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\(a,n_{Zn}=\dfrac{0,65}{65}=0,01\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,01--->0,02---->0,01---->0,01
\(V_{H_2}=0,01.22,4=0,224\left(l\right)\\ b,m_{ZnCl_2}=0,01.136=1,36\left(g\right)\\ V_{ddHCl}=\dfrac{0,02}{2}=0,01\left(l\right)\)
\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ LTL:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ n_{HCl\left(pứ\right)}=2n_{Zn}=0,4\left(mol\right)\\\Rightarrow m_{HCl\left(dư\right)}=\left(0,5-0,4\right).36,5=3,65\left(g\right)\\ b.n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ c.n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ \Rightarrow V_{H_2}=0,2.22,4,=4,48\left(l\right)\\ d.3H_2+Fe_2O_3-^{t^o}\rightarrow2Fe+3H_2O \\ n_{Fe_2O_3}=\dfrac{19,2}{160}=0,12\left(mol\right)\\ LTL:\dfrac{0,2}{3}< \dfrac{0,12}{1}\Rightarrow Fe_2O_3dưsauphảnứng\\ \Rightarrow n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{15}\left(mol\right)\\ \Rightarrow m_{Fe}=\dfrac{2}{15}.56=7,467\left(g\right)\)
a) n\(Zn\)=\(\dfrac{m}{M}\)=\(\dfrac{13}{65}\)=0,2(mol)
n\(HCl\)=\(\dfrac{m}{M}\)=\(\dfrac{18,25}{36,5}=\)0,5(mol)
PTHH : Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 0,5
Lập tỉ lệ mol : \(^{\dfrac{0,2}{1}}\)<\(\dfrac{0,5}{2}\)
n\(Zn\) hết , n\(HCl\) dư
-->Tính theo số mol hết
Zn + 2HCl->ZnCl\(2\) + H\(2\)
0,2 -> 0,4 0,2 0,2
n\(HCl\) dư= n\(HCl\)(đề) - n\(HCl\)(pt)= 0,5 - 0,4 = 0,1(mol)
m\(HCl\) dư= 0,1.36,5 = 3,65(g)
b) m\(ZnCl2\) = n.M= 0,2.136= 27,2 (g)
c)V\(H2\)=n.22,4=0,2.22,4=4,48(l)
d) n\(Fe\)\(2\)O\(3\)=\(\dfrac{m}{M}\)=\(\dfrac{19,2}{160}\)=0,12 (mol)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2 0,12
Lập tỉ lệ mol: \(\dfrac{0,2}{3}\)<\(\dfrac{0,12}{1}\)
nH2 hết .Tính theo số mol hết
\(HCl\)
3H2 +Fe2O3 → 2Fe + 3H2O
0,2-> 0,2
m\(Fe\)=n.M= 0,2.56= 11,2(g)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right);n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\a, Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,V\text{ì}:\dfrac{0,2}{1}>\dfrac{0,1}{1}\Rightarrow Zn\text{dư}\\ \Rightarrow n_{Zn\left(p.\text{ứ}\right)}=n_{ZnCl_2}=n_{H_2}=0,1\left(mol\right)\\b, m_{Zn\left(p.\text{ứ}\right)}=0,1.65=6,5\left(g\right)\\ n_{HCl}=0,1.2=0,2\left(mol\right)\\ m_{HCl}=0,2.36,5=7,3\left(g\right)\\ d,m_{ZnCl_2}=136.0,1=13,6\left(g\right)\)
a. \(Mg+2HCl\rightarrow MgCl_2+H_2\)
b. \(n_{Mg}=\dfrac{2.4}{24}=0.1mol\)
\(mct_{HCl}=\dfrac{500\times36.5}{100}=182.5g\Rightarrow n_{HCl}=\dfrac{182.5}{36.5}=5mol\)
Ta có: \(\dfrac{0.1}{1}< \dfrac{5}{2}\Rightarrow\) HCl dư
nHCl phản ứng = 0.2 mol => nHCl dư = 5 - 0.2 = 4.8 mol
mHCl dư = \(4.8\times36.5=175.2g\)
c. \(V_{H_2}=0.1\times22.4=2.24l\)
d. mdd sau phản ứng = \(2.4+500-0.1\times2=502.2g\)
\(C\%_{MgCl_2}=\dfrac{0.1\times95\times100}{502.2}=1.89\%\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{FeCl_2}=n_{Fe}=0,1\left(mol\right);n_{HCl}=2.0,1=0,2\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,m_{HCl}=0,2.36,5=7,3\left(g\right)\\ m_{FeCl_2}=127.0,1=12,7\left(g\right)\)
Cái khí ở dạng phân tử nên là H2 chứ không phải H em nha!
Zn+2HCl->Zncl2+H2
0,4----0,8----0,4----0,4
n Zn=0,4 mol
VH2=0,4.22,4=8,96l
m ZnCl2=0,4.136=54,4g
2H2+O2-to>2H2O
0,4------0,2----0,4
n O2=0,2 mol
=>pứ hết
=>m H2O=0,4.18=7,2g
a.b.\(n_{Zn}=\dfrac{26}{65}=0,4mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,4 0,4 0,4 ( mol )
\(m_{ZnCl_2}=0,4.136=54,4g\)
\(V_{H_2}=0,4.22,4=8,96l\)
c.\(n_{O_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(2H_2+O_2\rightarrow\left(t^o\right)2H_2O\)
0,4 = 0,2 ( mol )
0,4 0,2 0,4 ( mol )
\(m_{H_2O}=0,4.18=7,2g\)
Fe + 2HCl -> FeCl2 + H2
nFe = 5,6/56 = 0,1 mol
=>nH2 = 0,1 mol
=> VH2= 0,1*22,4= 2,24 lít
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,1-->0,2------------------>0,1
=> \(\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,2.36,5}{15\%}=\dfrac{146}{3}\left(g\right)\\V_{H_2}=0,1.22,4=4,48\left(l\right)\end{matrix}\right.\)
a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Ta có: \(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Mg}=0,3\left(mol\right)\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b, \(n_{Fe_2O_3}=\dfrac{48}{160}=0,3\left(mol\right)\)
PT: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,3}{3}\), ta được Fe2O3 dư.
Theo PT: \(n_{Fe_2O_3\left(pư\right)}=\dfrac{1}{3}n_{H_2}=0,1\left(mol\right)\Rightarrow n_{Fe_2O_3\left(dư\right)}=0,3-0,1=0,2\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,2.160=32\left(g\right)\)
a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)
\(m_{HCl}=36,5.15\%=5,475\left(g\right)\Rightarrow n_{HCl}=\dfrac{5,475}{36,5}=0,15\left(mol\right)\)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,15}{2}\), ta được Mg dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow V_{H_2}=0,075.22,4=1,68\left(l\right)\)
b, \(n_{Mg\left(pư\right)}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow n_{Mg\left(dư\right)}=0,1-0,075=0,025\left(mol\right)\)
\(\Rightarrow m_{Mg\left(dư\right)}=0,025.24=0,6\left(g\right)\)
c, - Cách 1:
\(n_{MgCl_2}=\dfrac{1}{2}n_{HCl}=0,075\left(mol\right)\Rightarrow m_{MgCl_2}=0,075.95=7,125\left(g\right)\)
- Cách 2:
Theo ĐLBT KL, có: mMg (pư) + mHCl = mMgCl2 + mH2
⇒ mMgCl2 = 2,4 - 0,6 + 5,475 - 0,075.2 = 7,125 (g)
8====D
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