}=\dfrac{0,1.12}{216,5}.100=5,54\%\)
Câu 5 :
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)
1 2 1 1
0,1 0,2 0,1 0,1
\(MgO+2HCl\rightarrow MgCl_2+H_2O|\)
1 2 1 1
0,15 0,3 0,15
a) \(n_{Mg}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{Mg}=0,1.24=2,4\left(g\right)\)
\(m_{MgO}=8,4-2,4=6\left(g\right)\)
0/0Mg = \(\dfrac{2,4.100}{8,4}=28,57\)0/0
0/0MgO = \(\dfrac{6.100}{8,4}=71,43\)0/0
b) Có : \(m_{MgO}=6\left(g\right)\)
\(n_{MgO}=\dfrac{6}{40}=0,15\left(mol\right)\)
\(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)
\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(m_{ddHCl}=\dfrac{18,25.100}{3,65}=500\left(g\right)\)
\(n_{MgCl2\left(tổng\right)}=0,1+0,15=0,25\left(mol\right)\)
⇒ \(m_{MgCl2}=0,15.95=14,25\left(g\right)\)
\(m_{ddspu}=8,4+500-\left(0,1.2\right)=508,2\left(g\right)\)
\(C_{MgCl2}=\dfrac{14,25.100}{508,2}=2,8\)0/0
Chúc bạn học tốt
nH2=0,1(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,1__________0,2___________0,1(mol)
MgO + 2 HCl -> MgCl2 + H2O
0,05____0,1___0,05(mol)
mMg=0,1. 24= 2,4(g) -> mMgO=4,4-2,4= 2(g) -> nMgO=0,05((mol)
b) %mMg= (2,4/4,4).100=54,545%
=> %mMgO=45,455%
c) nHCl=0,3(mol) -> mHCl=0,3.36,5=10,95(g)
=> mddHCl=(10,95.100)/7,3=150(g)
\(a)n_{HCl}=0,2.1,5=0,3mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}2n_{CaO}+2n_{CuO}=0,3\\56n_{CaO}+80n_{CuO}=10,8\end{matrix}\right.\\ \Rightarrow n_{CaO}=n_{CaCl_2}=0,05mol;n_{CuO}=n_{CuCl_2}=0,1mol\\ \%m_{CaO}=\dfrac{0,05.56}{10,8}\cdot100=25,93\%\\ \%m_{CuO}=100-25,93=74,07\%\\ b)C_{M_{CaCl_2}}=\dfrac{0,05}{0,2}=0,25M\\ C_{M_{CuCl_2}}=\dfrac{0,1}{0,2}=0,5M\)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
x 2x x x
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
y 2y y y
\(\left\{{}\begin{matrix}56x+80y=10,8\\2x+2y=0,2.1,5=0,3\end{matrix}\right.\)
\(\Rightarrow x=0,05;y=0,1\)
\(a,\%m_{CaO}=0,05.56:10,8.100\%=25,93\left(\%\right)\)
\(\%m_{CuO}=100\%-25,93\%=74,07\%\)
\(b,C_{M\left(CaCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(C_{M\left(CuCl_2\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
So sánh các phản ứng của hỗn hợp X với oxi và hỗn hợp Y với dung dịch HCl, ta thấy :
n HCl = 2 n trong oxit ; m O 2 = 8,7 - 6,7 = 2g
n O trong oxit = 0,125 mol; n HCl = 0,25 mol
V HCl = 0,25/2 = 0,125l
a)
$n_{HCl} = \dfrac{3,65}{36,5} = 0,1(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CaCO_3} = n_{CaCl_2} = n_{CO_2} = \dfrac{1}{2}n_{HCl} = 0,05(mol)$
$\%m_{CaCO_3} = \dfrac{0,05.100]{31,1}.100\% = 16,08\%$
$\%m_{Ba(NO_3)_2} = 100\% -16,08\% = 83,92\%$
b)
$m_{dd\ sau\ pư} = 31,1 + 96,1 - 0,05.44 = 125(gam)$
$C\%_{Ba(NO_3)_2} = \dfrac{31,1 - 0,05.100}{125}.100\% = 20,88\%$
$C\%_{CaCl_2} = \dfrac{0,05.111}{125}.100\% = 4,44\%$
%m_{CaCO_3} = \dfrac{0,05.100]{31,1}.100\% = 16,08\%\%m_{CaCO_3} = \dfrac{0,05.100]{31,1}.100\% = 16,08\%
cái này sao e ko hiểu