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Ta có nH2 = 3,36/22,4 = 0,15 mol
Fe +2 HCl -> FeCl2 + H2
0,15. 0,3 <-. 0,15. ( Mol)
=> mFe = 0,15 × 56 = 8,4g
=> %Fe = 8,4/15×100% = 56%
=> %Cu = 100% - 56% = 44%
=>VHCl =1\0,3=10\3 l
\(n_{Cu}=a\left(mol\right),n_{Fe}=b\left(mol\right),n_{Al}=c\left(mol\right)\)
\(m_X=64a+56b+27b=35.7\left(g\right)\left(1\right)\)
\(n_{Cl_2}=\dfrac{21.84}{22.4}=0.975\left(mol\right)\)
\(Cu+Cl_2\underrightarrow{^{^{t^0}}}CuCl_2\)
\(Fe+\dfrac{3}{2}Cl_2\underrightarrow{^{^{t^0}}}FeCl_3\)
\(Al+\dfrac{3}{2}Cl_2\underrightarrow{^{^{t^0}}}AlCl_3\)
\(n_{Cl_2}=a+1.5b+1.5c=0.975\left(mol\right)\left(2\right)\)
\(n_{hh}=ka+kb+kc=0.25\left(mol\right)\)
\(n_{H_2}=kb+k\cdot1.5c=0.2\left(mol\right)\)
\(\Leftrightarrow a-0.25b-0.875c=0\left(3\right)\)
\(\left(1\right),\left(2\right),\left(3\right):a=0.3,b=0.15,c=0.3\)
\(\%Cu=\dfrac{0.3\cdot64}{35.7}\cdot100\%=53.78\%\)
\(\%Fe=\dfrac{0.15\cdot56}{35.7}\cdot100\%=23.52\%\)
\(\text{%Al=22.7%}\)
a/ Fe + 2HCl \(\rightarrow\) FeCl2 + H2
nH2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PTHH: nH2 = nFe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)
\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)
b/ Theo PTHH ta có: nHCl = 2nFe = 2.0,15 = 0,3 (mol)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)
c/ mHCl = 36,5 . 0,3 = 10,95(g)
\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)
b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)
a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Cu+HCl\rightarrow\)(không phản ứng)
2Al + 6HCl => 2AlCl3 + 3H2
0,3/3*2 (6,72/22,4)
=> mAl = 0,2 *27 =5,4g; mCu = 11,8 - 5,4 = 6,4g
2Al + 2H2O + 2NaOH→ 3H2 + 2NaAlO2
0,2mol 0,3mol
mAl=0,2.27=5,4g
2Al + 6HCl→ 2AlCl3+ 3H2
0,2mol 0,3mol
Fe + 2HCl→ FeCl2+ H2
0,15mol 0,45-0,3 mol
mFe=0,15.56=8,4g
mCu=32,8-(6,4+8,4)=18g
%mFe=\(\frac{8,4}{32,8}.100=25,6\%\)
%mCu=\(\frac{18}{32,8}.100=54,8\%\)
%mAl=19,6%