Hãy nhập câu hỏi của bạn vào đây, nếu là tài khoản VIP, bạn sẽ được ưu tiên trả lời.
$a\bigg)$
Đặt $n_{Al}=x(mol);n_{Fe}=y(mol)$
$\to 27x+56y=22(1)$
BTe: $1,5x+y=n_{H_2}=\dfrac{17,92}{22,4}=0,8(2)$
Từ $(1)(2)\to x=0,4(mol);y=0,2(mol)$
$\to \%m_{Al}=\dfrac{0,4.27}{22}.100\%\approx 49,09\%$
$\to \%m_{Fe}=100-49,09=50,91\%$
$b\bigg)$
Bảo toàn H: $n_{HCl}=2n_{H_2}=1,6(mol)$
$\to m_{dd_{HCl}}=\dfrac{1,6.36,5}{25\%}=233,6(g)$
$\to m_{dd\, sau}=22+233,6-0,8.2=254(g)$
Bảo toàn Al,Fe: $n_{AlCl_3}=0,4(mol);n_{FeCl_2}=0,2(mol)$
$\to \begin{cases} C\%_{AlCl_3}=\dfrac{0,4.133,5}{254}.100\%\approx 21,02\%\\ C\%_{FeCl_2}=\dfrac{0,2.127}{254}.100\%=10\% \end{cases}$
\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)
\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)
\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)
0,02 0,06
\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)
0,05 0,05
\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)
\(Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+27b=5,1\\22,4a+22,4.1,5.b=5,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ a,\Rightarrow\%m_{Mg}=\dfrac{0,1.24}{5,1}.100\approx47,059\%\\ \Rightarrow\%m_{Al}\approx100\%-47,059\%\approx52,941\%\\ b,n_{HCl}=2.n_{H_2}=2.\left(0,1+0,1.1,5\right)=0,5\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,5}{2}=0,25\left(l\right)\)
a)\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
x 2x x x
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
y 3y y 1,5y
Ta có hệ:
\(\left\{{}\begin{matrix}24x+27y=5,1\\x+1,5y=\dfrac{5,6}{22,4}=0,25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%=47,06\%\)
\(\%m_{Al}=100\%-47,06\%=52,94\%\)
b)\(\Sigma n_{HCl}=2x+3y=2\cdot0,1+3\cdot0,1=0,5mol\)
\(V=\dfrac{n}{C_M}=\dfrac{0,5}{2}=0,25l=250ml\)
a) Gọi số mol Al, Fe là a, b (mol)
=> 27a + 56b = 11,1 (1)
\(n_{HCl}=\dfrac{60.36,5\%}{36,5}=0,6\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
a--->3a-------->a----->1,5a
Fe + 2HCl --> FeCl2 + H2
b--->2b------->b----->b
=> 3a + 2b = 0,6 (2)
(1)(2) => a = 0,1; b = 0,15
\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{11,1}.100\%=24,32\%\\\%m_{Fe}=\dfrac{0,15.56}{11,1}.100\%=75,68\%\end{matrix}\right.\)
b) \(n_{H_2}=1,5a+b=\) 0,3 (mol)
=> \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
mdd sau pư = 11,1 + 60 - 0,3.2 = 70,5 (g)
\(\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{0,1.133,5}{70,5}.100\%=18,94\%\\C\%_{FeCl_2}=\dfrac{0,15.127}{70,5}.100\%=27,02\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)
\(m_{HCl}=\dfrac{60\cdot36,5}{100}=21,9g\)
\(\Rightarrow n_{HCl}=\dfrac{21,9}{36,5}=0,6mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
x 3x 1,5x
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
y 2y y
\(\Rightarrow\left\{{}\begin{matrix}27x+56y=11,1\\3x+2y=0,6\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,15\end{matrix}\right.\)
a)\(\%m_{Al}=\dfrac{0,1\cdot27}{11,1}\cdot100\%=24,32\%\)
\(\%m_{Fe}=100\%-24,32\%=75,68\%\)
b)\(\Sigma n_{H_2}=1,5x+y=1,5\cdot0,1+0,15=0,3mol\)
\(V_{H_2}=0,3\cdot22,4=6,72l\)
Câu 1:
Gọi : nMg=a(mol); nMgO=b(mol) (a,b>0)
a) PTHH: Mg + 2 HCl -> MgCl2 + H2
a________2a_______a______a(mol)
MgO +2 HCl -> MgCl2 + H2O
b_____2b_______b___b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}24a+40b=8,8\\22,4a=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
=> mMg=0,2.24=4,8(g)
=>%mMg= (4,8/8,8).100=54,545%
=> %mMgO= 45,455%
b) m(muối)=mMg2+ + mCl- = 0,3. 24 + 0,6.35,5=28,5(g)
c) V=VddHCl=(2a+2b)/2=0,3(l)=300(ml)
Câu 2:
Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{HCl}=0,4\cdot2=0,8\left(mol\right)\end{matrix}\right.\)
PTHH: \(Ca+2HCl\rightarrow CaCl_2+H_2\uparrow\)
0,2____0,4_____0,2____0,2 (mol)
\(CaO+2HCl\rightarrow CaCl_2+H_2O\)
0,2____0,4______0,2____0,2 (mol)
Ta có: \(\left\{{}\begin{matrix}\%m_{Ca}=\dfrac{0,2\cdot40}{0,2\cdot40+0,2\cdot56}\cdot100\%\approx41,67\%\\\%m_{CaO}=58,33\%\\m_{CaCl_2}=\left(0,2+0,2\right)\cdot111=44,4\left(g\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+3H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Fe}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27a+56b=11\\1,5a+b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ a,n_{HCl}=2.n_{H_2}=2.0,4=0,8\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,8}{8}=0,1\left(l\right)\\ b,FeCl_2+2AgNO_3\rightarrow Fe\left(NO_3\right)_2+2AgCl\downarrow\\ AlCl_3+3AgNO_3\rightarrow Al\left(NO_3\right)_3+3AgCl\downarrow\\ n_{AgCl}=n_{AgNO_3}=3.n_{AlCl_3}+2.n_{FeCl_2}=3.a+2.b=3.0,2+2.0,1=0,8\left(mol\right)\\ \Rightarrow a=\dfrac{170.0,8}{250}.100=54,4\%\\ b=m_{\downarrow}=m_{AgCl}=0,8.143,5=114,8\left(g\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(n_{H_2}=n_{Fe}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(m_{CuO}=35.2-0.2\cdot56=24\left(g\right)\)
\(n_{CuO}=\dfrac{24}{80}=0.3\left(mol\right)\)
\(\%Fe=\dfrac{11.2}{35.2}\cdot100\%=31.82\%\)
\(\%CuO=100-31.82=68.18\%\)
\(n_{H_2SO_4}=0.2+0.3=0.5\left(mol\right)\)
\(m_{H_2SO_4}=0.5\cdot98=49\left(g\right)\)
\(C\%H_2SO_4=\dfrac{49}{800}\cdot100\%=6.125\%\)
\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)
\(m_{CuSO_4}=0.3\cdot160=48\left(g\right)\)
\(n_{Zn}=a\left(mol\right),n_{Al}=b\left(mol\right)\)
\(n_{H_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(2Al+6HCl\rightarrow2AlCl_3+H_2\)
\(n_{H_2}=a+1.5b=0.4\left(mol\right)\left(1\right)\)
\(m_{Muối}=m_{ZnCl_2}+m_{AlCl_3}=136a+133.5b=40.3\left(g\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.2\)
\(m_{hh}=0.1\cdot65+0.2\cdot27=11.9\left(g\right)\)
\(\%Zn=\dfrac{0.1\cdot65}{11.9}\cdot100\%=54.62\%\)
\(\%Al=100-54.62=45.38\%\)
Gọi x,y lần lượt là số mol của Al và Zn
ta có PTHH :
\(2Al+6Hcl->2AlCl3+3H2\uparrow\)
x mol....3xmol......xmol..........3/2xmol
\(Zn+2HCl->ZnCl2+H2\uparrow\)
ymol...2ymol............ymol.....ymol
ta có HPT : \(\left\{{}\begin{matrix}27x+65y=15,7\\133,5x+136y=40,55\end{matrix}\right.\) => x = 0,1 ; y = 0,2
a) Ta có : %mAl = \(\dfrac{0,1.27}{15,7}.100\%\approx17,2\%\) ; %mZn = 100% - 17,2% = 2,8%
b) CMddHCl = \(\dfrac{\left(3.0,1+2.0,2\right)}{0,2}=3,5\left(M\right)\)
đề thiếu dữ kiện nên ko làm tiếp đc
tính số mol AlCl3 và ZnCl2 ra rồi chia cho khối lg của đ sau pư
. m dd sau pư = m hỗn hợp cộng với m dd HCl trừ đi m của H
Gọi \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Zn}=y\left(mol\right)\end{matrix}\right.\)
\(n_{HCl}=0,2\cdot4=0,8mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(x\) \(\rightarrow\) \(3x\) \(x\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(y\) \(\rightarrow\) \(2y\) \(y\)
\(\Rightarrow\left\{{}\begin{matrix}27x+65y=11,9\\3x+2y=0,8\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
a)\(\%m_{Al}=\dfrac{0,2\cdot27}{11,9}\cdot100\%=45,38\%\)
\(\%m_{Zn}=100\%-45,38\%=54,62\%\)
b)\(\Sigma n_{H_2}=\dfrac{3}{2}x+y=\dfrac{3}{2}\cdot0,2+0,1=0,4mol\)
\(V_{H_2}=0,4\cdot22.4=8,96l\)