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\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
0,1<----------------0,05-------------->0,05
\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)
\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)
PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)
bđ 0,1 0,15
pư 0,1 0,1
spư 0 0,05 0,1
\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)
\(n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)
C2H4 + 3O2 ----to---> 2CO2 + 2H2O
0,4 1,2 0,8
\(m_{H_2O}=0,8.18=14,4\left(g\right)\)
\(V_{kk}=5V_{O_2}=5.1,2.22,4=134,4\left(l\right)\)
\(a)n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ n_{Mg}=\dfrac{4,8}{24}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2 0,1 0,1
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(V_{H_2}=\left(0,1+0,2\right).22,4=6,72l\\ b)V_{ddHCl}=\dfrac{0,2+0,4}{2}=0,3l\\ c)m_{muối}=0,1.127+95.0,2=31,7g\)
Pt: \(2CH_3COOH+Zn\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
\(n_{\left(CH_3COO\right)_2Zn}=\dfrac{14,2}{183}\approx0.077mol\)
Theo pt: nH2 = n(CH3COO)2Zn = 0,077mol
=> VH2 = 1,7248l
b) Theo pt: nCH3COOH = 2n(CH3COO)2Zn = 0,154 mol
=> CMCH3COOH = 0,154 : 0,25 = 0,616M
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 5,6 + 120 - 0,1.2 = 125,4 (g)
\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)
a, PT: \(4M+3O_2\underrightarrow{t^o}2M_2O_3\)
Ta có: \(n_M=\dfrac{10,8}{M_M}\left(mol\right)\)
\(n_{M_2O_3}=\dfrac{20,4}{2M_M+16.3}\left(mol\right)\)
Theo PT: \(n_M=2n_{M_2O_3}\Rightarrow\dfrac{10,8}{M_M}=2.\dfrac{20,4}{2M_M+16.3}\)
\(\Rightarrow M_M=27\left(g/mol\right)\)
→ M là Nhôm (Al)
b, Ta có: \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,3\left(mol\right)\) \(\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)
\(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{20\%}=33,6\left(l\right)\)
c, PT: \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
\(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\)
\(n_{HCl}=6n_{Al_2O_3}=1,2\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{1,2}{2}=0,6\left(l\right)\)
d, PT: \(Al_2O_3+2NaOH\rightarrow2NaAlO_2+H_2O\)
Theo PT: \(n_{NaOH}=2n_{Al_2O_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{NaOH}=0,4.40=16\left(g\right)\Rightarrow m_{ddNaOH}=\dfrac{16}{25\%}=64\left(g\right)\)
\(\Rightarrow V_{ddNaOH}=\dfrac{64}{1,25}=51,2\left(ml\right)\)
a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)
PTHH: 2CH3COOH + Mg --> (CH3COO)2Mg + H2
0,1<----------------------0,05------->0,05
=> VH2 = 0,05.22,4 = 1,12 (l)
b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)
\(n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ n_{O_2}=3.0,4=1,2\left(mol\right);n_{CO_2}=0,4.2=0,8\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=22,4.1,2=26,88\left(l\right)\\ b,V_{kk\left(đktc\right)}=\dfrac{100}{20}.26,88=134,4\left(l\right)\\ c,CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow\left(trắng\right)+H_2O\\ n_{CaCO_3}=n_{CO_2}=0,8\left(mol\right)\\ m_{kết.tủa}=m_{CaCO_3}=100.0,8=80\left(g\right)\)
nCH3COOH=48/60=0,8 mol
2CH3COOH + Fe --> (CH3COO)2Fe + H2
0,8 0,4 0,4 mol
=>m(CH3COO)2Fe=0,4*174=69,6 g
2H2 +O2 --> 2H2O
0,4 0,2 mol
=>VO2=0,2*22,4=4,48 lít
=> V không khí =4,48*5=22,4 lít
PT: \(2CH_3COOH+Fe\rightarrow\left(CH_3COO\right)_2Fe+H_2\)
a, Ta có: \(n_{CH_3COOH}=\dfrac{4,8}{60}=0,08\left(mol\right)\)
Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=\dfrac{1}{2}n_{CH_3COOH}=0,04\left(mol\right)\)
\(\Rightarrow m_{\left(CH_3COO\right)_2Fe}=0,04.174=6,96\left(g\right)\)
b, Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,04\left(mol\right)\)
PT: \(2H_2+O_2\underrightarrow{t^o}2H_2O\)
___0,04__0,02 (mol)
\(\Rightarrow V_{O_2}=0,02.22,4=0,448\left(l\right)\)
\(\Rightarrow V_{kk}=0,448.5=2,24\left(l\right)\)
Bạn tham khảo nhé!