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\(n_{H_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\\ n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
LTL: \(\dfrac{1,5}{2}< 1,5\rightarrow O_2\) dư
Theo pt: \(\left\{{}\begin{matrix}n_{O_2\left(pư\right)}=\dfrac{1}{2}n_{H_2}=\dfrac{1}{2}.1,5=0,75\left(mol\right)\\n_{H_2O}=n_{H_2}=1,5\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\left(1,5-0,75\right).32=24\left(g\right)\\V_{O_2}\left(1,5-0,75\right).22,4=16,8\left(l\right)\\m_{H_2O}=1,5.18=27\left(g\right)\end{matrix}\right.\)
\(n_{H_2}=n_{O_2}=\dfrac{33,6}{22,4}=1,5\left(MOL\right)\)
pthh: \(2H_2+O_2\underrightarrow{t^O}2H_2O\)
LTL : \(\dfrac{1,5}{2}< \dfrac{1,5}{1}\)
=> O2 dư , H2 hết
theo pthh: nH2O = nH2 = 1,5 (mol)
=> \(m_{H_2O}=1,5.18=27\left(g\right)\)
\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(n_{O_2}=\dfrac{8}{22,4}=\dfrac{5}{14}\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,5}{2}< \dfrac{\dfrac{5}{14}}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,5-->0,25
=> \(V_{O_2\left(dư\right)}=\left(\dfrac{5}{14}-0,25\right).22,4=2,4\left(l\right)\)
$n_{C_2H_2} = \dfrac{6,72}{22,4} = 0,3(mol) ; n_{O_2} = 0,5(mol)$
$2C_2H_2 + 5O_2 \xrightarrow{t^o} 4CO_2 + 2H_2O$
Ta thấy :
$n_{C_2H_2} : 2 > n_{O_2} : 5$ nên $C_2H_2$ dư
Theo PTHH :
$n_{C_2H_2\ pư} = \dfrac{5}{2} = 0,2(mol)$
$n_{CO_2} = 0,4(mol) ; n_{H_2O} = 0,2(mol)$
Suy ra :
$m_{C_2H_2\ dư} = (0,3 - 0,2).26 = 2,6(gam)$
$m_{CO_2} = 0,4.44 = 17,6(gam)$
$m_{H_2O} = 0,2.18 = 3,6(gam)$
\(n_{CO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: 2C2H2 + 5O2 --to--> 4CO2 + 2H2O
0,5--->0,25
=> m2 = 0,25.18 = 4,5 (g)
$2C_2H_2$ + $5O_2$ $\xrightarrow[]{t^o}$ $4CO_2$ + $2H_2O$
$nC_2H_2$ = $\frac{7,8}{26}$ = $0,4(mol)$
$nCO_2$ = $\frac{11,2}{22,4}$ = $0,5(mol)$
-Theo PT: $nO_2$ = $\frac{5}{4}$ $nCO_2$
-Theo PT: $nC_2H_2$ = $0,25(mol)$ < $0,3$
$\Rightarrow$ $C_2H_2$ phản ứng thiếu
$\Rightarrow$ $nO_2$ = $\frac{5}{4}$ * $0,5$ = $0,625(mol)$
-Bảo toàn khối lượng:
$mO_2$ + $mC_2H_2$ = $mCO_2$ + $mH_2O$
$0,25 * 26 + 0,625 * 32 = 0,5 * 44 + m_2$
$\Rightarrow$ $m_2$ = $45(g)$
a)
\(n_P = \dfrac{62}{31} = 2(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ n_{O_2} = \dfrac{5}{4}n_P = 2,5(mol)\\ V_{O_2} = 2,5.22,4 = 56(lít)\\ V_{không\ khí} = \dfrac{56}{20\%} = 280(lít)\)
b)
\(n_P = \dfrac{31}{31} = 1(mol) ; n_{O_2} = \dfrac{23}{32} = 0,71875(mol)\\ \dfrac{n_P}{4} = 0,25 > \dfrac{n_{O_2}}{5} = 0,14375 \to P\ dư\\ n_{P\ pư} = \dfrac{4}{5}n_{O_2} = 0,575(mol)\\ m_{P\ dư} = 31 - 0,575.31 = 13,175(gam)\\ n_{P_2O_5} = \dfrac{2}{5}n_{O_2} = 0,2875(mol) \Rightarrow m_{P_2O_5} = 0,2875.142=40,825(gam)\)
\(n_{C_2H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(n_{O_2}=\dfrac{11.2}{22.4}=0.5\left(mol\right)\)
\(C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^0}2CO_2+H_2O\)
\(Bđ:0.3.......0.5\)
\(Pư:0.2........0.5.........0.4.........0.2\)
\(Kt:0.1..........0..........0.4...........0.2\)
\(V_{CO_2}=0.4\cdot22.4=8.96\left(l\right)\)
\(V_{C_2H_2\left(dư\right)}=0.1\cdot22.4=2.24\left(l\right)\)