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a) Al2O3 + 3H2SO4 --> Al2(SO4)3 + 3H2O
b) \(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
PTHH: Al2O3 + 3H2SO4 --> Al2(SO4)3 + 3H2O
0,1---->0,3------->0,1
=> m = 0,1.342 = 34,2 (g)
c) \(C\%_{dd.H_2SO_4}=\dfrac{0,3.98}{120}.100\%=24,5\%\)
a) 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
b) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 3H2SO4 --> Al2(SO4)3 + 3H2
0,4--->0,6-------------------->0,6
=> VH2 = 0,6.22,4 = 13,44 (l)
c) \(V_{dd.H_2SO_4}=\dfrac{0,6}{1}=0,6\left(l\right)\)
d) \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,6}{3}\) => Fe2O3 hết, H2 dư
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1----------------->0,2
=> mFe = 0,2.56 = 11,2 (g)
2Al+3H2SO4->Al2(SO4)3+3H2
0,1----------------------0,075----0,15
n H2=0,15 mol
=>mAl=0,1.27=2,7g
=>m Al2(SO4)3=0,075.342=25,65g
a) PTHH: \(2Al+3H_2SO_2\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{Al}=\dfrac{2}{3}.0,15=0,1\left(mol\right)\)
\(m_{Al}=0,1.27=2,7\left(g\right)\)
c) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)
\(m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)
`a)PTHH:`
`2Al + 6HCl -> 2AlCl_3 + 3H_2`
`0,2` `0,6` `0,3` `(mol)`
`n_[Al]=[5,4]/27=0,2(mol)`
`b)V_[H_2]=0,3.22,4=6,72(l)`
`c)m_[dd HCl]=[0,6.36,5]/10 . 100 =219(g)`
\(n_{Al}=\dfrac{2.7}{27}=0.1\left(mol\right)\)
\(n_{CuSO_4}=0.6\cdot0.1=0.06\left(mol\right)\)
\(2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\)
\(2............3\)
\(0.1.........0.06\)
\(LTL:\dfrac{0.1}{2}>\dfrac{0.06}{3}\Rightarrow Aldư\)
\(m_{Al\left(dư\right)}=\left(0.1-0.04\right)\cdot27=1.62\left(g\right)\)
\(C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0.02}{0.1}=0.2\left(M\right)\)
PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)
Làm gộp các phần còn lại
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1mol\\n_{H_2SO_4}=n_{H_2}=0,3mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)
n H2SO4=\(\dfrac{10\%.490}{2+32+16.4}=0,5mol\)
n Al2O3 =\(\dfrac{10,2}{27.2+16.3}=0,1mol\)
\(Al_2O_3+3H_2SO_4->Al_2\left(SO_4\right)_3+3H_2O\)
bđ 0,1............0,5
pư 0,1............0,3..................0,1
spu 0 ................0,2................0,1
=> sau pư gồm H2SO4 dư , Al2(S04)3 và H2O
m H2SO4 dư = \(0,2.\left(2+32+16.3\right)=19,6g\)
m Al2(SO4)3 = \(0,1\left(27.2+32.3+16.4.3\right)=34,2g\)
m dd = \(490+10,2=500,2g\)
% Al2(SO4)3 = \(\dfrac{34,2}{500,2}.100\sim6,84\%\)
% H2SO4 dư = \(\dfrac{19,6}{500,2}.100\sim3,92\%\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,02` `0,02` `0,02` `(mol)`
`n_[Zn]=[1,3]/65=0,02(mol)`
`b)V_[H_2]=0,02.22,4=0,448(l)`
`c)C%_[ZnCl_2]=[0,02.136]/[1,3+50-0,02.2].100~~5,31%`
\(n_{Zn}=\dfrac{1,3}{65}=0,02\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,02 0,04 0,02 0,02 ( mol )
\(V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(C\%_{ZnCl_2}=\dfrac{0,02.136}{1,3+50-0,02.2}.100=5,3\%\)
a) $2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
b)
n Al = 2,7/27 = 0,1(mol)
Theo PTHH :
n H2SO4 = 3/2 n Al = 0,15(mol)
=> C% H2SO4 = 0,15.98/441 .100% = 3,33%
c)
Theo PTHH :
n H2 = 3/2 n Al = 0,15(mol)
=> V H2 = 0,15.22,4 = 3,36(lít)