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\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ m_{HCl}=\dfrac{109,5\cdot10\%}{100\%}=10,95\left(g\right)\\ \Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ \text{Vì }\dfrac{n_{Mg}}{1}< \dfrac{n_{HCl}}{2}\text{ nên sau p/ứ }HCl\text{ dư}\\ \Rightarrow n_{H_2}=0,1\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,1\cdot22,4=2,24\left(l\right)\)
\(b,n_{MgCl_2}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{MgCl_2}}=0,1\cdot95=9,5\left(g\right)\\ m_{H_2}=0,1\cdot2=0,2\left(mol\right)\\ m_{dd_{MgCl_2}}=2,4+109,5-0,2=111,7\left(g\right)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{9,5}{111,7}\cdot100\%\approx8,5\%\)
\(n_{Fe}=\dfrac{8,4}{56}=0,15mol\)
\(m_{CuCl_2}=\dfrac{270\cdot10\%}{100\%}=27g\Rightarrow n_{CuCl_2}=0,2mol\)
\(Fe+CuCl_2\rightarrow FeCl_2+Cu\)
0,15 0,2 0,15 0,15
\(a=m_{Cu}=0,15\cdot64=9,6g\)
\(m_{FeCl_2}=0,15\cdot127=19,05g\)
\(m_{ddFeCl_2}=8,4+270-0,15\cdot64=268,8g\)
\(C\%=\dfrac{19,05}{268,8}\cdot100\%=7,09\%\)
a, \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
\(m_{CuCl_2}=270.10\%=27\left(g\right)\Rightarrow n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\)
Ta có: \(\dfrac{0,15}{1}< \dfrac{0,2}{1}\) ⇒ Fe hết, CuCl2 dư
PTHH: Fe + CuCl2 ---> FeCl2 + Cu
Mol: 0,15 0,15 0,15 0,15
\(a=m_{Cu}=0,15.64=9,6\left(g\right)\)
b, \(m_{dd.sau.pứ}=8,4+270-9,6=268,8\left(g\right)\)
\(m_{CuCl_2dư}=\left(0,2-0,15\right).135=6,75\left(g\right)\)
\(\left\{{}\begin{matrix}C\%_{CuCl_2dư}=\dfrac{6,75.100\%}{268,8}=2,51\%\\C\%_{FeCl_2}=\dfrac{0,15.127.100\%}{268,8}=7,09\%\end{matrix}\right.\)
c, \(V_{ddCuCl_2}=\dfrac{270}{1,35}=200\left(ml\right)=0,2\left(l\right)\)
\(\left\{{}\begin{matrix}C_{M_{CuCl_2dư}}=\dfrac{0,2-0,15}{0,2}=0,25M\\C_{M_{FeCl_2}}=\dfrac{0,15}{0,2}=0,75M\end{matrix}\right.\)
a) \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,3--->0,6------>0,3-->0,3
=> V = 0,3.24,79 = 7,437 (l)
b) a = mHCl = 0,6.36,5 = 21,9 (g)
b = mZnCl2 = 0,3.136 = 40,8 (g)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
d, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
⇒ m dd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{27,2}{212,6}.100\%\approx12,79\%\)
a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4----->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) mHCl = 0,4.36,5 = 14,6 (g)
=> \(m_{dd.HCl}=\dfrac{14,6.100}{7,3}=200\left(g\right)\)
c)
mdd sau pư = 13 + 200 - 0,2.2 = 212,6 (g)
mZnCl2 = 0,2.136 = 27,2 (g)
=> \(C\%=\dfrac{27,2}{212,6}.100\%=12,8\%\)
\(n_{HCl}=\dfrac{10\%.109,5}{36,5}=0,3\left(mol\right);n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ Vì:\dfrac{0,3}{2}>\dfrac{0,1}{1}\Rightarrow HCldư\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.0,1=0,2\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\\ V_{H_2\left(đkc\right)}=24,79.0,1=2,479\left(l\right)\\ b,ddA:HCl\left(dư\right),MgCl_2\\ m_{ddA}=2,4+109,5-0,1.2=111,7\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,1.36,5}{111,7}.100\%\approx3,268\%;C\%_{ddMgCl_2}=\dfrac{0,1.95}{111,7}.100\%\approx8,505\%\)